scholarly journals A ruthenium cis-dihydride with 2-phosphinophosphinine ligands catalyses the acceptorless dehydrogenation of benzyl alcohol

2021 ◽  
Author(s):  
Elizabeth C. Trodden ◽  
Matthew P. Delve ◽  
Christian Luz ◽  
Robert J. Newland ◽  
John M. Andresen ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Benzyl Benzoate ◽  
Ruthenium Dihydride

The first ruthenium dihydride stabilised with phosphinine ligands is described. Formed in situ, it was shown to catalyse the acceptorless dehydrogenation (AD) of benzyl alcohol to benzyl benzoate.

scholarly journals Enhanced Selective Oxidation of Benzyl Alcohol via In Situ H2O2 Production over Supported Pd-Based Catalysts

ACS Catalysis ◽  
2021 ◽  
pp. 2701-2714
Author(s):  
Caitlin M. Crombie ◽  
Richard J. Lewis ◽  
Rebekah L. Taylor ◽  
David J. Morgan ◽  
Thomas E. Davies ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Selective Oxidation ◽  
H2o2 Production ◽  
Oxidation Of Benzyl Alcohol ◽  
Supported Pd

On the selective aerobic oxidation of benzyl alcohol with Pd/Au-nanoparticles in batch and flow

2014 ◽  
Vol 3 (1) ◽  
pp. 99-110 ◽  
Author(s):  
Hannes Alex ◽  
Norbert Steinfeldt ◽  
Klaus Jähnisch ◽  
Matthias Bauer ◽  
Sandra Hübner
Keyword(s):  
Catalytic Activity ◽  
Benzyl Alcohol ◽  
Aerobic Oxidation ◽  
X Ray ◽  
X Ray Scattering ◽  
Oxidation Of Benzyl Alcohol ◽  
Transmission Electron ◽  
Vis Spectroscopy ◽  
Selective Aerobic Oxidation

AbstractNanoparticles (NP) have specific catalytic properties, which are influenced by parameters like their size, shape, or composition. Bimetallic NPs, composed of two metal elements can show an improved catalytic activity compared to the monometallic NPs. We, herein, report on the selective aerobic oxidation of benzyl alcohol catalyzed by unsupported Pd/Au and Pd NPs at atmospheric pressure. NPs of varying compositions were synthesized and characterized by UV/Vis spectroscopy, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS). The NPs were tested in the model reaction regarding their catalytic activity, stability, and recyclability in batch and continuous procedure. Additionally, in situ extended X-ray absorption fine structure (EXAFS) measurements were performed in order to get insight in the process during NP catalysis.

scholarly journals Selective oxidation of benzyl alcohol using in situ generated H2O2 over hierarchical Au–Pd titanium silicalite catalysts

2013 ◽  
Vol 3 (9) ◽  
pp. 2425 ◽  
Author(s):  
Inés Moreno ◽  
Nicholas F. Dummer ◽  
Jennifer K. Edwards ◽  
Mosaed Alhumaimess ◽  
Meenakshisundaram Sankar ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Selective Oxidation ◽  
Titanium Silicalite ◽  
Oxidation Of Benzyl Alcohol

scholarly journals In situ spectroscopic investigation of oxidative dehydrogenation and disproportionation of benzyl alcohol

2013 ◽  
Vol 15 (29) ◽  
pp. 12147 ◽  
Author(s):  
Ewa Nowicka ◽  
Jan P. Hofmann ◽  
Stewart F. Parker ◽  
Meenakshisundaram Sankar ◽  
Giacomo M. Lari ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Oxidative Dehydrogenation ◽  
Spectroscopic Investigation

scholarly journals Matching the organic and inorganic counterparts during nucleation and growth of copper-based nanoparticles – in situ spectroscopic studies

CrystEngComm ◽  
2015 ◽  
Vol 17 (36) ◽  
pp. 6962-6971 ◽  
Author(s):  
Malwina Staniuk ◽  
Daniel Zindel ◽  
Wouter van Beek ◽  
Ofer Hirsch ◽  
Niklaus Kränzlin ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Spectroscopic Studies ◽  
Nucleation And Growth ◽  
Cu Nanoparticles ◽  
Closing The Loop

Closing the loop: initially, the reactivity of benzyl alcohol determines the nucleation of Cu nanoparticles, but as soon as they start to form they begin to catalyze the condensation of benzyl alcohol to dibenzylether.

Sign in / Sign up

Export Citation Format

Share Document