pH-dependent formation of three porous In(III)-MOFs: framework diversity and selective gas adsorption

2022 ◽  
Author(s):  
Chengcheng Zhang ◽  
Yuanyuan Qin ◽  
Lijuan Duan ◽  
Lu Wang ◽  
Yuewei Wu ◽  
...  

pH-dependent self-assembly and structural transformation have been observed in a series of porous In(III)-MOFs, H3O[In3(pta)4(OH)2]·10H2O (NXU-1), [In(pta)2]·C3H10N (NXU-2) and [In(pta)2]·C3H10N (NXU-3) (H2pta = 2-(4-pyridyl)-terephthalic acid). The structural diversities of NXU-1–3...

Soft Matter ◽  
2021 ◽  
Vol 17 (11) ◽  
pp. 3096-3104
Author(s):  
Valeria Castelletto ◽  
Jani Seitsonen ◽  
Janne Ruokolainen ◽  
Ian W. Hamley

A designed surfactant-like peptide is shown, using a combination of cryogenic-transmission electron microscopy and small-angle X-ray scattering, to have remarkable pH-dependent self-assembly properties.


Polyhedron ◽  
2008 ◽  
Vol 27 (12) ◽  
pp. 2672-2680 ◽  
Author(s):  
Zhao-Peng Qi ◽  
Zheng-Shuai Bai ◽  
Qing Yuan ◽  
Taka-aki Okamura ◽  
Kai Cai ◽  
...  

2017 ◽  
Vol 18 (3) ◽  
pp. 943-950 ◽  
Author(s):  
Muhammad Waqas ◽  
Woo-jin Jeong ◽  
Young-Joo Lee ◽  
Dae-Hwan Kim ◽  
Chongsuk Ryou ◽  
...  

2019 ◽  
Vol 17 (18) ◽  
pp. 4543-4553 ◽  
Author(s):  
Jessica A. Hutchinson ◽  
Ian W. Hamley ◽  
Charlotte J. C. Edwards-Gayle ◽  
Valeria Castelletto ◽  
Cristian Piras ◽  
...  

The self-assembly of a palmitoylated peptide C16-EELNRYY based on a fragment of the gut hormone peptide PYY3–36 is investigated.


2017 ◽  
Vol 5 (16) ◽  
pp. 7555-7563 ◽  
Author(s):  
Michael C. Nolan ◽  
James J. Walsh ◽  
Laura L. E. Mears ◽  
Emily R. Draper ◽  
Matthew Wallace ◽  
...  

We show the importance of the self-assembly of a perylene bisimide on its photocatalytic activity.


Tetrahedron ◽  
2007 ◽  
Vol 63 (25) ◽  
pp. 5539-5547 ◽  
Author(s):  
Oana M. Martin ◽  
Sandro Mecozzi
Keyword(s):  

2013 ◽  
Vol 575-576 ◽  
pp. 30-36 ◽  
Author(s):  
Ning Ning Wu ◽  
Can Xiong Guo ◽  
Gui An Wu ◽  
Zhao Cai ◽  
Wan Hong He

A novel one-dimensional metal-organic coordination polymer, [Zn (NH3)2(BDC)]n (BDC=1,4-benzenedicaboxylate), has been synthesized by solvent evaporation method through self-assembly of Zn (II) salts with terephthalic acid ligand in ammonia aqueous solution. Single crystal X-ray diffraction analysis indicated that each Zn (II) was coordinated by two nitrogen donors from two NH3 and two oxygen counter donors from terephthalic acid ligand. The adjacent zigzag chains are arranged in a parallel fashion and linked by interchain hydrogen bonding interaction and π-π stacking interactions into higher-dimensional framework. The compound has also been characterized by CHN elemental analyses, Single crystal X-ray diffraction analysis, powder X-ray diffraction (PXRD) analysis, Fourier transform infrared (FT-IR) spectra, Thermalgravimetric-differential scanning calorimetric (TG-DSC) and Solid-state nuclear magnetic resonance (NMR), etc. Results showed that the framework of compound was stable at the temperature up to 246°C. The desolvated product [Zn (BDC)]n, which was obtained by removal of molecular NH3 from [Zn (NH3)2(BDC)]n, can be transferred to the different skeleton structures through coordinating different small hydrogen-bond-forming molecules.


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