scholarly journals Applicability of electro-osmotic flow for the analysis of the surface zeta potential

RSC Advances ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 6777-6789 ◽  
Author(s):  
Olivija Plohl ◽  
Lidija Fras Zemljič ◽  
Sanja Potrč ◽  
Thomas Luxbacher

Detail comparison of two different electrokinetic phenomena EOF and SP method for the SZP determination with taking into account various materials with different surface and bulk properties.

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ramin Zakeri

AbstractOne of the unresolved issues in physiology is how exactly myosin moves in a filament as the smallest responsible organ for contracting of a natural muscle. In this research, inspired by nature, a model is presented consisting of DPD (dissipative particle dynamics) particles driven by electro-osmotic flow (EOF) in micro channel that a thin movable impermeable polymer membrane has been attached across channel width, thus momentum of fluid can directly transfer to myosin stem. At the first, by validation of electro-osmotic flow in micro channel in different conditions with accuracy of less than 10 percentage error compared to analytical results, the DPD results have been developed to displacement of an impermeable polymer membrane in EOF. It has been shown that by the presence of electric field of 250 V/m and Zeta potential − 25 mV and the dimensionless ratio of the channel width to the thickness of the electric double layer or kH = 8, about 15% displacement in 8 s time will be obtained compared to channel width. The influential parameters on the displacement of the polymer membrane from DPD particles in EOF such as changes in electric field, ion concentration, zeta potential effect, polymer material and the amount of membrane elasticity have been investigated which in each cases, the radius of gyration and auto correlation velocity of different polymer membrane cases have been compared together. This simulation method in addition of probably helping understand natural myosin displacement mechanism, can be extended to design the contraction of an artificial muscle tissue close to nature.


2019 ◽  
Vol 141 (8) ◽  
Author(s):  
Hyunsung Kim ◽  
Aminul Islam Khan ◽  
Prashanta Dutta

Mixing in a microfluidic device is a major challenge due to creeping flow, which is a significant roadblock for development of lab-on-a-chip device. In this study, an analytical model is presented to study the fluid flow behavior in a microfluidic mixer using time-periodic electro-osmotic flow. To facilitate mixing through microvortices, nonuniform surface charge condition is considered. A generalized analytical solution is obtained for the time-periodic electro-osmotic flow using a stream function technique. The electro-osmotic body force term is accounted as a slip boundary condition on the channel wall, which is a function of time and space. To demonstrate the applicability of the analytical model, two different surface conditions are considered: sinusoidal and step change in zeta potential along the channel surface. Depending on the zeta potential distribution, we obtained diverse flow patterns and vortices. The flow circulation and its structures depend on channel size, charge distribution, and the applied electric field frequency. Our results indicate that the sinusoidal zeta potential distribution provides elliptical shaped vortices, whereas the step change zeta potential provides rectangular shaped vortices. This analytical model is expected to aid in the effective micromixer design.


2006 ◽  
Vol 128 (6) ◽  
pp. 1133-1143 ◽  
Author(s):  
S. A. Mirbozorgi ◽  
H. Niazmand ◽  
M. Renksizbulut

The effects of non-uniform zeta potentials on electro-osmotic flows in flat microchannels have been investigated with particular attention to reservoir effects. The governing equations, which consist of a Laplace equation for the distribution of external electric potential, a Poisson equation for the distribution of electric double layer potential, the Nernst-Planck equation for the distribution of charge density, and modified Navier-Stokes equations for the flow field are solved numerically for an incompressible steady flow of a Newtonian fluid using the finite-volume method. For the validation of the numerical scheme, the key features of an ideal electro-osmotic flow with uniform zeta potential have been compared with analytical solutions for the ionic concentration, electric potential, pressure, and velocity fields. When reservoirs are included in the analysis, an adverse pressure gradient is induced in the channel due to entrance and exit effects even when the reservoirs are at the same pressure. Non-uniform zeta potentials lead to complex flow fields, which are examined in detail.


Author(s):  
R Kamali ◽  
M Eslami

Transient electro-osmotic flow in rectangular microchannels is investigated numerically in this article. The complete Poisson—Boltzmann equation along with the time-dependent momentum equation is solved using the finite-difference method. Moreover, linearized equations based on the Debye—Huckle assumption are also solved to compare with the available analytical approximate solutions. The effects of different parameters such as wall zeta potential, non-dimensional electrokinetic width, and channel aspect ratio are also studied. It is shown that the Debye—Huckle approximation is not only valid for small values of zeta potential, but also the channel hydraulic diameter should be large enough with respect to electrical double layer (EDL) thickness. In addition, the flow behaviour at higher values of zeta potential is shown to be completely different from what available analytical solutions predict. Effective parameters on the transition period from the start time to the steady-state condition are also discussed. On the other hand, a comparison between the present numerical solution and the results of slip velocity approximation reveals that the slip model could be only used for very large values of non-dimensional electro-kinetic width. Finally, velocity distributions in channels of different aspect ratios are provided and discussed.


2020 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Ahamed Saleel C. ◽  
Asif Afzal ◽  
Irfan Anjum Badruddin ◽  
T.M. Yunus Khan ◽  
Sarfaraz Kamangar ◽  
...  

Purpose The characteristics of fluid motions in micro-channel are strong fluid-wall surface interactions, high surface to volume ratio, extremely low Reynolds number laminar flow, surface roughness and wall surface or zeta potential. Due to zeta potential, an electrical double layer (EDL) is formed in the vicinity of the wall surface, namely, the stern layer (layer of immobile ions) and diffuse layer (layer of mobile ions). Hence, its competent designs demand more efficient micro-scale mixing mechanisms. This paper aims to therefore carry out numerical investigations of electro osmotic flow and mixing in a constricted microchannel by modifying the existing immersed boundary method. Design/methodology/approach The numerical solution of electro-osmotic flow is obtained by linking Navier–Stokes equation with Poisson and Nernst–Planck equation for electric field and transportation of ion, respectively. Fluids with different concentrations enter the microchannel and its mixing along its way is simulated by solving the governing equation specified for the concentration field. Both the electro-osmotic effects and channel constriction constitute a hybrid mixing technique, a combination of passive and active methods. In microchannels, the chief factors affecting the mixing efficiency were studied efficiently from results obtained numerically. Findings The results indicate that the mixing efficiency is influenced with a change in zeta potential (ζ), number of triangular obstacles, EDL thickness (λ). Mixing efficiency decreases with an increment in external electric field strength (Ex), Peclet number (Pe) and Reynolds number (Re). Mixing efficiency is increased from 28.2 to 50.2% with an increase in the number of triangular obstacles from 1 to 5. As the value of Re and Pe is decreased, the overall percentage increase in the mixing efficiency is 56.4% for the case of a mixing micro-channel constricted with five triangular obstacles. It is also vivid that as the EDL overlaps in the micro-channel, the mixing efficiency is 52.7% for the given zeta potential, Re and Pe values. The findings of this study may be useful in biomedical, biotechnological, drug delivery applications, cooling of microchips and deoxyribonucleic acid hybridization. Originality/value The process of mixing in microchannels is widely studied due to its application in various microfluidic devices like micro electromechanical systems and lab-on-a-chip devices. Hence, its competent designs demand more efficient micro-scale mixing mechanisms. The present study carries out numerical investigations by modifying the existing immersed boundary method, on pressure-driven electro osmotic flow and mixing in a constricted microchannel using the varied number of triangular obstacles by using a modified immersed boundary method. In microchannels, the theory of EDL combined with pressure-driven flow elucidates the electro-osmotic flow.


Author(s):  
Ramil Siraev ◽  
Dmitry Bratsun ◽  
Pavel Ilyushin

In recent years, the gradual minimization of continuous-flow chemical reactors, which is stimulated by the interests of pharmaceutical production, has led to the emergence of a new generation of microreactors.  A decrease in the thickness of the channels where the species contact and react, forces to search for new, non-mechanical, mechanisms for mixing the initial solutions.  In this work, we consider the efficiency of mixing the reactants induced by electro-osmotic flow in a Hele-Shaw configuration with non-uniform zeta potential distribution. We consider the neutralization reaction, which has simple but non-linear kinetics, as a test reaction. The reaction occurs between two miscible solutions, which are initially separated in space and come into contact in a continuous-flow microreactor. The reaction proceeds frontally, which prevents the efficient mixing of the reactants due to diffusion. We show numerically that the mixing of solutions can be effectively controlled by specifying special forms of the zeta potential, which make it possible to lengthen the reaction front by an order of magnitude and increase the yield of the reaction product by several times.


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