Water as Hole-Predatory Instrumental to Create Metal Nanoparticles on Triple-Conducting Oxides

2022 ◽  
Author(s):  
Jun Hyuk Kim ◽  
Jaewoon Hong ◽  
Dae-Kwang Lim ◽  
Sejong Ahn ◽  
Jinwook Kim ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Nanoparticles ◽  
Single Phase ◽  
Electronic Conductivity ◽  
Conducting Oxides ◽  
Oxygen Ions ◽  
Electrochemical Devices ◽  
Electron Holes

Single-phase materials with mixed ionic and electronic conductivity underpin multiple solid-state electrochemical devices as promising electrodes. In particular, triple-conducting oxides that carry protons, oxygen ions, and electron holes simultaneously have...

scholarly journals Cobalt Nanoparticle-Embedded Nitrogen-Doped Carbon Catalyst Derived from a Solid-State Metal-Organic Framework Complex for OER and HER Electrocatalysis

Energies ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1320
Author(s):  
Shaik Gouse Peera ◽  
Ravindranadh Koutavarapu ◽  
Chao Liu ◽  
Gaddam Rajeshkhanna ◽  
Arunchander Asokan ◽  
...  
Keyword(s):  
Solid State ◽  
Alkaline Medium ◽  
Glassy Carbon ◽  
Metal Organic Framework ◽  
Electronic Conductivity ◽  
Organic Ligand ◽  
Synthesis Process ◽  
Ni Foam ◽  
Shell Nanoparticles ◽  
Energy Devices

Electrochemical water splitting is considered a promising way of producing hydrogen and oxygen for various electrochemical energy devices. An efficient single, bi-functional electrocatalyst that can perform hydrogen evolution reactions (HERs) and oxygen evolution reactions (OERs) is highly essential. In this work, Co@NC core-shell nanoparticles were synthesized via a simple, eco-friendly, solid-state synthesis process, using cobalt nitrate and with pyrazole as the N and C source. The morphological analysis of the resulting Co@NC nanoparticles was performed with a scanning and transmission electron microscope, which showed Co nanoparticles as the core and the pyrolysis of pyrazole organic ligand N-doped carbon derived shell structure. The unique Co@NC nanostructures had excellent redox sites for electrocatalysis, wherein the N-doped carbon shell exhibited superior electronic conductivity in the Co@NC catalyst. The resulting Co@NC nanocatalyst showed considerable HER and OER activity in an alkaline medium. The Co@NC catalyst exhibited HERs overpotentials of 243 and 170 mV at 10 mA∙cm−2 on glassy carbon and Ni foam electrodes, respectively, whereas OERs were exhibited overpotentials of 450 and 452 mV at a current density of 10 and 50 mA∙cm−2 on glassy carbon electrode and Ni foam, respectively. Moreover, the Co@NC catalyst also showed admirable durability for OERs in an alkaline medium.

scholarly journals Structure and transport properties of triple-conducting BaxSr1−xTi1−yFeyO3−δ oxides

RSC Advances ◽  
2021 ◽  
Vol 11 (32) ◽  
pp. 19570-19578
Author(s):  
T. Miruszewski ◽  
K. Dzierzgowski ◽  
P. Winiarz ◽  
D. Jaworski ◽  
K. Wiciak-Pawłowska ◽  
...  
Keyword(s):  
Transport Properties ◽  
Charge Carriers ◽  
Conducting Oxides ◽  
Oxygen Ions ◽  
Perovskite Materials

BaxSr1−xTi1−yFeyO3−δ-based perovskite materials with different barium and iron contents are reported as triple conducting oxides (TCOs), which may conduct three charge carriers: oxygen ions, protons and electrons/holes.

Solid Phase Synthesis and Sintering Properties of Yttrium Iron Garnet

2008 ◽  
Vol 368-372 ◽  
pp. 588-590 ◽  
Author(s):  
Ming Hao Fang ◽  
Jun Tong Huang ◽  
Zhao Hui Huang ◽  
Yan Gai Liu ◽  
Bin Jiang ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Single Phase ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Volume Density ◽  
Phase Synthesis ◽  
Fe2o3 Content ◽  
Sintering Properties ◽  
Iron Garnet

Single phase YIG powders were synthesized successfully using Fe2O3 and Y2O3 as starting materials by solid state reaction, and YIG ceramics were prepared by pressureless sintering. The influence of synthesizing temperature and Fe2O3 content on the final production were studied The effect of Fe2O3 content on volume density and microstructure of the sintered YIG was also investigated. The results showed that single phase YIG powders were synthesized by solid state reaction at 1400°C for 3h. When Fe2O3 content was excessive 3 wt%, YIG ceramics with a density of 5.294g·cm-3 was fabricated by sintering at 1480°C for 2.5h.

scholarly journals Thermoelectric properties of Cu3SbSe3 with intrinsically ultralow lattice thermal conductivity

2014 ◽  
Vol 2 (38) ◽  
pp. 15829-15835 ◽  
Author(s):  
Kriti Tyagi ◽  
Bhasker Gahtori ◽  
Sivaiah Bathula ◽  
A. K. Srivastava ◽  
A. K. Shukla ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Solid State ◽  
Spark Plasma Sintering ◽  
Thermoelectric Properties ◽  
Solid State Reaction ◽  
Electrical Transport ◽  
Single Phase ◽  
Lattice Thermal Conductivity ◽  
Plasma Sintering ◽  
Spark Plasma

Intrinsically ultra-low thermal conductivity and electrical transport in single-phase Cu2SbSe3 synthesized employing a solid state reaction and spark plasma sintering.

Combustion Synthesis of Sr-Substituted LaCo0.4Fe0.6O3 Powders

1992 ◽  
Vol 271 ◽  
Author(s):  
J. J. Kingsley ◽  
L. A. Chick ◽  
G. W. Coffey ◽  
D. E. McCready ◽  
L. R. Pederson
Keyword(s):  
Solid State ◽  
Metal Oxides ◽  
Mixed Oxides ◽  
Electronic Conductivity ◽  
Solid State Reactions ◽  
Bet Surface Area ◽  
Metal Nitrates ◽  
Subsequent Calcination ◽  
Multi Phase ◽  
Sorption Characteristics

ABSTRACTSr-substituted perovskite LaCo0.4Fe0.6O3 is known to have excellent mixed ionic and electronic conductivity and increased O2 sorption characteristics. These perovskites are usually prepared by lengthy solid-state reactions of the component oxides at temperatures near 1150°C, and often produce inhomogeneous, multi-phase powders. Presently, it has been prepared by the calcination of combustion-derived fine mixed oxides at 850°C in 6 hrs. Combustion reactions are carried out using precursor solutions containing the corresponding metal nitrates (oxidizers) and glycine (fuel) at 250°C. The metal oxides produced by this process and subsequent calcination were characterized by XRD, TEM and BET surface area analysis.

A single-phase all-solid-state lithium battery based on Li1.5Cr0.5Ti1.5(PO4)3 for high rate capability and low temperature operation

2018 ◽  
Vol 54 (25) ◽  
pp. 3178-3181 ◽  
Author(s):  
Atsushi Inoishi ◽  
Akira Nishio ◽  
Yuto Yoshioka ◽  
Ayuko Kitajou ◽  
Shigeto Okada
Keyword(s):  
Solid State ◽  
Low Temperature ◽  
Lithium Battery ◽  
Single Phase ◽  
Rate Capability ◽  
High Rate ◽  
High Rate Capability ◽  
Single Material

We report a battery made from a single material using Li1.5Cr0.5Ti1.5(PO4)3 as the anode, cathode and electrolyte.

The Fabricated Collagen-Based Nano-Hydroxyapatite/β-Tricalcium Phosphate Scaffolds

2012 ◽  
Vol 506 ◽  
pp. 57-60 ◽  
Author(s):  
M. Ebrahimi ◽  
Naruporn Monmaturapoj ◽  
S. Suttapreyasri ◽  
P. Pripatnanont
Keyword(s):  
Mechanical Properties ◽  
Solid State ◽  
Calcium Phosphate ◽  
Biphasic Calcium Phosphate ◽  
Single Phase ◽  
Physical And Mechanical Properties ◽  
Total Porosity ◽  
Xrd Pattern ◽  
Collagen Coating ◽  
Dimensional Shrinkage

The biphasic calcium phosphate (BCP) concept was introduced to overcome disadvantages of single phase biomaterials. In this study, we prepared BCP from nanoHA and β-TCP that were synthesized via a solid state reaction. Three different ratios of pure BCP and collagen-based BCP scaffolds (%HA/%β-TCP; 30/70, 40/60 and 50/50) were produced using a polymeric sponge method. Physical and mechanical properties of all materials and scaffolds were investigated. XRD pattern proved the purity of each HA, β-TCP and BCP. SEM showed overall distribution of macropores (80-200 µm) with appropriate interconnected porosities. Total porosity of pure BCP (93% ± 2) was found to be higher than collagen-based BCP (85%± 3). It was observed that dimensional shrinkage of larger scaffold (39% ± 4) is lower than smaller one (42% ± 5) and scaffolds with higher HA (50%) ratio experienced greater shrinkage than those with higher β-TCP (70%) ratio (45% ±3 and 36% ±1 respectively). Mechanical properties of both groups tend to be very low and collagen coating had no influence on mechanical behavior. Further studies may improve the physical properties of these composite BCP.

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