scholarly journals Rapid production of block copolymer nano-objects via continuous-flow ultrafast RAFT dispersion polymerisation

2020 ◽  
Vol 11 (20) ◽  
pp. 3465-3474
Author(s):  
Sam Parkinson ◽  
Stephen T. Knox ◽  
Richard A. Bourne ◽  
Nicholas J. Warren

Continuous-flow reactors are exploited for conducting ultrafast RAFT dispersion polymerisation for the preparation of diblock copolymer nanoparticles.

2020 ◽  
Vol 11 (44) ◽  
pp. 7094-7103
Author(s):  
Kirsten Verstraete ◽  
Neomy Zaquen ◽  
Tanja Junkers

Low dispersity poly[2-methoxy-5-(3′,7′-dimethyloctyloxy)]-1,4-phenylenevinylene (MDMO-PPV) with well-defined end-groups is made available by performing the anionic polymerization in a continuous tubular reactor under flash chemistry conditions.


2012 ◽  
Vol 14 (1) ◽  
pp. 38-54 ◽  
Author(s):  
Charlotte Wiles ◽  
Paul Watts

Author(s):  
Xabier Lopez de Pariza ◽  
Tim Erdmann ◽  
Pedro L. Arrechea ◽  
Leron Perez ◽  
Charles Dausse ◽  
...  

2021 ◽  
Vol 25 ◽  
Author(s):  
Alexander Leslie ◽  
Angel Maria Joseph ◽  
Marcus Baumann

: An overview of the current uptake of continuous flow techniques for various functional group interconversion reactions is presented. Besides highlighting a variety of prominent examples and their main features, this review provides insights into specific reaction classes, such as oxidations, reductions, rearrangements as well as different C-H functionalization processes. While this review can only include key examples from the last decade, the reader will find a solid foundation of important transformations along with further references to inform and appreciate the opportunities arising from modern synthesis technologies such as flow synthesis.


2017 ◽  
Vol 8 (42) ◽  
pp. 6496-6505 ◽  
Author(s):  
Maarten Rubens ◽  
Phanumat Latsrisaeng ◽  
Tanja Junkers

Visible-light induced photoiniferter polymerization in continuous flow reactors is very efficient in yielding low dispersity methacrylate block copolymers.


2017 ◽  
Vol 13 ◽  
pp. 120-126 ◽  
Author(s):  
Christian H Hornung ◽  
Miguel Á Álvarez-Diéguez ◽  
Thomas M Kohl ◽  
John Tsanaktsidis

This work describes the Diels–Alder reaction of the naturally occurring substituted butadiene, myrcene, with a range of different naturally occurring and synthetic dienophiles. The synthesis of the Diels–Alder adduct from myrcene and acrylic acid, containing surfactant properties, was scaled-up in a plate-type continuous-flow reactor with a volume of 105 mL to a throughput of 2.79 kg of the final product per day. This continuous-flow approach provides a facile alternative scale-up route to conventional batch processing, and it helps to intensify the synthesis protocol by applying higher reaction temperatures and shorter reaction times.


2017 ◽  
Vol 7 (1) ◽  
pp. 84-89 ◽  
Author(s):  
Ajay A. Sathe ◽  
Anirudh M. K. Nambiar ◽  
Robert M. Rioux

The direct catalytic conversion of olefins into cyclic carbonates using peroxide and carbon dioxide is demonstrated using continuous flow reactors.


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