Highly efficient synergistic CO2 conversion with epoxide using copper polyhedron-based MOFs with Lewis acid and base sites

2020 ◽  
Vol 7 (22) ◽  
pp. 4517-4526
Author(s):  
Jiaming Gu ◽  
Xiaodong Sun ◽  
Xinyao Liu ◽  
Yang Yuan ◽  
Hongyan Shan ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Cycloaddition Reaction ◽  
Catalytic Efficiency ◽  
Co2 Conversion ◽  
Highly Efficient ◽  
Acid And Base ◽  
Catalytic Stability ◽  
Lewis Acid And Base ◽  
Catalytic Performances

The catalytic performances and effect of LASs and LBSs of four isomorphous Cu-PMOFs in CO2 cycloaddition reaction were systematically studied. JLU-Liu21 exhibited significant catalytic efficiency, remarkable recyclability and catalytic stability.

scholarly journals Lewis acid / Base-free Strategy for the Synthesis of 2-Arylthio and Selenyl Benzothiazole / Thiazole and Imidazole

2021 ◽  
Vol 27 (1) ◽  
pp. 17-23
Author(s):  
Guniganti Balakishan ◽  
Gullapalli Kumaraswamy ◽  
Vykunthapu Narayanarao ◽  
Pagilla Shankaraiah
Keyword(s):  
Lewis Acid ◽  
Bond Formation ◽  
Acid Base ◽  
Mechanistic Pathway ◽  
Wide Range ◽  
Acid And Base ◽  
Lewis Acid And Base ◽  
Sulfur Bond

Abstract A Cu(II)-catalyzed Csp2-Se and Csp2-Sulfur bond formation was achieved with moderate to good yields without the aid of Lewis acid and base. The reaction is compatible with a wide range of heterocycles such as benzothiazole, thiazole, and imidazole. Also, this typical protocol is found to be active in thio-selenation via S-H activation. Additionally, we proposed a plausible mechanistic pathway involving Cu(III) putative intermediate.

Combined theoretical and experimental study on alcoholysis of amides on CeO2 surface: A catalytic interplay between Lewis acid and base sites

2018 ◽  
Vol 303 ◽  
pp. 256-262 ◽  
Author(s):  
Takashi Kamachi ◽  
S.M.A. Hakim Siddiki ◽  
Yoshitsugu Morita ◽  
Md. Nurnobi Rashed ◽  
Kenichi Kon ◽  
...  
Keyword(s):  
Experimental Study ◽  
Lewis Acid ◽  
Acid And Base ◽  
Lewis Acid And Base

Role of the Surface Lewis Acid and Base Sites in the Adsorption of CO2 on Titania Nanotubes and Platinized Titania Nanotubes: An in Situ FT-IR Study

2013 ◽  
Vol 117 (24) ◽  
pp. 12661-12678 ◽  
Author(s):  
Kaustava Bhattacharyya ◽  
Alon Danon ◽  
Baiju K.Vijayan ◽  
Kimberly A. Gray ◽  
Peter C. Stair ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Titania Nanotubes ◽  
Acid And Base ◽  
Ft Ir ◽  
Ir Study ◽  
Adsorption Of Co2 ◽  
Lewis Acid And Base

scholarly journals Ruthenium catalysis in organic synthesis

2002 ◽  
Vol 74 (1) ◽  
pp. 19-24 ◽  
Author(s):  
Shun-Ichi Murahashi ◽  
Hikaru Takaya ◽  
Takeshi Naota
Keyword(s):  
Organic Synthesis ◽  
Lewis Acid ◽  
Catalytic Reactions ◽  
Biologically Active ◽  
Hydride Complexes ◽  
Base Catalysts ◽  
Acid And Base ◽  
Ruthenium Catalysis ◽  
Lewis Acid And Base ◽  
Neutral Conditions

Ruthenium, rhodium, iridium, and rhenium hydride complexes are highly useful redox Lewis acid and base catalysts. Various substrates bearing hetero atoms are activated by these catalysts and undergo reactions with either nucleophiles or electrophiles under neutral conditions. These types of catalytic reactions are described together with their application to the preparation of various biologically active compounds.

Base-promoted Lewis acid catalyzed synthesis of quinazoline derivatives

2020 ◽  
Vol 18 (23) ◽  
pp. 4376-4380 ◽  
Author(s):  
Fang-Peng Hu ◽  
Xin-Feng Cui ◽  
Guo-Qiang Lu ◽  
Guo-Sheng Huang
Keyword(s):  
Lewis Acid ◽  
One Pot ◽  
Acid And Base ◽  
Quinazoline Derivatives ◽  
Acid Catalyzed ◽  
Lewis Acid And Base

A one-pot protocol has been developed for the synthesis of quinazolinones from amide-oxazolines with TsCl via a cyclic 1,3-azaoxonium intermediate and 6π electron cyclization in the presence of a Lewis acid and base.

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