scholarly journals Highly fluorescent hybrid Au/Ag nanoclusters stabilized with poly(ethylene glycol)- and zwitterion-modified thiolate ligands

2019 ◽  
Vol 21 (38) ◽  
pp. 21317-21328 ◽  
Author(s):  
Dinesh Mishra ◽  
Sisi Wang ◽  
Zhicheng Jin ◽  
Yan Xin ◽  
Eric Lochner ◽  
...  

We report the growth, via core transformation, of highly fluorescing, near-infrared-emitting bimetallic Au/Ag nanoclusters, which are capped with hydrophobic or hydrophilic monothiol-terminated ligands.

2016 ◽  
Vol 52 (5) ◽  
pp. 978-981 ◽  
Author(s):  
Xinyu Wang ◽  
Changping Wang ◽  
Qiang Zhang ◽  
Yiyun Cheng

A near infrared light-responsive supramolecular hydrogel consisting of α-cyclodextrin and poly(ethylene glycol)-modified dendrimer-encapsulated platinum nanoparticles was developed for on-demand drug delivery.


2014 ◽  
Vol 5 (3) ◽  
pp. 799-813 ◽  
Author(s):  
Ji Liu ◽  
Christophe Detrembleur ◽  
Marie-Claire De Pauw-Gillet ◽  
Stéphane Mornet ◽  
Etienne Duguet ◽  
...  

2012 ◽  
Vol 8 (2) ◽  
pp. 228-236 ◽  
Author(s):  
Hyunah Cho ◽  
Guilherme L. Indig ◽  
Jamey Weichert ◽  
Ho-Chul Shin ◽  
Glen S. Kwon

2019 ◽  
Vol 10 (10) ◽  
Author(s):  
Anton Bonartsev ◽  
Vera Voinova ◽  
Elizaveta Akoulina ◽  
Andrey Dudun ◽  
Irina Zharkova ◽  
...  

2018 ◽  
Author(s):  
Dinesh Mishra ◽  
Sisi Wang ◽  
Zhicheng Jin ◽  
Eric Lochner ◽  
Hedi Mattoussi

<p>We describe the growth and characterization of highly fluorescing, near-infrared-emitting nanoclusters made of bimetallic Au<sub>25-x</sub>Ag<sub>x</sub> cores, prepared using various monothiol-appended hydrophobic and hydrophilic ligands. The reaction uses well-defined triphenylphosphine-protected Au<sub>11</sub> clusters (as precursors), which are reacted with Ag(I)-thiolate complexes. The prepared nanoclusters are small (diameter < 2nm, as characterized by TEM) with emission peak at 760 nm and long lifetime (~12 µs). The quantum yield measured for these materials was 0.3 - 0.4 depending on the ligand. XPS measurements show the presence of both metal atoms in the core, with measured binding energies that agree with reported values for nanocluster materials. The NIR emission combined with high quantum yield, small size and ease of surface functionalization afforded by the coating, make these materials suitable to implement investigations that address fundamental questions and potentially useful for biological sensing and imaging applications.<br></p>


2007 ◽  
Vol 32 (5) ◽  
pp. 431-446 ◽  
Author(s):  
Tahar Bartil ◽  
Mahmoud Bounekhel ◽  
Cedric Calberg ◽  
Robert Jerome

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