Design and synthesis of Ba3SiSe5 with suitable birefringence modulated via MIV atoms in Ba-MIV-Q (MIV = Si, Ge; Q = S, Se) system

2021 ◽  
Author(s):  
Huanhuan Cheng ◽  
Abudukadi Tudi ◽  
Peng Wang ◽  
Kewang Zhang ◽  
Zhihua Yang ◽  
...  

A new ternary Ba-based selenide, Ba3SiSe5, was synthesized by high-temperature solid-state method. It crystalizes in the centrosymmetric space group Pnma (No. 62) of the orthorhombic system. The structure of the...

2018 ◽  
Vol 73 (6) ◽  
pp. 555-558 ◽  
Author(s):  
Zhi-Qing Peng ◽  
Rong Chen ◽  
Wen-Lin Feng

AbstractNovel luminescent materials Ca3-xSi2O7: xPr3+ were successfully prepared by the high-temperature solid-state method. The crystal structure, morphology, and optical spectrum were characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), and spectroscopy, respectively. The XRD patterns of the samples indicate that the crystal structure is monoclinic symmetry. The SEM shows that the selected sample has good crystallinity although its appearance is irregular and scalelike. The peak of the excitation spectrum of the sample is located at around 449 nm, corresponding to 3H4→3P2 transition of Pr3+. The peak of the emission spectrum of the sample is situated at around 612 nm which is attributed to 3P0→3H6 transition of Pr3+, and the colour is orange-red. The optimum concentration for Pr3+ replaced Ca2+ sites in Ca3Si2O7: Pr3+ is 0.75 mol%. The lifetime (8.48 μs) of a typical sample (Ca2.9925Pr0.0075)Si2O7 is obtained. It reveals that orange-red phosphors Ca3-xSi2O7: xPr3+ possess remarkable optical properties and can be used in white light emitting devices.


RSC Advances ◽  
2022 ◽  
Vol 12 (3) ◽  
pp. 1563-1570
Author(s):  
Ichrak Ben Slima ◽  
Karim Karoui ◽  
Abdelfattah Mahmoud ◽  
Frédéric Boschini ◽  
Abdallah Ben Rhaiem

The compound NaCu0.2Fe0.3Mn0.5O2 was synthesized using a solid-state method and it crystallized in a hexagonal system with a R3̄m space group in an O3-type phase.


2017 ◽  
Vol 37 (5) ◽  
pp. 0516001
Author(s):  
马诗章 Ma Shizhang ◽  
冯文林 Feng Wenlin ◽  
彭志清 Peng Zhiqing

2018 ◽  
Vol 47 (39) ◽  
pp. 13913-13925 ◽  
Author(s):  
Qi Bao ◽  
Zhijun Wang ◽  
Jiang Sun ◽  
Zhipeng Wang ◽  
Xiangyu Meng ◽  
...  

A series of color-tunable NaBa1−zSrzB9O15:Ce3+,Mn2+ phosphors were synthesized by a high temperature solid state method.


2012 ◽  
Vol 502 ◽  
pp. 132-135 ◽  
Author(s):  
Jia Yue Sun ◽  
Ji Cheng Zhu ◽  
Jun Hui Zeng ◽  
Zhi Guo Xia ◽  
Hai Yan Du

YVO4 co-doped with Tm3+/Ho3+/Yb3+ were synthesized by the high temperature solid state method and the optical properties of phosphors were characterized. Intense visible emissions centered at around 475, 541 and 649 nm, originated from the transitions of Tm3+:1G4→3H6, Ho3:5S2/>:5F4 →5I8, Tm3+:5G4→3F4 and Ho3+:5F5→5I8, respectively, have been observed in samples upon excitation with a 980 nm laser diode, and the involved mechanisms have been explained.


RSC Advances ◽  
2015 ◽  
Vol 5 (88) ◽  
pp. 71735-71742 ◽  
Author(s):  
Ting Li ◽  
Panlai Li ◽  
Zhijun Wang ◽  
Shuchao Xu ◽  
Qiongyu Bai ◽  
...  

A series of activator Sm3+, Eu3+, Mn2+ ion doped Ba3Tb(PO4)3 phosphors with tunable emitting color were synthesized via the high temperature solid state method.


2016 ◽  
Vol 4 (29) ◽  
pp. 7110-7118 ◽  
Author(s):  
Fangping Zhuo ◽  
Qiang Li ◽  
Jinghan Gao ◽  
Yujie Wang ◽  
Qingfeng Yan ◽  
...  

(Pb1−1.5xLax)(Zr0.66Sn0.23Ti0.11)O3 ceramics were fabricated using the conventional solid-state method. Enhanced and wide temperature range tunable pyroelectric properties were achieved in this system.


2021 ◽  
Author(s):  
Hongbo Gao ◽  
Ruijiao Chen ◽  
kewang zhang ◽  
Ailijiang Abudurusuli ◽  
Kangrong Lai ◽  
...  

A new fluorine-contained chalcohalide, Ba4GaS4F3, has been synthesized by conventional high-temperature solid-state reaction. The compound crystallizes in the centrosymmetric space group I41/a with a = b = 16.628 (5) Å,...


RSC Advances ◽  
2018 ◽  
Vol 8 (19) ◽  
pp. 10246-10254 ◽  
Author(s):  
Jie Liu ◽  
Gen Li ◽  
Haijie Guo ◽  
Dongwei Liu ◽  
Peng Feng ◽  
...  

A newly proposed bluish-green emitting long-lasting phosphor, BaLu2Si3O10:Eu2+, Nd3+, with prominent LLP properties is successfully achieved via a high temperature solid state method.


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