scholarly journals Influence of the hydrophobic domain on the self-assembly and hydrogen bonding of hydroxy-amphiphiles

2019 ◽  
Vol 21 (21) ◽  
pp. 11242-11258
Author(s):  
Valery Andrushchenko ◽  
Walter Pohle
Keyword(s):  
Hydrogen Bonding ◽  
Ir Spectroscopy ◽  
Self Assembly ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Hydrophobic Domain

IR spectroscopy paired with calculations reveals that structurally similar amphiphiles ODA and DOG form very different supramolecular assemblies.

Halogen bonding controlled 2D self-assembled polymorphism of regioisomeric thienophenanthrene derivatives by coadsorption

2021 ◽  
Author(s):  
Peng Pang ◽  
Yi Wang ◽  
Xinrui Miao ◽  
Bang Li ◽  
Wenli Deng
Keyword(s):  
Hydrogen Bonding ◽  
Formation Mechanism ◽  
Self Assembly ◽  
Halogen Bond ◽  
Bond Formation ◽  
Halogen Bonding ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Self Assembled

Deeply understanding the halogen-bond formation mechanism in surface-supported supramolecular assemblies is under explored compared with the existing knowledge of hydrogen bonding. Here we report the self-assembly of regioisomeric bromine substituted...

Estimating the shape and size of supramolecular assemblies by variable temperature diffusion ordered spectroscopy

2014 ◽  
Vol 12 (40) ◽  
pp. 7932-7936 ◽  
Author(s):  
Benjamin M. Schulze ◽  
Davita L. Watkins ◽  
Jing Zhang ◽  
Ion Ghiviriga ◽  
Ronald K. Castellano
Keyword(s):  
Self Assembly ◽  
Variable Temperature ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Conjugated Oligomers ◽  
Photovoltaic Devices ◽  
Temperature Diffusion ◽  
Shape And Size

Reported is characterization of the self-assembly of π-conjugated oligomers, molecules studied recently in photovoltaic devices, using variable temperature diffusion ordered spectroscopy; the approach has allowed estimation of assembly size, shape, and molecularity.

Recording the Self-Assembly Behavior of Nanomaterials Directed by Hydrogen Bonding

2021 ◽  
Author(s):  
Ganghuo Pan ◽  
Jie Leng ◽  
Liye Deng ◽  
Liwen Xing ◽  
Rui Feng
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
The Self ◽  
Assembly Behavior

scholarly journals Supramolecular assemblies of organo-functionalised hybrid polyoxometalates: from functional building blocks to hierarchical nanomaterials

2022 ◽  
Author(s):  
Jamie M. Cameron ◽  
Geoffroy Guillemot ◽  
Theodor Galambos ◽  
Sharad S. Amin ◽  
Elizabeth Hampson ◽  
...  
Keyword(s):  
Self Assembly ◽  
Building Blocks ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Supramolecular Materials ◽  
Inorganic Hybrid ◽  
Hierarchical Nanomaterials

Organic–inorganic hybrid polyoxometalates are versatile building blocks for the self-assembly of functional supramolecular materials.

Intermolecular interactions in dictating the self-assembly of halogen derivatives of bis-(N-substituted oxamato)palladate(ii) complexes

RSC Advances ◽  
2016 ◽  
Vol 6 (8) ◽  
pp. 6164-6170 ◽  
Author(s):  
Francisco Ramón Fortea-Pérez ◽  
Nadia Marino ◽  
Giovanni de Munno ◽  
Donatella Armentano ◽  
Miguel Julve ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Intermolecular Interactions ◽  
Self Assembly ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Derivatives Of

The reaction of aqueous [PdCl4]2−withN-4-Xphenyloxamate ligands (X = F, Cl, Br) afforded three non-isostructural compounds exhibiting intriguing diverse supramolecular assemblies driven by hydrogen bonds and/or halogen⋯halogen interactions.

Cooperative self-assembly and gelation of organogold(i) complexes via hydrogen bonding and aurophilic Au⋯Au interactions

2017 ◽  
Vol 53 (84) ◽  
pp. 11552-11555 ◽  
Author(s):  
Jiangjun Chen ◽  
Zhongxin Zhang ◽  
Chengming Wang ◽  
Zhao Gao ◽  
Zongchun Gao ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
The Self ◽  
Self Assembled

Organogold(i)-based fibers and gels have been successfully constructed, which involve Au⋯Au interactions in the self-assembled structures.

Charge-Assisted Hydrogen Bonding and Other Noncovalent Interactions in the Self-Assembly of the Organometallic Building Block [(η6-hydroquinone)Rh(P(OPh)3)2]+with a Range of Counteranions

2006 ◽  
Vol 25 (22) ◽  
pp. 5276-5285 ◽  
Author(s):  
Seung Uk Son ◽  
Jeffrey A. Reingold ◽  
Gene B. Carpenter ◽  
Paul T. Czech ◽  
Dwight A. Sweigart
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
Building Block ◽  
Noncovalent Interactions ◽  
The Self

Mastering nanostructured materials through H-bonding recognitions at interfaces

2010 ◽  
Vol 82 (4) ◽  
pp. 917-929 ◽  
Author(s):  
Stefan Mohnani ◽  
Anna Llanes-Pallas ◽  
Davide Bonifazi
Keyword(s):  
Hydrogen Bonding ◽  
Electronic Properties ◽  
Nanostructured Materials ◽  
Self Assembly ◽  
The Self ◽  
Memory Storage ◽  
Technological Application ◽  
Storage Devices ◽  
Hydrogen Bonding Interactions ◽  
Fundamental Research

The controlled engineering of functional architectures composed of π-systems with unusual opto-electronic properties is currently being investigated intensively from both fundamental research and technological application viewpoints. In particular, the exploitation of the supramolecular approach for the facile construction of multidimensional architectures, featuring cavities capable of hosting functional molecules, could be used in several applications, such as nanomedicine, molecular-based memory storage devices, and sensors. This paper highlights our recent strategies to use hydrogen-bonding interactions to prepare nanostructured functional architectures via the self-assembly of organic molecular modules studied at different interfaces.

scholarly journals {N 1-[2-(Butylselanyl)benzyl]-N 2,N 2-dimethylethane-1,2-diamine}dichloridomercury(II)

2018 ◽  
Vol 74 (8) ◽  
pp. 1151-1154
Author(s):  
Pushpendra Singh ◽  
Harkesh B. Singh ◽  
Ray J. Butcher
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Self Assembly ◽  
Title Compound ◽  
Supramolecular Assembly ◽  
Molecular Geometry ◽  
The Self ◽  
Intermolecular Hydrogen Bonding ◽  
Hydrogen Bonding Interactions ◽  
Donor Acceptor

In the title compound, [HgCl2(C16H28N2Se)], the primary geometry around the Se and Hg atoms is distorted trigonal–pyramidal and distorted square-pyramidal, respectively. The distortion of the molecular geometry in the complex is caused by the steric demands of the ligands attached to the Se atom. The Hg atom is coordinated through two chloride anions, an N atom and an Se atom, making up an unusual HgNSeCl2 coordination sphere with an additional long Hg...N interaction. Intermolecular C—H...Cl interactions are the only identified intermolecular hydrogen-bonding interactions that seem to be responsible for the self assembly. These relatively weak C—H...Cl hydrogen bonds possess the required linearity and donor–acceptor distances. They act as molecular associative forces that result in a supramolecular assembly along the b-axis direction in the solid state of the title compound.

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