scholarly journals Selective Detection of nano-molar range Noxious Anions in Water by a Luminescent Metal-Organic Framework

2021 ◽  
Author(s):  
Sudip Kumar Mondal ◽  
Partha Mahata ◽  
Pooja Daga ◽  
Sourav Sarkar ◽  
Prakash Majee ◽  
...  

A new metal-organic framework (MOF) showed excellent recognition ability towards five toxic oxo-anions viz. arsenate (HAsO42-), phosphate (PO43-), permanganate (MnO4-), chromate (CrO42-) and dichromate (Cr2O72-) in aqueous medium upon irradiation...

2019 ◽  
Vol 58 (23) ◽  
pp. 16065-16074 ◽  
Author(s):  
Richa Rajak ◽  
Mohit Saraf ◽  
Sanjay K. Verma ◽  
Ravinder Kumar ◽  
Shaikh M. Mobin

2021 ◽  
Vol 231 ◽  
pp. 117798
Author(s):  
Ting Gao ◽  
Lingling Gao ◽  
Jie Zhang ◽  
Wendi Zhou ◽  
Zhikai Zhang ◽  
...  

Author(s):  
Shivani Sharma ◽  
Sumanta Let ◽  
Aamod V. Desai ◽  
Subhajit Dutta ◽  
Gopalsamy Karuppasamy ◽  
...  

Fast, selective capture of oxoanions of selenium [Se(iv), Se(vi)] and arsenic [As(v)] by a chemically stable cationic MOF, viz. iMOF-3C, is reported. The compound successfully yields drinking quality water from complicated matrix including river water.


Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 419
Author(s):  
Hamza Ahmad Isiyaka ◽  
Khairulazhar Jumbri ◽  
Nonni Soraya Sambudi ◽  
Jun Wei Lim ◽  
Bahruddin Saad ◽  
...  

Drift deposition of emerging and carcinogenic contaminant dicamba (3,6-dichloro-2-methoxy benzoic acid) has become a major health and environmental concern. Effective removal of dicamba in aqueous medium becomes imperative. This study investigates the adsorption of a promising adsorbent, MIL-101(Cr) metal-organic framework (MOF), for the removal of dicamba in aqueous solution. The adsorbent was hydrothermally synthesized and characterized using N2 adsorption-desorption isotherms, Brunauer, Emmett and Teller (BET), powdered X-ray diffraction (XRD), Fourier Transformed Infrared (FTIR) and field emission scanning electron microscopy (FESEM). Adsorption models such as kinetics, isotherms and thermodynamics were studied to understand details of the adsorption process. The significance and optimization of the data matrix, as well as the multivariate interaction of the adsorption parameters, were determined using response surface methodology (RSM). RSM and artificial neural network (ANN) were used to predict the adsorption capacity. In each of the experimental adsorption conditions used, the ANN gave a better prediction with minimal error than the RSM model. The MIL-101(Cr) adsorbent was recycled six times to determine the possibility of reuse. The results show that MIL-101(Cr) is a very promising adsorbent, in particular due to the high surface area (1439 m2 g−1), rapid equilibration (~25 min), high adsorption capacity (237.384 mg g−1) and high removal efficiency of 99.432%.


2017 ◽  
Vol 32 (3) ◽  
pp. e4132 ◽  
Author(s):  
Sen Yang ◽  
Zhi‐Hui Zhang ◽  
Qun Chen ◽  
Ming‐Yang He ◽  
Liang Wang

ChemPlusChem ◽  
2016 ◽  
Vol 81 (8) ◽  
pp. 885-892 ◽  
Author(s):  
Bao-Hong Li ◽  
Jian Wu ◽  
Jian-Qiang Liu ◽  
Chu-Ying Gu ◽  
Jing-Wen Xu ◽  
...  

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