scholarly journals Porous MOF-808@PVDF beads for removal of iodine from gas streams

RSC Advances ◽  
2020 ◽  
Vol 10 (73) ◽  
pp. 44679-44687
Author(s):  
Lingyu Wang ◽  
Peng Chen ◽  
Xiuting Dong ◽  
Wen Zhang ◽  
Song Zhao ◽  
...  

Porous millimeter-sized MOF-808@PVDF composite beads with ultrahigh iodine adsorption capacity for capture of radioiodine from gas streams.

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2309
Author(s):  
Po-Hsiang Tang ◽  
Pamela Berilyn So ◽  
Kueir-Rarn Lee ◽  
Yu-Lun Lai ◽  
Cheng-Shiuan Lee ◽  
...  

A variety of metal organic frameworks (MOFs) were synthesized and evaluated for their iodine adsorption capacity. Out of the MOFs tested, ZIF-8 showed the most promising result with an iodine vapor uptake of 876.6 mg/g. ZIF-8 was then incorporated into a polymer, polyethersulfone (PES), at different proportions to prepare mixed matrix membranes (MMMs), which were then used to perform further iodine adsorption experiments. With a mixing ratio of 40 wt % of ZIF-8, the iodine adsorption capacity reached 1387.6 mg/g, wherein an astounding 60% improvement in adsorption was seen with the MMMs prepared compared to the original ZIF-8 powder.


Author(s):  
Dayin Tong ◽  
Yaolin Zhao ◽  
Zhongcun Chen ◽  
Yuqi Wang ◽  
Ziqi Jia ◽  
...  

COF-DL229 is one of the promising sorbents towards the capture of volatile radioiodine due to its large adsorption capacity. However, the interaction mechanism between them remains unclear. In the present...


2018 ◽  
Vol 54 (61) ◽  
pp. 8450-8453 ◽  
Author(s):  
Shaohui Xiong ◽  
Jian Tao ◽  
Yuanyuan Wang ◽  
Juntao Tang ◽  
Cheng Liu ◽  
...  

The iodine adsorption capacity of porous organic polymers is greatly enhanced due to the extended π-conjugated units on the backbone.


2016 ◽  
Vol 10 (1) ◽  
pp. 24-35
Author(s):  
Haspiadi Haspiadi

Solid waste of Palm kernel cake (PKC) is a by product of oil extraction from palm nut pose a serious environmental problem in some factories of Palm Kernel Oil (PKO. Thererfore the research about utilization of palm kernel cake solid waste (PKC) as a source of activated carbon was performed. From this research is to know quality of activated carbon using palm kernel cake as a row material to compare with the SNI 06-3730-1995. The process was carried out is chemical activation method with in laboratory scale using two types activator, which is phosphoric acid and potassium hydroxide at six different concentration 2%, 4%, 6%, 8%, 10% and 12% respectively. Whereas, carbonization was held at temperature of 400oC during 120 minutes. The result indicated that the quality of activated carbon according to key parameters using  the lowest concentration of  activator fulfilling with SNI 06-3730-1995 was produced by H3PO4 6%  with iodine adsorption capacity 769 mg/g. Meanwhile for activator KOH 10% according to key parameters using  the lowest concentration of  activator fulfilling with SNI 06-3730-1995 was produced by with condition of iodine adsorption capacity 778 mg/gABSTAKLimbah padat palm kernel cake (PKC) yang dihasilkan dari proses ekstraksi kernel merupakan permasalahan lingkungan yang serius dibeberapa industri yang mengolah Palm Kernel Oil (PKO). Oleh karena itu dilakukan penelitian untuk memanfaatkan limbah padat Palm Kernel Cake (PKC) sebagai sumber karbon aktif. Diharapkan dari penelitian ini dapat diketahui mutu karbon aktif yang dihasilkan dibandingkan dengan SNI 06 3730-1995. Proses pengolahan yang dilakukan secara kimia dalam skala laboratorium, menggunakan dua jenis aktivator yaitu H3PO4 dan KOH dengan konsentrasi 2%, 4%, 6%, 8%, 10% dan 12%. Karbonisasi dilakukan pada suhu 400 oC selama 120 menit. Hasil uji mutu karbon aktif yang dihasilkan berdasarkan parameter kunci dengan pertimbangan penggunaan bahan kimia dengan konsentrasi aktivator terkecil menunjukkan bahwa pengggunaan aktivator 6% H3PO4  memiliki daya serap terhadap iod sebesar (I2) 769 mg/g, bila dibandingkan dengan SNI 06 3730-1995 telah dapat memenuhi syarat mutu. Sedangkan penggunaan aktivator KOH 10%  dengan pertimbangan penggunaan bahan kimia dengan konsentrasi aktivator terkecil memiliki daya serap terhadap iod sebesar 778 mg/g. Kata kunci :  asam fosfat, kalium hidroksida, karbon aktif, limbah padat, daya serap iod, palm kernel cake


2013 ◽  
Vol 2013 ◽  
pp. 1-11 ◽  
Author(s):  
S. Sugashini ◽  
K. M. Meera Sheriffa Begum

The objective of this present study is the optimization of process parameters in adsorption of Cr(VI) ions by ethylamine modified chitosan carbonized rice husk composite beads (EAM-CCRCBs) using response surface methodology (RSM) and continuous adsorption studies of Cr(VI) ions by ethylamine modified chitosan carbonized rice husk composite beads (EAM-CCRCBs). The effect of process variables such as initial metal ion concentration, adsorbent dosage and pH were optimized using RSM in order to ensure high adsorption capacity at low adsorbent dosage and high initial metal ion concentration of Cr(VI) in batch process. The optimum condition suggested by the model for the process variable such as adsorbent dosage, pH and initial metal ion concentration was 0.14 g, 300 mg/L and pH2 with maximum removal of 99.8% and adsorption capacity of 52.7 mg/g respectively. Continuous adsorption studies were conducted under optimized initial metal ion concentration and pH for the removal of Cr(VI) ions using EAM-CCRCBs. The breakthrough curve analysis was determined using the experimental data obtained from the continuous adsorption. Continuous adsorption modelling such as bed depth service model and Thomson model were established by fitting it with experimental data.


Author(s):  
H. Lu ◽  
F. Luo ◽  
Q. Zhang ◽  
J. Li ◽  
L. Cai

To understand the features and best preparation of sludge activated carbon (SAC), and the pore structure, component, adsorption characteristics, and the yield rate of SAC, many tests have been carried out. The study illustrated that the pore structure was mostly mesopore and amorphous pore such as the ink bottle hole. In terms of different preparations to obtain SAC, the yield of SAC in sample No.1 achieved 88.09%. Using the preparation of ZnCl2 as an activator, the iodine adsorption value was significantly higher than other preparations. However, the content of quartz in sample No.1 achieved a maximum of 52.51%. Charcoal was detected in all samples except sample nos 9-12. The adsorption capacity of Cu(II) and Cd(II) reached a maximum of 600.02 mg.kg-1 and 383.2 mg.kg-1. The results showed an optimum preparation condition, which was by using the ZnCl2 as an activator, 2:1 as the impregnated ratio, 40% concentration in activator and at 400ºC reaction temperature could create rich pore structure and charcoal inside.


2019 ◽  
Vol 7 (21) ◽  
pp. 13173-13179 ◽  
Author(s):  
Bingbing Guo ◽  
Fugang Li ◽  
Chiming Wang ◽  
Liangliang Zhang ◽  
Daofeng Sun

We synthesized a rare (3,12)-connected zirconium metal–organic framework with a sky topology showing efficient iodine adsorption and pH sensing capacity.


2020 ◽  
Vol 49 (10) ◽  
pp. 1163-1166
Author(s):  
Pu Huang ◽  
Guozong Yue ◽  
Jiazhou Chen ◽  
Jinfan Chen ◽  
Xiaojiao Yang ◽  
...  

2013 ◽  
Vol 712-715 ◽  
pp. 527-530
Author(s):  
Jing Wen Xue

Corncob xylitol residue was soaked with H3PO4 for 16h and carbonized in microwave for 9min to obtain activated carbon. Methylene blue and iodine adsorption values were determined and were 119.92mg/g and 839.47mg/g, respectively. The adsorption property on Cr6+ was determined and the proper adsorption condition was pH2, 30min, 80°C. The maximum Cr adsorption capacity was 50mg/g.


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