A novel donor–π–acceptor halochromic 2,6-distyrylnaphthalene chromophore: synthesis, photophysical properties and DFT studies

A new pH-responsive fluorescence chromophore with white light emission at pH = 3 was synthesized which has high potential application in the preparation of high-performance lighting devices.

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Utilizing an effective framework to dye energy transfer in a carbazole-based metal–organic framework for high performance white light emission tuning

Inorganic Chemistry Frontiers ◽

10.1039/c8qi00747k ◽

2018 ◽

Vol 5 (11) ◽

pp. 2868-2874 ◽

Cited By ~ 13

Author(s):

Yu-Pei Xia ◽

Chen-Xue Wang ◽

Lian-Cai An ◽

Da-Shuai Zhang ◽

Tong-Liang Hu ◽

...

Keyword(s):

Energy Transfer ◽

White Light ◽

High Performance ◽

Light Emission ◽

Metal Organic Framework ◽

White Light Emission ◽

Transfer Mechanism ◽

Energy Transfer Mechanism ◽

Light Emitting ◽

Metal Organic

By introducing dyes into a MOF, a white-light-emitting luminophor was obtained based on effective framework to dye energy transfer mechanism.

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Secondary Through-Space Interactions: Achieving Single-Molecule White-Light Emission from Clusteroluminogens with Isolated Phenyl Rings

10.26434/chemrxiv-2022-6mctw ◽

2022 ◽

Author(s):

Jianyu Zhang ◽

Parvej Alam ◽

Siwei Zhang ◽

Hanchen Shen ◽

Lianrui Hu ◽

...

Keyword(s):

Single Molecule ◽

White Light ◽

Light Emission ◽

Photophysical Properties ◽

White Light Emission ◽

Excitation Wavelength ◽

Conjugated Molecules ◽

Long Wavelength ◽

Phenyl Rings ◽

Donor Acceptor

Clusteroluminogens (CLgens) refer to some non-conjugated molecules that show visible light due to the formation of aggregates and unique electronic properties with through-space interactions (TSI). Although mature and systematic theories of molecular photophysics have been developed to study conventional conjugated chromophores, it is still challenging to endow CLgens with designed photophysical properties by manipulating TSI. Herein, three CLgens with non-conjugated donor-acceptor structures and different halide substituents with secondary TSI are designed and synthesized. These molecules show multiple emissions and even white-light emission in the crystalline state and the intensity ratio of these multiple emission peaks is easily manipulated by changing the halide atom and excitation wavelength. Experimental and theoretical results successfully disclose the electronic nature of these multiple emissions: through-space conjugation for short-wavelength fluorescence, through-space charge transfer based on secondary TSI for long-wavelength fluorescence, and room-temperature phosphorescence. The introduction of secondary TSI to CLgens not only enriches their varieties of photophysical properties but also inspires the establishment of novel aggregate photophysics for clusteroluminescence.

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Indium-antimony-halide single crystals for high-efficiency white-light emission and anti-counterfeiting

Science Advances ◽

10.1126/sciadv.abg3989 ◽

2021 ◽

Vol 7 (34) ◽

pp. eabg3989

Author(s):

Jun-Hua Wei ◽

Jin-Feng Liao ◽

Lei Zhou ◽

Jian-Bin Luo ◽

Xu-Dong Wang ◽

...

Keyword(s):

Single Crystals ◽

White Light ◽

High Performance ◽

High Efficiency ◽

Light Emission ◽

Blue Emission ◽

White Light Emission ◽

Information Storage ◽

Yellow Emission ◽

Bright White Light

Although single-source white emissive perovskite has emerged as a class of encouraging light-emitting material, the synthesis of lead-free halide perovskite materials with high luminous efficiency is still challenging. Here, we report a series of zero-dimensional indium-antimony (In/Sb) alloyed halide single crystals, BAPPIn2–2xSb2xCl10 (BAPP = C10H28N4, x = 0 to 1), with tunable emission. In BAPPIn1.996Sb0.004Cl10, bright yellow emission with near 100% photoluminescence quantum yield (PLQY) is yielded when it was excited at 320 nm, which turns into bright white-light emission with a PLQY of 44.0% when excited at 365 nm. Combined spectroscopy and theoretical studies reveal that the BAPP4+-associated blue emission and inorganic polyhedron–afforded orange emission function as a perfect pair of complementary colors affording white light in BAPPIn1.996Sb0.004Cl10. Moreover, the interesting afterglow behavior, together with excitation-dependent emission property, makes BAPPIn2–2xSb2xCl10 as high-performance anti-counterfeiting/information storage materials.

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Highly efficient white-light emission in a polar two-dimensional hybrid perovskite

Chemical Communications ◽

10.1039/c8cc01663a ◽

2018 ◽

Vol 54 (32) ◽

pp. 4053-4056 ◽

Cited By ~ 44

Author(s):

Sasa Wang ◽

Yunpeng Yao ◽

Jintao Kong ◽

Sangen Zhao ◽

Zhihua Sun ◽

...

Keyword(s):

Solid State ◽

White Light ◽

Potential Application ◽

Nonlinear Optical ◽

Light Emission ◽

White Light Emission ◽

Two Dimensional ◽

Optical Effect ◽

Nonlinear Optical Effect ◽

Hybrid Perovskite

A polar two-dimensional hybrid perovskite showing efficient white-light emission and a nonlinear optical effect suggests potential application in solid-state optics.

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Photophysical properties of acid-responsive triphenylamine derivatives bearing pyridine fragments: Towards white light emission

Dyes and Pigments ◽

10.1016/j.dyepig.2017.07.043 ◽

2017 ◽

Vol 146 ◽

pp. 467-478 ◽

Cited By ~ 26

Author(s):

Jiří Tydlitát ◽

Sylvain Achelle ◽

Julián Rodríguez-López ◽

Oldřich Pytela ◽

Tomáš Mikýsek ◽

...

Keyword(s):

White Light ◽

Light Emission ◽

Photophysical Properties ◽

White Light Emission

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Photophysical properties of organogold(i) complexes bearing a benzothiazole-2,7-fluorenyl moiety: selection of ancillary ligand influences white light emission

Dalton Transactions ◽

10.1039/c9dt02312g ◽

2019 ◽

Vol 48 (42) ◽

pp. 15917-15927 ◽

Cited By ~ 9

Author(s):

Joseph J. Mihaly ◽

David J. Stewart ◽

Tod A. Grusenmeyer ◽

Alexis T. Phillips ◽

Joy E. Haley ◽

...

Keyword(s):

White Light ◽

Light Emission ◽

Photophysical Properties ◽

White Light Emission ◽

Ancillary Ligand ◽

Ancillary Ligands ◽

Selection Of

Herein we report three new gold(i) complexes with a benzothiazole-2,7-fluorenyl moiety bound through a gold–carbon σ-bond and either an N-heterocyclic carbene or organophosphine as ancillary ligands.

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Molecular Conformational Twist Controlled Wide Fluorescence Tuning and White Light Emission in a Single Fluorophore via Halochromism

New Journal of Chemistry ◽

10.1039/d1nj04911a ◽

2021 ◽

Author(s):

Parthasarathy Gayathri ◽

Probal Nag ◽

Neethu Anand ◽

Vennapusa Sivaranjana Reddy ◽

Mehboobali Pannippara ◽

...

Keyword(s):

Single Molecule ◽

White Light ◽

Light Emission ◽

White Light Emission ◽

Ph Responsive ◽

Donor Acceptor

pH responsive fluorescence molecules are interesting candidates for achieving tunable as well as white light emission from single molecule. Herein we have synthesized pyridine integrated carbazole and triphenylamine donor-acceptor isomers,...

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