Switchable behaviors of quadratic nonlinear optical properties originating from bi-step phase transitions in a molecule-based crystal

2018 ◽  
Vol 6 (15) ◽  
pp. 4150-4155 ◽  
Author(s):  
Kewen Tao ◽  
Zhenyue Wu ◽  
Shiguo Han ◽  
Jing Zhang ◽  
Chengmin Ji ◽  
...  

An organic molecular crystal exhibits remarkable switching behaviors of quadratic NLO properties with a large contrast.

2019 ◽  
Vol 43 (32) ◽  
pp. 12865-12873 ◽  
Author(s):  
Sepideh Samiee ◽  
Parisa Hossienpour

A series of [Pt(bpy)(qdt)] {bpy = 2,2′-bipyridine; qdt = quinoxaline-2,3-dithiolate} derivatives was chosen to study the effect of structural modifications on the optoelectronic and nonlinear optical (NLO) properties of the molecules.


2004 ◽  
Vol 08 (07) ◽  
pp. 984-988 ◽  
Author(s):  
Lung-Chang Liu ◽  
Chia-Hon Tai ◽  
Andrew Teh Hu ◽  
Tai-Huei Wei

The nonlinear optical (NLO) properties of lanthanide bisphthalocyanine (Lu(TBPc)Pc), including first hyperpolarizability, second hyperpolarizability and reverse saturable absorption (RSA), have been investigated. Furthermore, Lu(TBPc)Pc has also been applied for optical switch based on its RSA performance.


2017 ◽  
Vol 5 (11) ◽  
pp. 2865-2870 ◽  
Author(s):  
Tariq Khan ◽  
Muhammad Adnan Asghar ◽  
Zhihua Sun ◽  
Aurang Zeb ◽  
Chengmin Ji ◽  
...  

A supra-molecular crystal, 1-[C6H13NH][18-crown-6][ClO4] monohydrate, has been reported to show reversible dielectric anomalies and nonlinear optical properties, which suggests that it could be conceived as the potential switchable dielectric and non-linear optical material.


2019 ◽  
Vol 43 (34) ◽  
pp. 13616-13629
Author(s):  
Muhammed Jeneesh Kariyottu Kuniyil ◽  
Ramanathan Padmanaban

Here we investigate the structural, photophysical and nonlinear optical (NLO) properties of phenoxazin-3-one dyes, resazurin (Rz) and resorufin (Rf), by performing quantum chemical calculations using the DFT and TDDFT methods.


2017 ◽  
Vol 19 (33) ◽  
pp. 22573-22579 ◽  
Author(s):  
E. Cariati ◽  
X. Liu ◽  
Y. Geng ◽  
A. Forni ◽  
E. Lucenti ◽  
...  

Tetrathiafulvalene-fused electron donor–acceptor dyads display second order nonlinear optical properties that can be triggered by a pH or a redox stimulus.


1993 ◽  
Vol 328 ◽  
Author(s):  
Pascal G. Lacroix ◽  
Rene Clement ◽  
Keitaro Nakatani ◽  
Isabelle Ledoux ◽  
Joseph Zyss

ABSTRACTWe have investigated intercalation into optically transparent MPS3 (M = Mn, Cd) phases as a way towards spontaneous poling of cationic chromophores. Two nano-composite Materials of formula M0.86PS3 (dimethylamino-N-Methyl stilbazolium)0.28 were synthezised, and an efficiency up to 750 times that of urea was recorded in the cadmium intercalate. An additional interest arises from the possibility to associate NLO properties with the magnetization of the host lattice in the case of MnPS3 below 40 K.


2021 ◽  
Author(s):  
Chu-Lin Qu ◽  
Zhong-Min Su ◽  
Feng-Wei Gao

 The present work aims to study the second-order NLO properties of m-AD and p-AD regioisomers. The βtot value of p-AD is larger than that of m-AD. Significantly, the external electric field effectively regulates the βtot values (0–3.70 × 104 a.u.) of p-AD.


2018 ◽  
Vol 47 (11) ◽  
pp. 3965-3975 ◽  
Author(s):  
Raphaël J. Durand ◽  
Sébastien Gauthier ◽  
Sylvain Achelle ◽  
Thomas Groizard ◽  
Samia Kahlal ◽  
...  

This work describes the synthesis and electrochemical, photophysical and 2nd order NLO properties of a series of dipolar Ru(ii) dialkynyl complexes.


2020 ◽  
Vol 44 (16) ◽  
pp. 6142-6150 ◽  
Author(s):  
P. K. Vineetha ◽  
A. Aswathy ◽  
E. Shiju ◽  
K. Chandrasekharan ◽  
N. Manoj

The nonlinear optical (NLO) properties of a series of pyran based bipodal D–π–A molecules have been studied experimentally and theoretically.


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