Effects of antiferroelectric substitution on the structure and ferroelectric properties of a complex perovskite solid solution

Novel ferro-/piezoelectric solid solutions between bismuth-based perovskite and antiferroelectric material are designed and synthesized and their crystal structure, phase transitions, ferro-/piezoelectric properties and local polar structure are investigated.

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ChemInform Abstract: Crystal Structure, Phase Transitions and Mechanical Properties of Solid Solutions Based on GeTe in Systems GeTe-PbTe-MTe (M: Mn, Sc, La)

ChemInform ◽

10.1002/chin.199416019 ◽

2010 ◽

Vol 25 (16) ◽

pp. no-no

Author(s):

L. E. SHELIMOVA ◽

O. G. KARPINSKII ◽

E. S. AVILOV ◽

M. A. KRETOVA

Keyword(s):

Crystal Structure ◽

Mechanical Properties ◽

Phase Transitions ◽

Solid Solutions ◽

Structure Phase

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Crystal structure phase transitions and a vibrational study of disordered solid solution

Journal of Physics Condensed Matter ◽

10.1088/0953-8984/10/37/010 ◽

1998 ◽

Vol 10 (37) ◽

pp. 8235-8245 ◽

Cited By ~ 6

Author(s):

M Gargouri ◽

R Ben Hassen ◽

T Mhiri ◽

A Daoud

Keyword(s):

Crystal Structure ◽

Solid Solution ◽

Phase Transitions ◽

Vibrational Study ◽

Structure Phase

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Electrical Conductivity and Phase Transitions in Ferroelectric Solid Solutions Li0.17Na0.83ТауNb1-уO3 (y = 0 – 0.5) in High Pressure

Solid State Phenomena ◽

10.4028/www.scientific.net/ssp.310.6 ◽

2020 ◽

Vol 310 ◽

pp. 6-13

Author(s):

Vadim V. Efremov ◽

Mikhail N. Palatnikov ◽

Yuriy V. Radyush ◽

Olga B. Shcherbina

Keyword(s):

Solid Solution ◽

Electrical Conductivity ◽

High Pressure ◽

Phase Transitions ◽

Solid Solutions ◽

Synthesis Method ◽

Ferroelectric Ceramic ◽

Synthesis Temperature ◽

Structure Phase ◽

Ceramic Solid Solution

Ferroelectric ceramic solid solutions LixNa1-xTayNb1-yO3 (х = 0.17; у = 0 – 0.5) with the perovskite structure have been obtained by the thermobaric synthesis method. Particularities of their microstructure, elastic properties, electrical conductivity and permittivity have been researched. It has been established that an increase in the thermobaric synthesis temperature leads to a decrease in the Young’s modulus value. Specific static conductivity values have been determined; charge carrier activation enthalpies На have been calculated. The Curie temperature of the samples has been determined to decrease with an increase in tantalum content. A Ferroelectric ceramic solid solution Li0.17Na0.83Ta0.1Nb0.9O3 was shown to undergo four structure phase transitions in the temperature range 300-820 К. A Li0.17Na0.83Ta0.1Nb0.9O3 has been shown to be a high temperature superionic. Possible mechanisms of the detected phenomena are discussed.

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Doping Strategies of Bi (Ti0.5Ni0.5)O3 for Increased Performance in BiFeO3

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.1004-1005.358 ◽

2014 ◽

Vol 1004-1005 ◽

pp. 358-361

Author(s):

Zheng Zheng Ma ◽

Jian Qing Li ◽

Zi Peng Chen ◽

Xiao Jun Hu

Keyword(s):

Crystal Structure ◽

Solid Solution ◽

Magnetic Properties ◽

Solid Solutions ◽

Perovskite Structure ◽

Room Temperature ◽

Ferroelectric Properties ◽

Hysteresis Loops ◽

Space Group ◽

Substituted 1

Investigation of crystal structure, dielectric, magnetic and local ferroelectric properties of the diamagnetically substituted (1-x)BiFeO3-xBi (Ti0.5Ni0.5)O3solid solutions samples have been carried out. The solid solutions have been found to possess a rhombohedrally distorted perovskite structure described by the space group R3c. Compared with pure BiFeO3compound, both ferroelectric and magnetic properties are much improved by solid solution with Bi (Ti0.5Ni0.5)O3with saturation hysteresis loops observed. Among all the samples, thex=0.1 samples shows the optimal ferromagnetism with Mr~0.56531emμ/g and the optimal ferroelectricity with Pr~5.767μC/cm2 at room temperature.

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Structure and local polar domains of Dy-modified BiFeO3–PbTiO3 multiferroic solid solutions

Journal of Materials Chemistry C ◽

10.1039/c5tc02289d ◽

2015 ◽

Vol 3 (48) ◽

pp. 12450-12456 ◽

Cited By ~ 13

Author(s):

Jian Zhuang ◽

Jingyan Zhao ◽

Lun-Wei Su ◽

Hua Wu ◽

Alexei A. Bokov ◽

...

Keyword(s):

Crystal Structure ◽

Phase Transition ◽

Phase Diagram ◽

Solid Solution ◽

Solid Solutions ◽

Room Temperature ◽

Ferroelectric Phase ◽

Phase Transition Behavior ◽

Structure Phase ◽

Structure Phase Transition

Based on the detailed investigations of the crystal structure, phase transition behavior and local polar domains, a ferroelectric phase diagram is established in this study for the room-temperature multiferroic Dy-modified BiFeO3–PbTiO3 solid solution.

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