scholarly journals Sequence-defined l-glutamamide oligomers with pendant supramolecular motifs via iterative synthesis and orthogonal post-functionalization

2020 ◽  
Vol 11 (46) ◽  
pp. 7393-7401
Author(s):  
Marcin L. Ślęczkowski ◽  
Ian Segers ◽  
Yiliu Liu ◽  
Anja R. A. Palmans

One of the great challenges in polymer chemistry is to achieve discrete and sequence-defined synthetic polymers that fold in defined conformations and form well-defined three-dimensional structured particles.

Chemistry ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 164-181
Author(s):  
Joyita Sarkar ◽  
Swapnil C. Kamble ◽  
Nilambari C. Kashikar

Three-dimensional (3D) printing techniques have revolutionized the field of tissue engineering. This is especially favorable to construct intricate tissues such as liver, as 3D printing allows for the precise delivery of biomaterials, cells and bioactive molecules in complex geometries. Bioinks made of polymers, of both natural and synthetic origin, have been very beneficial to printing soft tissues such as liver. Using polymeric bioinks, 3D hepatic structures are printed with or without cells and biomolecules, and have been used for different tissue engineering applications. In this review, with the introduction to basic 3D printing techniques, we discuss different natural and synthetic polymers including decellularized matrices that have been employed for the 3D bioprinting of hepatic structures. Finally, we focus on recent advances in polymeric bioinks for 3D hepatic printing and their applications. The studies indicate that much work has been devoted to improvising the design, stability and longevity of the printed structures. Others focus on the printing of tissue engineered hepatic structures for applications in drug screening, regenerative medicine and disease models. More attention must now be diverted to developing personalized structures and stem cell differentiation to hepatic lineage.


2014 ◽  
pp. 1-31 ◽  
Author(s):  
Ortensia Ilaria Parisi ◽  
Manuela Curcio ◽  
Francesco Puoci

2017 ◽  
Vol 2017 (14) ◽  
pp. 2079-2079
Author(s):  
Ravi Shankar ◽  
Rohit Singh ◽  
Swati Mendiratta ◽  
Amanpreet Kaur Jassal ◽  
Gabriele Kociok-Köhn ◽  
...  

2017 ◽  
Vol 2017 (14) ◽  
pp. 2081-2087 ◽  
Author(s):  
Ravi Shankar ◽  
Rohit Singh ◽  
Swati Mendiratta ◽  
Amanpreet Kaur Jassal ◽  
Gabriele Kociok-Köhn ◽  
...  

2017 ◽  
Vol 2017 (14) ◽  
pp. 2080-2080
Author(s):  
Ravi Shankar ◽  
Rohit Singh ◽  
Swati Mendiratta ◽  
Amanpreet Kaur Jassal ◽  
Gabriele Kociok-Köhn ◽  
...  

2020 ◽  
Vol 20 (4) ◽  
pp. 175-205
Author(s):  
Aigul S. Istomina ◽  
◽  
Olga V. Bushkova ◽  

The second part of the review describes the prospects of using alternative polymer binders for composite electrodes of lithium electrochemical systems. Possible options having been taken into account, the most popular commercially-available synthetic polymers with functional group (the ones forming aqueous solutions or dispersions predominantly) and water-soluble polymers of natural origin are considered. The versatility of such materials is their distinctive feature. The availability of salt forms for natural and synthetic polymers, many of which are polyelectrolytes, makes it possible to significantly affect the ion transfer in the composite electrode mass, reducing the polarization of the electrodes and improving the power characteristics of batteries. The ability to form “artificial SEI” and / or form a three-dimensional network with self-healing cross-links between macromolecules allows long-term safe cycling, the latter being especially important for active materials with very large volume changes during lithium intercalation / deintercalation (e.g. silicon).


Biomimetics ◽  
2021 ◽  
Vol 6 (4) ◽  
pp. 71
Author(s):  
Léna Ciffréo ◽  
Claire Marchand ◽  
Caroline R. Szczepanski ◽  
Marie-Gabrielle Medici ◽  
Guilhem Godeau

Desertification is a growing risk for humanity. Studies show that water access will be the leading cause of massive migration in the future. For this reason, significant research efforts are devoted to identifying new sources of water. Among this work, one of the more interesting strategies takes advantage of atmospheric non-liquid water using water harvesting. Various strategies exist to harvest water, but many suffer from low yield. In this work, we take inspiration from a Mexican plant (Echeveria pulvinate) to prepare a material suitable for future water harvesting applications. Observation of E. pulvinate reveals that parahydrophobic properties are favorable for water harvesting. To mimic these properties, we leveraged a combination of 3D printing and post-functionalization to control surface wettability and obtain parahydrophobic properties. The prepared surfaces were investigated using IR and SEM. The surface roughness and wettability were also investigated to completely describe the elaborated surfaces and strongly hydrophobic surfaces with parahydrophobic properties are reported. This new approach offers a powerful platform to develop parahydrophobic features with desired three-dimensional shape.


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