Hydrazone exchange: a viable route for the solid-tethered synthesis of [2]rotaxanes

2021 ◽  
Vol 45 (9) ◽  
pp. 4414-4421
Author(s):  
Rafael Da Silva Rodrigues ◽  
Ena T. Luis ◽  
David L. Marshall ◽  
John C. McMurtrie ◽  
Kathleen M. Mullen
Keyword(s):  
Solid Supports ◽  
Resin Beads ◽  
Self Assembled ◽  
Synthetic Approaches

Using a hydrazone exchange methodology, resin beads were functionalised with [2]rotaxanes at up to 80% efficiency—higher than using other dynamic or irreversible synthetic approaches to form self-assembled structures on solid supports.

Spectrochemical Characterization of Thin Layers of Lipoprotein Self-Assembled Films on Solid Supports Under Oxidation Process

2011 ◽  
Vol 44 (5) ◽  
pp. 747-760 ◽  
Author(s):  
Andreia Tache ◽  
Serafina Cotrone ◽  
Simona-Carmen Litescu ◽  
Nicola Cioffi ◽  
Luisa Torsi ◽  
...  
Keyword(s):  
Oxidation Process ◽  
Thin Layers ◽  
Solid Supports ◽  
Self Assembled

scholarly journals Recent Advances in Sequential Infiltration Synthesis (SIS) of Block Copolymers (BCPs)

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 994
Author(s):  
Eleonora Cara ◽  
Irdi Murataj ◽  
Gianluca Milano ◽  
Natascia De Leo ◽  
Luca Boarino ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Large Scale ◽  
Inorganic Materials ◽  
Ex Situ ◽  
Selective Incorporation ◽  
Microelectronics Industry ◽  
Self Assembled ◽  
Definition Of ◽  
Synthetic Approaches

In the continuous downscaling of device features, the microelectronics industry is facing the intrinsic limits of conventional lithographic techniques. The development of new synthetic approaches for large-scale nanopatterned materials with enhanced performances is therefore required in the pursuit of the fabrication of next-generation devices. Self-assembled materials as block copolymers (BCPs) provide great control on the definition of nanopatterns, promising to be ideal candidates as templates for the selective incorporation of a variety of inorganic materials when combined with sequential infiltration synthesis (SIS). In this review, we report the latest advances in nanostructured inorganic materials synthesized by infiltration of self-assembled BCPs. We report a comprehensive description of the chemical and physical characterization techniques used for in situ studies of the process mechanism and ex situ measurements of the resulting properties of infiltrated polymers. Finally, emerging optical and electrical properties of such materials are discussed.

Formation of Self-Assembled, Air-Stable Lipid Bilayer Membranes on Solid Supports

Langmuir ◽  
2001 ◽  
Vol 17 (8) ◽  
pp. 2305-2307 ◽  
Author(s):  
Eric E. Ross ◽  
Bruce Bondurant ◽  
Tony Spratt ◽  
John C. Conboy ◽  
David F. O'Brien ◽  
...  
Keyword(s):  
Lipid Bilayer ◽  
Lipid Bilayer Membranes ◽  
Solid Supports ◽  
Bilayer Membranes ◽  
Self Assembled

Pyridyl disulfide-based thiol–disulfide exchange reaction: shaping the design of redox-responsive polymeric materials

2020 ◽  
Vol 11 (48) ◽  
pp. 7603-7624
Author(s):  
Ismail Altinbasak ◽  
Mehmet Arslan ◽  
Rana Sanyal ◽  
Amitav Sanyal
Keyword(s):  
Exchange Reaction ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Disulfide Exchange ◽  
Redox Responsive ◽  
Synthetic Approaches

This review provides an overview of synthetic approaches utilized to incorporate the thiol-reactive pyridyl-disulfide motif into various polymeric materials, and briefly highlights its utilization to obtain functional materials.

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