Luminescent metal–organic framework-based phosphor for the detection of toxic oxoanions in an aqueous medium

2020 ◽  
Vol 49 (3) ◽  
pp. 829-840 ◽  
Author(s):  
Debal Kanti Singha ◽  
Prakash Majee ◽  
Sayani Hui ◽  
Sudip Kumar Mondal ◽  
Partha Mahata

Compound 1 has been utilized for the luminescence based visible detection of chromate, permanganate and phosphate ions in aqueous medium.

2021 ◽  
Author(s):  
Sudip Kumar Mondal ◽  
Partha Mahata ◽  
Pooja Daga ◽  
Sourav Sarkar ◽  
Prakash Majee ◽  
...  

A new metal-organic framework (MOF) showed excellent recognition ability towards five toxic oxo-anions viz. arsenate (HAsO42-), phosphate (PO43-), permanganate (MnO4-), chromate (CrO42-) and dichromate (Cr2O72-) in aqueous medium upon irradiation...


Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 419
Author(s):  
Hamza Ahmad Isiyaka ◽  
Khairulazhar Jumbri ◽  
Nonni Soraya Sambudi ◽  
Jun Wei Lim ◽  
Bahruddin Saad ◽  
...  

Drift deposition of emerging and carcinogenic contaminant dicamba (3,6-dichloro-2-methoxy benzoic acid) has become a major health and environmental concern. Effective removal of dicamba in aqueous medium becomes imperative. This study investigates the adsorption of a promising adsorbent, MIL-101(Cr) metal-organic framework (MOF), for the removal of dicamba in aqueous solution. The adsorbent was hydrothermally synthesized and characterized using N2 adsorption-desorption isotherms, Brunauer, Emmett and Teller (BET), powdered X-ray diffraction (XRD), Fourier Transformed Infrared (FTIR) and field emission scanning electron microscopy (FESEM). Adsorption models such as kinetics, isotherms and thermodynamics were studied to understand details of the adsorption process. The significance and optimization of the data matrix, as well as the multivariate interaction of the adsorption parameters, were determined using response surface methodology (RSM). RSM and artificial neural network (ANN) were used to predict the adsorption capacity. In each of the experimental adsorption conditions used, the ANN gave a better prediction with minimal error than the RSM model. The MIL-101(Cr) adsorbent was recycled six times to determine the possibility of reuse. The results show that MIL-101(Cr) is a very promising adsorbent, in particular due to the high surface area (1439 m2 g−1), rapid equilibration (~25 min), high adsorption capacity (237.384 mg g−1) and high removal efficiency of 99.432%.


2019 ◽  
Vol 7 (27) ◽  
pp. 8383-8388 ◽  
Author(s):  
Yan-Mei Ying ◽  
Chen-Lei Tao ◽  
Maoxing Yu ◽  
Yi Xiong ◽  
Chang-Rui Guo ◽  
...  

A highly luminescent MOF containing tetraphenylethene-based cations has been prepared through in situ encapsulation, which can serve as a fluorescent sensor for selective and sensitive detection of nitrofuran antibiotics in aqueous media.


2020 ◽  
Vol 49 (36) ◽  
pp. 12565-12573
Author(s):  
Soutick Nandi ◽  
Mostakim SK ◽  
Shyam Biswas

A diacetoxy-functionalized Zr-based metal–organic framework was employed for the selective, ultra-sensitive, turn-on fluorescent detection of hydrazine in an aqueous medium.


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