Exploring the role of halide mixing in lead-free BZA2SnX4 two dimensional hybrid perovskites

2020 ◽  
Vol 8 (4) ◽  
pp. 1875-1886 ◽  
Author(s):  
Ambra Pisanu ◽  
Mauro Coduri ◽  
Marta Morana ◽  
Yasemin O. Ciftci ◽  
Aurora Rizzo ◽  
...  

The role of halide substitution in a lead-free 2D hybrid perovskite is studied on the BZA2SnX4 (BZA = benzylammonium; X = Cl, Br, I) system, by reporting the two novel compositions BZA2SnBr4 and BZA2SnCl4.

2020 ◽  
Vol 8 (37) ◽  
pp. 12848-12853
Author(s):  
Tao Yang ◽  
Yaobin Li ◽  
Shiguo Han ◽  
Yi Liu ◽  
Zhiyun Xu ◽  
...  

We present a new 2D hybrid perovskite by alloying secondary dimethylammonium cation as the “perovskiter” into the PbI3 framework, which shows the strong in-plane photoresponses.


Author(s):  
Yu Ma ◽  
Jiaqi Wang ◽  
Yi Liu ◽  
Shiguo Han ◽  
Yaobin Li ◽  
...  

Self-powered photodetection with an extremely low detection limit of 82 nW cm−2 is achieved in a 2D hybrid perovskite ferroelectric. This result sheds light on future advances of ferroelectrics toward smart optoelectronic device applications.


2019 ◽  
Vol 75 (3) ◽  
pp. 354-358 ◽  
Author(s):  
Ling Cheng ◽  
Yingjie Cao

Recently, with the prevalence of `perovskite fever', organic–inorganic hybrid perovskites (OHPs) have attracted intense attention due to their remarkable structural variability and highly tunable properties. In particular, the optical and electrical properties of organic–inorganic hybrid lead halides are typical of the OHP family. Besides, although three-dimensional hybrid perovskites, such as [CH3NH3]PbX 3 (X = Cl, Br or I), have been reported, the development of new organic–inorganic hybrid semiconductors is still an area in urgent need of exploration. Here, an organic–inorganic hybrid lead halide perovskite is reported, namely poly[(2-azaniumylethyl)trimethylphosphanium [tetra-μ-bromido-plumbate(II)]], {(C5H16NP)[PbBr4]} n , in which an organic cation is embedded in inorganic two-dimensional (2D) mesh layers to produce a sandwich structure. This unique sandwich 2D hybrid perovskite material shows an indirect band gap of ∼2.700 eV. The properties of this compound as a semiconductor are demonstrated by a series of optical characterizations and indicate potential applications for optical devices.


Author(s):  
beibei wang ◽  
Huaixi Chen ◽  
Wuqian Guo ◽  
Yi Liu ◽  
Shiguo Han ◽  
...  

Two-dimensional (2D) Ruddlesden-Popper hybrid perovskites (RPHPs) have shown enormous potentials for photoelectric applications, owing to their advantages of structural diversity and unique physical properties. Despite extensive studies, the cage-incorporation of...


2020 ◽  
Vol 2 (2) ◽  
Author(s):  
Misaki Ozawa ◽  
Ludovic Berthier ◽  
Giulio Biroli ◽  
Gilles Tarjus
Keyword(s):  

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