Evaluation of the Pr + O → PrO+ + e− chemi-ionization reaction enthalpy and praseodymium oxide, carbide, dioxide, and carbonyl cation bond energies

2021 ◽  
Vol 23 (4) ◽  
pp. 2938-2952
Author(s):  
Maryam Ghiassee ◽  
Brandon C. Stevenson ◽  
P. B. Armentrout

Guided ion beam tandem mass spectrometry was used to measure the kinetic energy dependent product ion cross sections for reactions of the lanthanide metal praseodymium cation (Pr+) with O2, CO2, and CO and reactions of PrO+ with CO, O2, and Xe.

2002 ◽  
Vol 117 (1) ◽  
pp. 132-141 ◽  
Author(s):  
Fuyi Liu ◽  
Rohana Liyanage ◽  
P. B. Armentrout

2016 ◽  
Vol 144 (18) ◽  
pp. 184309 ◽  
Author(s):  
Richard M Cox ◽  
Murat Citir ◽  
P. B. Armentrout ◽  
Samuel R. Battey ◽  
Kirk A. Peterson

2016 ◽  
Vol 48 (3) ◽  
pp. 379-386
Author(s):  
Zeljka Nikitovic ◽  
Martina Gilic ◽  
Milica Petrovic ◽  
Nebojsa Romcevic ◽  
Zoran Raspopovic ◽  
...  

In this work we select most probable reactions of alkali metal ion Na+ with dimethoxyethane (DXE) molecule. Appropriate gas phase enthalpies of formation for the products were used to calculate scattering cross section as a function of kinetic energy with Denpoh-Nanbu theory. Calculated cross sections were compared with existing experimental results obtained by guided ion beam tandem mass spectrometry. Three body association reactions of ions with DXE is studied and compared to experimental results. Calculated cross sections were used to obtain transport parameters for alkali metal ion in DXE gas.


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