Experimental investigations on the irregular synthesis of the iron(III) terephthalate metal-organic frameworks MOF-235 and MIL-101

Experimental Investigations ◽

Surface Areas ◽

(Fe)-MOF-235 and (Fe)-MIL-101 are two well-studied iron(III) terephthalate metal-organic frameworks (MOFs) with dissimilar crystal structures and topologies. Previously reported syntheses of the former show greatly varying surface areas, indicating a...

Negative linear compressibility in nanoporous metal-organic frameworks rationalized by the empty channel structural mechanism

Physical Chemistry Chemical Physics ◽

10.1039/d1cp00214g ◽

2021 ◽

Author(s):

Francisco Colmenero

Keyword(s):

Crystal Structures ◽

Structural Mechanism ◽

Nanoporous Metal ◽

Metal Organic ◽

Linear Compressibility

Cobalt squarate hydroxide (Co3(C4O4)2(OH)2), zinc squarate tetrahydrate (ZnC4O4·4 H2O) and titanium oxalate trioxide dihydrate (Ti2(C2O4)O3·2 H2O) are nanoporous metal-organic frameworks possessing empty channels in their crystal structures. The crystal structures...

Lanthanide-Based Metal–Organic Frameworks Containing “V-Shaped” Tetracarboxylate Ligands: Synthesis, Crystal Structures, “Naked-Eye” Luminescent Detection, and Catalytic Properties

Inorganic Chemistry ◽

10.1021/acs.inorgchem.9b02177 ◽

2019 ◽

Vol 59 (1) ◽

pp. 264-273 ◽

Cited By ~ 11

Author(s):

Pengyan Wu ◽

Lingling Xia ◽

Mengjie Huangfu ◽

Fubin Fu ◽

Mengqiu Wang ◽

...

Keyword(s):

Crystal Structures ◽

Catalytic Properties ◽

Naked Eye ◽

Stabilization of Metal−Organic Frameworks with High Surface Areas by the Incorporation of Mesocavities with Microwindows

Journal of the American Chemical Society ◽

10.1021/ja901109t ◽

2009 ◽

Vol 131 (26) ◽

pp. 9186-9188 ◽

Cited By ~ 269

Author(s):

Dan Zhao ◽

Daqiang Yuan ◽

Daofeng Sun ◽

Hong-Cai Zhou

Keyword(s):

High Surface ◽

Surface Areas ◽

Construction of a series of metal–organic frameworks based on novel flexible ligand 4-carboxy-1-(3,5-dicarboxy-benzyl)-pyridinium chloride and selective d-block metal ions: crystal structures and photoluminescence

CrystEngComm ◽

10.1039/c5ce01008j ◽

2015 ◽

Vol 17 (33) ◽

pp. 6297-6307 ◽

Cited By ~ 19

Author(s):

Hai-Yang Li ◽

Li-Hui Cao ◽

Yong-Li Wei ◽

Hong Xu ◽

Shuang-Quan Zang

Keyword(s):

Metal Ions ◽

Crystal Structures ◽

Pyridinium Chloride ◽

Flexible Ligand ◽

Four unprecedented cobalt(II) and cadmium(II) metal-organic frameworks based on a rigid tricarboxylate ligand: Synthesis, crystal structures, magnetic and fluorescence properties

Journal of Molecular Structure ◽

10.1016/j.molstruc.2017.12.027 ◽

2018 ◽

Vol 1156 ◽

pp. 583-591 ◽

Cited By ~ 6

Author(s):

Yaru Liu ◽

Lan Liu ◽

Xiao Zhang ◽

Jie Wu

Keyword(s):

Crystal Structures ◽

Fluorescence Properties ◽

Metal Organic ◽

Ligand Synthesis

Synthesis and Characterization of New Metal–Organic Frameworks Based on Tetracyanoplatinate(II) and N,N′-bis(2-hydroxyethyl)ethylenediamine: Single Crystal Structures of ZnII and CdII Complexes Along with Magnetic Properties of NiII and CuII Complexes

Journal of Inorganic and Organometallic Polymers and Materials ◽

10.1007/s10904-011-9466-x ◽

2011 ◽

Vol 21 (3) ◽

pp. 438-449 ◽

Cited By ~ 9

Author(s):

Ayşegül Şenocak ◽

Ahmet Karadağ ◽

Ertan Şahin ◽

Yusuf Yerli

Keyword(s):

Magnetic Properties ◽

Single Crystal ◽

Crystal Structures ◽

Synthesis And Characterization ◽

Single Crystal Structures ◽

Four three-dimensional metal–organic frameworks assembled from 1H-tetrazole: Synthesis, crystal structures and thermal properties

Polyhedron ◽

10.1016/j.poly.2018.12.035 ◽

2019 ◽

Vol 160 ◽

pp. 198-206 ◽

Cited By ~ 2

Author(s):

Xuemin Hou ◽

Zhaoqi Guo ◽

Liqiang Yang ◽

Haixia Ma

Keyword(s):

Thermal Properties ◽

Crystal Structures ◽

Three Dimensional ◽

Mixed-ligand strategy affording two 6-connected 3-fold interpenetrated metal-organic frameworks with binuclear CoII2/NiII2 subunits: Synthesis, crystal structures and magnetic properties

Inorganic Chemistry Communications ◽

10.1016/j.inoche.2019.107624 ◽

2020 ◽

Vol 111 ◽

pp. 107624 ◽

Cited By ~ 4

Author(s):

Jie Zhou ◽

Zhen Zhang ◽

Ling-Feng Xu ◽

Run-Jiao Li ◽

Rui-Dan Bao ◽

...

Keyword(s):

Magnetic Properties ◽

Crystal Structures ◽

Mixed Ligand ◽

Reticular Chemistry and Metal-Organic Frameworks for Clean Energy

MRS Bulletin ◽

10.1557/mrs2009.180 ◽

2009 ◽

Vol 34 (9) ◽

pp. 682-690 ◽

Cited By ~ 64

Author(s):

Omar M. Yaghi ◽

Qiaowei Li

Keyword(s):

Carbon Dioxide ◽

Clean Energy ◽

Building Blocks ◽

Zeolitic Imidazolate Frameworks ◽

Design Concepts ◽

Surface Areas ◽

Molecular Building Blocks ◽

Metal Organic ◽

Molecular Aspects

AbstractReticular chemistry concerns the linking of molecular building blocks into predetermined structures using strong bonds. We have been working on creating and developing the conceptual and practical basis of this new area of research. As a result, new classes of crystalline porous materials have been designed and synthesized: metal-organic frameworks, zeolitic imidazolate frameworks, and covalent organic frameworks. Crystals of this type have exceptional surface areas (2,000−6,000 m2/g) and take up voluminous amounts of hydrogen (7.5 wt% at 77 K and 3−4 × 106 Pa), methane (50 wt% at 298 K and 2.5 × 106 Pa), and carbon dioxide (140 wt% at 298 K and 3 × 106 Pa). We have driven the basic science all the way to applications without losing sight of our quest for understanding the underlying molecular aspects of this chemistry. The presentation was focused on the design concepts, synthesis, and structure of these materials, with emphasis on their applications to onboard energy storage.