Na2.3Cu1.1Mn2O7−δ nanoflakes as enhanced cathode materials for high-energy sodium-ion batteries achieved by a rapid pyrosynthesis approach

2020 ◽  
Vol 8 (2) ◽  
pp. 770-778 ◽  
Author(s):  
Vaiyapuri Soundharrajan ◽  
Balaji Sambandam ◽  
Muhammad H. Alfaruqi ◽  
Sungjin Kim ◽  
Jeonggeun Jo ◽  
...  
Keyword(s):  
Cathode Materials ◽  
Single Phase ◽  
High Energy ◽  
Positive Electrode ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Phase Reaction

Na2.3Cu1.1Mn2O7−δ nanoflakes prepared by an ultrafast pyrosynthesis approach are used as the positive electrode for SIBs. In situ GITT and XRD results support the occurrence of a single-phase reaction in the Na2.3Cu1.1Mn2O7−δ nanoflakes cathode during Na+ (de)intercalation.

scholarly journals RECENT ADVANCES IN SODIUM INTERCALATION POSITIVE ELECTRODE MATERIALS FOR SODIUM ION BATTERIES

2013 ◽  
Vol 06 (01) ◽  
pp. 1330001 ◽  
Author(s):  
JING XU ◽  
DAE HOE LEE ◽  
YING SHIRLEY MENG
Keyword(s):  
Electrode Materials ◽  
High Energy ◽  
Positive Electrode ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Significant Progress ◽  
Layered Oxides ◽  
Solid State Physics ◽  
The Past ◽  
Positive Electrode Materials

Significant progress has been achieved in the research on sodium intercalation compounds as positive electrode materials for Na-ion batteries. This paper presents an overview of the breakthroughs in the past decade for developing high energy and high power cathode materials. Two major classes, layered oxides and polyanion compounds, are covered. Their electrochemical performance and the related crystal structure, solid state physics and chemistry are summarized and compared.

scholarly journals Tuning local chemistry of P2 layered-oxide cathode for high energy and long cycles of sodium-ion battery

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Chenchen Wang ◽  
Luojia Liu ◽  
Shuo Zhao ◽  
Yanchen Liu ◽  
Yubo Yang ◽  
...  
Keyword(s):  
Phase Transition ◽  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Cathode Materials ◽  
Specific Capacity ◽  
High Energy ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Two Phase

AbstractLayered transition-metal oxides have attracted intensive interest for cathode materials of sodium-ion batteries. However, they are hindered by the limited capacity and inferior phase transition due to the gliding of transition-metal layers upon Na+ extraction and insertion in the cathode materials. Here, we report that the large-sized K+ is riveted in the prismatic Na+ sites of P2-Na0.612K0.056MnO2 to enable more thermodynamically favorable Na+ vacancies. The Mn-O bonds are reinforced to reduce phase transition during charge and discharge. 0.901 Na+ per formula are reversibly extracted and inserted, in which only the two-phase transition of P2 ↔ P’2 occurs at low voltages. It exhibits the highest specific capacity of 240.5 mAh g−1 and energy density of 654 Wh kg−1 based on the redox of Mn3+/Mn4+, and a capacity retention of 98.2% after 100 cycles. This investigation will shed lights on the tuneable chemical environments of transition-metal oxides for advanced cathode materials and promote the development of sodium-ion batteries.

scholarly journals Toward high energy density cathode materials for sodium-ion batteries: investigating the beneficial effect of aluminum doping on the P2-type structure

2017 ◽  
Vol 5 (9) ◽  
pp. 4467-4477 ◽  
Author(s):  
Ivana Hasa ◽  
Stefano Passerini ◽  
Jusef Hassoun
Keyword(s):  
Energy Density ◽  
Beneficial Effect ◽  
Layered Structure ◽  
Cathode Materials ◽  
High Energy ◽  
Sodium Ion ◽  
High Energy Density ◽  
Sodium Ion Batteries ◽  
Excellent Performance ◽  
Aluminum Doping

Aluminum doping of the P2-type layered structure results in a Na-ion cathode material (Na0.6Ni0.22Al0.11Mn0.66O2) with excellent performance.

In Situ-Formed Hierarchical Metal-Organic Flexible Cathode for High-Energy Sodium-Ion Batteries

ChemSusChem ◽  
2017 ◽  
Vol 10 (23) ◽  
pp. 4704-4708 ◽  
Author(s):  
Ying Huang ◽  
Chun Fang ◽  
Rui Zeng ◽  
Yaojun Liu ◽  
Wang Zhang ◽  
...  
Keyword(s):  
High Energy ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Metal Organic

Triclinic Off-Stoichiometric Na3.12Mn2.44(P2O7)2/C Cathode Materials for High-Energy/Power Sodium-Ion Batteries

2018 ◽  
Vol 10 (29) ◽  
pp. 24564-24572 ◽  
Author(s):  
Huangxu Li ◽  
Zhian Zhang ◽  
Ming Xu ◽  
Weizhai Bao ◽  
Yanqing Lai ◽  
...  
Keyword(s):  
Cathode Materials ◽  
High Energy ◽  
Sodium Ion ◽  
Sodium Ion Batteries

scholarly journals Off-stoichiometric Na3−3xV2+x(PO4)3/C nanocomposites as cathode materials for high-performance sodium-ion batteries prepared by high-energy ball milling

RSC Advances ◽  
2018 ◽  
Vol 8 (36) ◽  
pp. 20319-20326 ◽  
Author(s):  
Pingping Sun ◽  
Yuanting Wang ◽  
Xiuzhen Wang ◽  
Qingyu Xu ◽  
Qi Fan ◽  
...  
Keyword(s):  
Energy Storage ◽  
Cathode Material ◽  
Ball Milling ◽  
Cathode Materials ◽  
High Performance ◽  
High Energy ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Energy Ball ◽  
Energy Storage Applications

Na3V2(PO4)3 (NVP) is regarded as a promising cathode material for sustainable energy storage applications.

Recent advances in high energy-density cathode materials for sodium-ion batteries

2019 ◽  
Vol 21 ◽  
pp. e00098 ◽  
Author(s):  
Yingchun Lyu ◽  
Yuchen Liu ◽  
Zhuo-Er Yu ◽  
Na Su ◽  
Yang Liu ◽  
...  
Keyword(s):  
Energy Density ◽  
Cathode Materials ◽  
High Energy ◽  
Sodium Ion ◽  
High Energy Density ◽  
Sodium Ion Batteries ◽  
Recent Advances

Multidimensional Na4VMn0.9Cu0.1(PO4)3/C cotton-candy cathode materials for high energy Na-ion batteries

2020 ◽  
Vol 8 (24) ◽  
pp. 12055-12068
Author(s):  
Vaiyapuri Soundharrajan ◽  
Muhammad H. Alfaruqi ◽  
Seulgi Lee ◽  
Balaji Sambandam ◽  
Sungjin Kim ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Cathode Materials ◽  
High Energy ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Cotton Candy ◽  
Superior Electrochemical Properties

NASICON-structured Na4VMn0.9Cu0.1(PO4)3 cotton candy-like cathode, which was employed for sodium-ion batteries, demonstrates superior electrochemical properties..

Na+/Vacancy Disordered P2-Na0.67Co1–xTixO2: High-Energy and High-Power Cathode Materials for Sodium Ion Batteries

2018 ◽  
Vol 10 (4) ◽  
pp. 3562-3570 ◽  
Author(s):  
Seok Mun Kang ◽  
Jae-Hyuk Park ◽  
Aihua Jin ◽  
Young Hwa Jung ◽  
Junyoung Mun ◽  
...  
Keyword(s):  
High Power ◽  
Cathode Materials ◽  
High Energy ◽  
Sodium Ion ◽  
Sodium Ion Batteries

High-Energy/Power and Low-Temperature Cathode for Sodium-Ion Batteries: In Situ XRD Study and Superior Full-Cell Performance

2017 ◽  
Vol 29 (33) ◽  
pp. 1701968 ◽  
Author(s):  
Jin-Zhi Guo ◽  
Peng-Fei Wang ◽  
Xing-Long Wu ◽  
Xiao-Hua Zhang ◽  
Qingyu Yan ◽  
...  
Keyword(s):  
Low Temperature ◽  
High Energy ◽  
Cell Performance ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Full Cell ◽  
In Situ Xrd ◽  
Xrd Study
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