A soluble iron(ii)-phthalocyanine-catalyzed intramolecular C(sp3)–H amination with alkyl azides

2021 ◽  
Vol 57 (82) ◽  
pp. 10711-10714
Author(s):  
Tingjie You ◽  
Si-Hao Zeng ◽  
Jianqiang Fan ◽  
Liangliang Wu ◽  
Fangyuan Kang ◽  
...  
Keyword(s):  
Effective Catalyst ◽  
Soluble Iron ◽  
Alkyl Azides

A soluble iron(ii)-phthalocyanine, [FeII(tBu4Pc)(py)2], is an effective catalyst in intramolecular C(sp3)–H bond amination of alkyl azides to give the amination products in moderate to excellent yields with a broad substrate scope.

Reactivity of Barbituric, Thiobarbituric Acids and Their Related Analogues: Synthesis of Substituted and Heterocycles-based Pyrimidines

2020 ◽  
Vol 24 (14) ◽  
pp. 1610-1642 ◽  
Author(s):  
Ahmed El-Mekabaty ◽  
Hassan A. Etman ◽  
Ahmed Mosbah ◽  
Ahmed A. Fadda
Keyword(s):  
Xanthine Oxidase ◽  
Multicomponent Reactions ◽  
Biological Activities ◽  
Present Review ◽  
Urease Inhibitors ◽  
Effective Catalyst ◽  
Inhibitory Activities ◽  
Catalyst Reusability ◽  
High Yields ◽  
Nano Catalysts

Barbituric, thiobarbituric acids and their related analogs are reactive synthons for the synthesis of drugs and biologically, and pharmaceutically active pyrimidines. The present review aimed to summarize the recent advances in the synthesis of different alkylsubstituted, fused cycles, spiro-, and binary heterocycles incorporated pyrimidine skeleton based on barbituric derivatives. In this sequence, the eco-friendly techniques under catalytic conditions were used for the diverse types of multicomponent reactions under different conditions for the synthesis of various types of heterocycles. Nano-catalysts are efficient for the synthesis of these compounds in high yields and effective catalyst reusability. The compounds are potent antibacterial, cytotoxic, xanthine oxidase inhibitory activities, and attend as urease inhibitors. The projected mechanisms for the synthesis of pyranopyrimidines, benzochromenopyrimidines, chromeno-pyranopyrimidines, spiroxyindoles, oxospiro-tricyclic furopyrimidines, pyrimidine-based monoand bicyclic pyridines were discussed. The potent and diverse biological activities for instance, antioxidant, antibacterial, cytotoxic, and xanthine oxidase inhibitory activities, as well as urease inhibitors, are specified.

l-Prolinal Dithioacetal: A Highly Effective Organocatalyst for the Direct Nitro-Michael Addition to Selected Cyclic and Aromatic Ketones

Synthesis ◽  
2019 ◽  
Vol 51 (17) ◽  
pp. 3356-3368
Author(s):  
Piotr Pomarański ◽  
Zbigniew Czarnocki
Keyword(s):  
Michael Addition ◽  
Ring Size ◽  
Cyclic Ketones ◽  
Asymmetric Syntheses ◽  
Aromatic Ketones ◽  
Ring Systems ◽  
Effective Catalyst ◽  
Acetophenone Derivatives ◽  
Highly Effective ◽  
Related Compounds

The synthesis of novel l-prolinal dithioacetal and its application as an organocatalyst for the direct Michael addition of cyclic ketones and acetophenone derivatives to trans-β-nitrostyrene and related compounds is described. The prolinal dithioacetal acts as effective catalyst in the case of cyclic ketones of different ring size, in particular five- and six-membered examples, as well as larger and smaller ring systems. High enantioselectivity and diastereoselectivity is observed for different substrates and trans-β-nitrostyrenes. Also, the first asymmetric syntheses of selected 2-methyl-4-nitro-1,3-diphenylbutan-1-one derivatives by application of the obtained organocatalyst is presented.

Synthesis of copper containing polyaniline composites through interfacial polymerisation: An effective catalyst for Click reaction at room temperature

2021 ◽  
Vol 1233 ◽  
pp. 130019
Author(s):  
Mitali Chetia ◽  
Manashjyoti Konwar ◽  
Biswajit Pegu ◽  
Surajit Konwer ◽  
Diganta Sarma
Keyword(s):  
Room Temperature ◽  
Click Reaction ◽  
Effective Catalyst ◽  
Polyaniline Composites

Cross β-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles

2021 ◽  
Author(s):  
Masaki Kobayashi ◽  
Hiroki Yamaguchi ◽  
Takeyuki Suzuki ◽  
Yasushi Obora
Keyword(s):  
Primary Alcohols ◽  
Recycling Process ◽  
Catalyst Recycling ◽  
Simple Method ◽  
Benzyl Alcohols ◽  
Effective Catalyst ◽  
Iridium Nanoparticles ◽  
Highly Effective ◽  
Linear Alcohols ◽  
The Cross

A simple method for the cross β-alkylation of linear alcohols with benzyl alcohols in the presence of DMF-stabilized iridium nanoparticles was developed. Furthermore, a highly effective catalyst-recycling process was also developed.

Heteropolyacids supported on micro/mesoporous materials PMoW@HKUST-1@ZSM-5-MCM-41: Effective catalyst for oxidative desulfurization with oxygen

2021 ◽  
Vol 504 ◽  
pp. 111419
Author(s):  
Jiarong Li ◽  
Zhe Liu ◽  
Guangfa Hu ◽  
Ruimin Gao ◽  
Ronglan Zhang ◽  
...  
Keyword(s):  
Mesoporous Materials ◽  
Oxidative Desulfurization ◽  
Effective Catalyst ◽  
Mcm 41

Preparation of Ag@PNCMs nanocomposite as an effective catalyst for hydrogen generation from hydrolysis of sodium borohydride

2021 ◽  
pp. 129828
Author(s):  
Zhiqiong Li ◽  
Yan Xu ◽  
Qi Guo ◽  
Yuan Li ◽  
Xiaoying Ma ◽  
...  
Keyword(s):  
Sodium Borohydride ◽  
Hydrogen Generation ◽  
Effective Catalyst ◽  
Hydrolysis Of

Highly Effective Catalyst for the Reaction of Trialkylphosphites with C˭X Electrophiles

2011 ◽  
Vol 186 (4) ◽  
pp. 796-798 ◽  
Author(s):  
Olga O. Kolodiazhna ◽  
Anastasia O. Kolodiazhna ◽  
Oleg I. Kolodiazhnyi
Keyword(s):  
Effective Catalyst ◽  
Highly Effective

An Amine Functionalized Metal–Organic Framework as an Effective Catalyst for Conversion of CO2 and Biginelli Reactions

2017 ◽  
Vol 56 (16) ◽  
pp. 9765-9771 ◽  
Author(s):  
Ashish Verma ◽  
Dinesh De ◽  
Kapil Tomar ◽  
Parimal K. Bharadwaj
Keyword(s):  
Metal Organic Framework ◽  
Effective Catalyst ◽  
Amine Functionalized ◽  
Metal Organic ◽  
Biginelli Reactions ◽  
Organic Framework
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