Ti3+ self-doped TiO2−x nanowires for efficient electrocatalytic N2 reduction to NH3

2020 ◽  
Vol 56 (7) ◽  
pp. 1074-1077 ◽  
Author(s):  
Bingyue Li ◽  
Xiaojuan Zhu ◽  
Jianwei Wang ◽  
Ruimin Xing ◽  
Qian Liu ◽  
...  
Keyword(s):  
Reversible Hydrogen Electrode ◽  
Hydrogen Electrode ◽  
Faradaic Efficiency ◽  
Doped Tio2

Ti3+–TiO2−x/TM behaves as an efficient electrocatalyst for ambient N2-to-NH3 fixation with a high faradaic efficiency of 14.62% and a NH3 yield of 3.51 × 10−11 mol s−1 cm−2 at −0.55 V versus a reversible hydrogen electrode in 0.1 M Na2SO4.

An ultrasmall Ru2P nanoparticles–reduced graphene oxide hybrid: an efficient electrocatalyst for NH3 synthesis under ambient conditions

2020 ◽  
Vol 8 (1) ◽  
pp. 77-81 ◽  
Author(s):  
Runbo Zhao ◽  
Chuangwei Liu ◽  
Xiaoxue Zhang ◽  
Xiaojuan Zhu ◽  
Peipei Wei ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Reversible Hydrogen Electrode ◽  
Ambient Conditions ◽  
Hydrogen Electrode ◽  
Faradaic Efficiency ◽  
Reduced Graphene

A Ru2P–reduced graphene oxide hybrid acts as a superior catalyst for electrochemical N2 fixation in 0.1 M HCl, achieving a large NH3 yield of 32.8 μg h−1mgcat.−1 and a high faradaic efficiency of 13.04%−0.05 V vs. the reversible hydrogen electrode.

Electroreduction of carbon dioxide to formate over a thin-layered tin diselenide electrode

2018 ◽  
Vol 8 (21) ◽  
pp. 5428-5433 ◽  
Author(s):  
Hui Yang ◽  
Haoxuan Liu ◽  
Xijun Liu ◽  
Zhe Zhao ◽  
Jun Luo
Keyword(s):  
Carbon Dioxide ◽  
Reversible Hydrogen Electrode ◽  
Hydrogen Electrode ◽  
Faradaic Efficiency ◽  
First Report

We first report a thin-layered SnSe2 film as a robust catalyst for CO2 electroreduction, efficiently affording formate with a faradaic efficiency of 91% and a stable activity for more than 100 h at −0.8 V versus the reversible hydrogen electrode.

Electrocatalytic N2-to-NH3 conversion with high faradaic efficiency enabled using a Bi nanosheet array

2019 ◽  
Vol 55 (36) ◽  
pp. 5263-5266 ◽  
Author(s):  
Rong Zhang ◽  
Lei Ji ◽  
Wenhan Kong ◽  
Huanbo Wang ◽  
Runbo Zhao ◽  
...  
Keyword(s):  
Reversible Hydrogen Electrode ◽  
Hydrogen Electrode ◽  
Faradaic Efficiency ◽  
Nanosheet Array ◽  
Cu Foil

A Bi nanosheet array on Cu foil (Bi NS/CF) is efficient and stable for electrocatalytic N2 reduction. In 0.1 M HCl, it shows a high faradaic efficiency of 10.26% at −0.50 V vs. the reversible hydrogen electrode.

Dendritic Cu: a high-efficiency electrocatalyst for N2 fixation to NH3 under ambient conditions

2019 ◽  
Vol 55 (96) ◽  
pp. 14474-14477 ◽  
Author(s):  
Chengbo Li ◽  
Shiyong Mou ◽  
Xiaojuan Zhu ◽  
Fengyi Wang ◽  
Yuting Wang ◽  
...  
Keyword(s):  
N2 Fixation ◽  
High Efficiency ◽  
Reversible Hydrogen Electrode ◽  
Ambient Conditions ◽  
Hydrogen Electrode ◽  
Faradaic Efficiency ◽  
Yield Rate

Dendritic Cu behaves as an efficient electrocatalyst for ambient N2-to-NH3 fixation with a high Faradaic efficiency of 15.12% and a large NH3 yield rate of 25.63 μg h−1 mgcat.−1 at −0.40 V versus reversible hydrogen electrode in 0.1 M HCl.

Boron-doped CuO nanobundles for electroreduction of carbon dioxide to ethylene

2020 ◽  
Vol 22 (9) ◽  
pp. 2750-2754 ◽  
Author(s):  
Qiang Wan ◽  
Jianling Zhang ◽  
Bingxing Zhang ◽  
Dongxing Tan ◽  
Lei Yao ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Reversible Hydrogen Electrode ◽  
Carbon Product ◽  
Hydrogen Electrode ◽  
Faradaic Efficiency ◽  
Boron Doped

Herein, we synthesize B-doped CuO nanobundles for electrocatalytic CO2 reduction. Ethylene is the only multi-carbon product and a maximum ethylene faradaic efficiency (FE) of 58.4% can be achieved at −1.1 V (versus the reversible hydrogen electrode).

scholarly journals Intimate atomic Cu-Ag interfaces for high CO2RR selectivity towards CH4 at low over potential

Nano Research ◽  
2021 ◽  
Author(s):  
Chungseok Choi ◽  
Jin Cai ◽  
Changsoo Lee ◽  
Hyuck Mo Lee ◽  
Mingjie Xu ◽  
...  
Keyword(s):  
Value Added ◽  
Carbon Dioxide Reduction ◽  
Reduction Reaction ◽  
Reversible Hydrogen Electrode ◽  
Hydrogen Electrode ◽  
Faradaic Efficiency ◽  
Cu Nanowires ◽  
The Past ◽  
Cu Alloys ◽  
Electrochemical Catalysts

AbstractDeveloping highly efficient electrochemical catalysts for carbon dioxide reduction reaction (CO2RR) provides a solution to battle global warming issues resulting from ever-increasing carbon footprint due to human activities. Copper (Cu) is known for its efficiency in CO2RR towards value-added hydrocarbons; hence its unique structural properties along with various Cu alloys have been extensively explored in the past decade. Here, we demonstrate a two-step approach to achieve intimate atomic Cu-Ag interfaces on the surface of Cu nanowires, which show greatly improved CO2RR selectivity towards methane (CH4). The specially designed Cu-Ag interfaces showed an impressive maximum Faradaic efficiency (FE) of 72% towards CH4 production at −1.17 V (vs. reversible hydrogen electrode (RHE)).

TiS2 nanosheets for efficient electrocatalytic N2 fixation to NH3 under ambient conditions

2019 ◽  
Vol 6 (8) ◽  
pp. 1986-1989 ◽  
Author(s):  
Kun Jia ◽  
Yuan Wang ◽  
Lang Qiu ◽  
Jiajia Gao ◽  
Qi Pan ◽  
...  
Keyword(s):  
N2 Fixation ◽  
Reversible Hydrogen Electrode ◽  
Ambient Conditions ◽  
Hydrogen Electrode ◽  
Faradaic Efficiency

TiS2 is efficient for electrochemical N2 fixation to NH3 in 0.1 M Na2SO4, achieving a faradaic efficiency of 5.50% with an NH3 yield of 16.02 μg h−1 mg−1cat at a potential of −0.6 V vs. reversible hydrogen electrode.

Promoting electrocatalytic nitrogen reduction to ammonia via Fe-boosted nitrogen activation on MnO2 surfaces

2020 ◽  
Vol 8 (27) ◽  
pp. 13679-13684 ◽  
Author(s):  
Ting Huang ◽  
Zaichun Liu ◽  
Yu Zhang ◽  
Faxing Wang ◽  
Juan Wen ◽  
...  
Keyword(s):  
Formation Rate ◽  
Good Stability ◽  
Reversible Hydrogen Electrode ◽  
Hydrogen Electrode ◽  
Faradaic Efficiency ◽  
Nitrogen Reduction ◽  
Nitrogen Activation

Fe-doped MnO2 shows excellent NRR behaviour including a high faradaic efficiency of 16.8%, a high NH3 formation rate of 39.2 μg h−1 mgcat.−1 at −0.29 V vs. the reversible hydrogen electrode in 0.1 M Na2SO4, and good stability.

Ambient electrohydrogenation of N2 for NH3 synthesis on non-metal boron phosphide nanoparticles: the critical role of P in boosting the catalytic activity

2019 ◽  
Vol 7 (27) ◽  
pp. 16117-16121 ◽  
Author(s):  
Xiaojuan Zhu ◽  
Tongwei Wu ◽  
Lei Ji ◽  
Chengbo Li ◽  
Ting Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Critical Role ◽  
Reduction Reaction ◽  
Reversible Hydrogen Electrode ◽  
Hydrogen Electrode ◽  
Faradaic Efficiency ◽  
Boron Phosphide

As a non-metal electrocatalyst for the N2 reduction reaction, boron phosphide nanoparticles offer a high NH3 yield of 26.42 μg h−1 mgcat.−1 and a high faradaic efficiency of 12.7% at –0.60 V vs. the reversible hydrogen electrode in 0.1 M HCl.

Sulfur-doped graphene for efficient electrocatalytic N2-to-NH3 fixation

2019 ◽  
Vol 55 (23) ◽  
pp. 3371-3374 ◽  
Author(s):  
Li Xia ◽  
Jiajia Yang ◽  
Huanbo Wang ◽  
Runbo Zhao ◽  
Hongyu Chen ◽  
...  
Keyword(s):  
Reversible Hydrogen Electrode ◽  
Hydrogen Electrode ◽  
Faradaic Efficiency ◽  
Doped Graphene

Sulfur-doped graphene (S-G) is superior for electrocatalytic ambient N2-to-NH3 fixation, offering a remarkably large NH3 yield of 27.3 μg h−1 mgcat.−1 and a high Faradaic efficiency of 11.5% at −0.6 and −0.5 V vs. a reversible hydrogen electrode, respectively, in 0.1 M HCl.

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