Iridium-catalysed borylation of pyrene – a powerful route to novel optoelectronic materials

2021 ◽  
Author(s):  
Yufeng Zhang ◽  
Leibo Tan ◽  
Junqing Shi ◽  
Lei Ji

We summarized the Ir-catalysed borylation of PAHs, especially pyrene, and the optoelectronic materials generated by following this chemistry. The optoelectronic properties of pyrene derivatives have also been discussed.

Synthesis ◽  
2021 ◽  
Author(s):  
Hee Nam Lim ◽  
Wan Pyo Hong ◽  
Inji Shin

AbstractThis short review summarizes the origins and recent progress in 1,4-azaborine research, focusing on synthetic methodologies. Academic laboratories have made significant efforts to generate boron-nitrogen-containing heteroaromatic compounds that mimic arenes. 1,2-, 1,3-, and 1,4-Azaborine motifs have provided breakthrough molecules in applications ranging from medicines to materials. Owing to recent advances in polyaromatic 1,4-azaborine synthesis and applications in industry, the research field is currently undergoing a renaissance. Photo- and electroluminescent properties driven by distinct structural variations are key components in the design of novel 1,4-azaborine structures. In this review, seminal reports on the synthesis of simple 1,4-azaborines to complex π-extended structures are briefly highlighted together along with key optoelectronic properties.1 Introduction2 Non-Fused 1,4-Azaborines3 Monobenzo-Fused 1,4-Azaborines4 Dibenzo-Fused 1,4-Azaborines and Their Derivatives5 Ladder-Type 1,4-Azaborines6 Complex 1,4-Azaborines7 Optoelectronic Properties of Key 1,4-Azaborines8 Conclusion and Outlook


2019 ◽  
Vol 7 (41) ◽  
pp. 12822-12834 ◽  
Author(s):  
Julian M. W. Chan

The pentafluorosulfanyl (SF5) moiety has emerged as a versatile tool for tailoring optoelectronic properties in a wide range of functional materials.


2019 ◽  
Vol 18 (1) ◽  
pp. 15-29 ◽  
Author(s):  
Soorya Sasi ◽  
Sunish K. Sugunan ◽  
P. Radhakrishnan Nair ◽  
K. R. V. Subramanian ◽  
Suresh Mathew

In this perspective article, we discuss the possibilities of integrating liquefied organic and inorganic semiconducting materials with tunable optoelectronic properties into solvent-free fluidic systems of functional optoelectronic materials to generate flexible DSSCs/QDSSCs.


2014 ◽  
Vol 12 (44) ◽  
pp. 8902-8910 ◽  
Author(s):  
Di Wu ◽  
Haojie Ge ◽  
Zhao Chen ◽  
Jinhua Liang ◽  
Jie Huang ◽  
...  

Imide-modified polycyclic aromatic hydrocarbons can be widely applied in the field of optoelectronic materials.


Synlett ◽  
2022 ◽  
Author(s):  
Birgit Esser ◽  
Jan S Wössner ◽  
Mathias Hermann

Conjugated nanohoops are excellent candidates to study structure-property relationships, as optoelectronic materials and as hosts for supramolecular chemistry. While carbon nanohoops containing aromatics are well studied, antiaromatic units had not been incorporated until recently by our group using dibenzo[a,e]pentalene (DBP). The non-alternant electronic character of the DBP units significantly influences the optoelectronic properties of such nanohoops. We herein summarize our synthetic strategies to DBP-containing nanohoops, their structural and electronic properties, chirality and host-guest chemistry. We demonstrate how incorporating antiaromatic units leads to unique properties and opens new synthetic avenues, making such nanohoops attractive as potential electronic materials.


RSC Advances ◽  
2017 ◽  
Vol 7 (15) ◽  
pp. 9194-9236 ◽  
Author(s):  
Paulina Hibner-Kulicka ◽  
John Arthur Joule ◽  
Joanna Skalik ◽  
Piotr Bałczewski

The dibenzophospholes, synthesized in the 1950s, have recently gained a greater importance, due to their use in organic electronics and the possibility of designing new π-conjugated, optoelectronic materials that incorporate these heterocycles.


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