Comment on “Revisiting π backbonding: the influence of d orbitals on metal–CO bonds and ligand red shifts” by D. Koch, Y. Chen, P. Golub and S. Manzhos, Phys. Chem. Chem. Phys., 2019, 21, 20814
2020 ◽
Vol 22
(9)
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pp. 5377-5379
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Keyword(s):
We challenge the statement of Koch et al. that the M → CO charge transfer and the decrease of the CO stretching frequency in metal carbonyl complexes do not depend on the metal d orbitals.
1986 ◽
Vol 47
(C8)
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pp. C8-589-C8-592
2019 ◽
Vol 58
(21)
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pp. 14931-14937
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2019 ◽
Vol 6
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pp. 3041-3056
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2004 ◽
Vol 76
(3)
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pp. 557-564
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1988 ◽
Vol 37
(3)
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pp. 470-475
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1993 ◽
Vol 447
(1)
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pp. 59-65
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