Crossover of positive and negative magnetoconductance in composites of nanosilica glass containing dual transition metal oxides

This work provides guidance on controlling anionic redox activity and finding novel high-capacity transition metal oxide cathodes for sodium-ion batteries.

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Ultrathin Transition Metal Oxide: Atomically Thin 2D Transition Metal Oxides: Structural Reconstruction, Interaction with Substrates, and Potential Applications (Adv. Mater. Interfaces 1/2019)

Advanced Materials Interfaces ◽

10.1002/admi.201970003 ◽

2019 ◽

Vol 6 (1) ◽

pp. 1970003

Author(s):

Tong Yang ◽

Ting Ting Song ◽

Martin Callsen ◽

Jun Zhou ◽

Jian Wei Chai ◽

...

Keyword(s):

Transition Metal ◽

Metal Oxide ◽

Metal Oxides ◽

Transition Metal Oxides ◽

Transition Metal Oxide ◽

Potential Applications

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Conductive Polymer/Transition Metal Oxide Hybrid Materials for Lithium Batteries

MRS Proceedings ◽

10.1557/proc-726-q11.7 ◽

2002 ◽

Vol 726 ◽

Cited By ~ 1

Author(s):

Chai-Won Kwon ◽

Armel Poquet ◽

Stéphane Mornet ◽

Guy Campet ◽

Josik Portier ◽

...

Keyword(s):

Transition Metal ◽

Metal Oxide ◽

Metal Oxides ◽

Hybrid Materials ◽

Vanadium Pentoxide ◽

Transition Metal Oxides ◽

Conductive Polymer ◽

Transition Metal Oxide ◽

Core Shell ◽

Potential Range

AbstractOrganic-inorganic hybrid materials were synthesized for use of lithium battery electrode by two strategies: 1) core-shell strategy for tri-dimensional transition metal oxide and 2) intercalation strategy for bi-dimensional (lamellar) transition metal oxide. We choose conductive polymers as an organic component for high electric conductivity and 3d-transition metal oxides as an inorganic counterpart for large capacity and processibility. Polypyrrole/maghemite and poly(3,4-ethylenedioxythiophene) (PEDOT)/vanadium pentoxide hybrids will be presented and compared with their pristine materials for core-shell and intercalation strategies, respectively. Polypyrrole/maghemite showed an enhanced electrochemical reversibility and capacity up to ∼270 mAh/g in the potential range between 1.3 and 4.3 V vs. Li at 8 mA/g. PEDOT/vanadium pentoxide also exhibited improved reversibility and capacity up to ∼330 mAh/g at 15 mA/g between 2.0 ∼ 4.4 V vs. Li on the second discharge. XRD, IR, electron microscopy, XPS and Xray absorption spectroscopy were used to characterize the samples, and to examine oxidation state of the transition metals, doping character of the polymer and the nature of interaction between the polymer and the transition metal oxides.

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Transition Metal Oxides for Rocking-Chair Cells

MRS Proceedings ◽

10.1557/proc-369-17 ◽

1994 ◽

Vol 369 ◽

Cited By ~ 1

Author(s):

M. M. Thackeray ◽

E. Ferg ◽

R. J. Gummow ◽

A. De Kock

Keyword(s):

Transition Metal ◽

Metal Oxide ◽

Metal Oxides ◽

Transition Metal Oxides ◽

Low Voltage ◽

Lithium Ion ◽

Cell Voltage ◽

Transition Metal Oxide ◽

Carbon Anode ◽

Lithium Cells

AbstractTransition metal oxides have been evaluated extensively in the past as cathode materials for lithium cells. The major emphasis of recent research has been to develop lithium-ion or rockingchair cells that are assembled in the discharged state with a lithiated transition metal oxide cathode and a carbon anode. Although these cells are significantly safer to use than lithium cells with metallic lithium anodes, the possibility of depositing lithium at the surface of the carbon particles at the top of charge or at high rates of charge cannot be discounted. This paper discusses some recent developments in fabricating rocking-chair cells with transition metal oxide host structures as both anode and cathode, the anode providing a relatively low voltage vs. lithium and the cathode a relatively highvoltage vs. lithium. These cells avoid the reduction and oxidation of lithium during charge and discharge and, therefore, reduce the safety hazards of lithium cells. Improved safety is gained, however, at the expense of cell voltage and specific energy.

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Effects of a conductive support on the bonding of oxygen containing molecules to transition metal oxide surfaces

Physical Chemistry Chemical Physics ◽

10.1039/d0cp04536e ◽

2020 ◽

Vol 22 (45) ◽

pp. 26216-26222

Author(s):

Hao Li ◽

Jens K. Nørskov

Keyword(s):

Transition Metal ◽

Metal Oxide ◽

Metal Oxides ◽

Transition Metal Oxides ◽

Transition Metal Oxide ◽

Wide Bandgap ◽

Oxide Surfaces ◽

Metal Oxide Surfaces ◽

Marked Enhancement ◽

Metal Support

The presence of a metal support leads to a marked enhancement of ORR/OER adsorbate binding strengths on wide bandgap transition metal oxides.

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Methane-to-Methanol Conversion by First-Row Transition-Metal Oxide Ions: ScO+, TiO+, VO+, CrO+, MnO+, FeO+, CoO+, NiO+, and CuO+

Journal of the American Chemical Society ◽

10.1021/ja0017965 ◽

2000 ◽

Vol 122 (49) ◽

pp. 12317-12326 ◽

Cited By ~ 172

Author(s):

Yoshihito Shiota ◽

Kazunari Yoshizawa

Keyword(s):

Transition Metal ◽

Metal Oxide ◽

Transition Metal Oxide ◽

Methanol Conversion ◽

Oxide Ions

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Binary metal oxide: advanced energy storage materials in supercapacitors

Journal of Materials Chemistry A ◽

10.1039/c4ta04996a ◽

2015 ◽

Vol 3 (1) ◽

pp. 43-59 ◽

Cited By ~ 300

Author(s):

Yufei Zhang ◽

Laiquan Li ◽

Haiquan Su ◽

Wei Huang ◽

Xiaochen Dong

Keyword(s):

Energy Storage ◽

Transition Metal ◽

Metal Oxide ◽

Metal Oxides ◽

Transition Metal Oxides ◽

Electrode Materials ◽

Electronic Conductivity ◽

Reversible Capacity ◽

Energy Storage Materials ◽

Binary Metal Oxide

Binary transition metal oxides (BTMOs) possess higher reversible capacity, better structural stability and electronic conductivity, and have been widely studied to be novel electrode materials for supercapacitors.

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Interaction of a bioactive molecule with surfaces of nanoscale transition metal oxides: experimental and theoretical studies

New Journal of Chemistry ◽

10.1039/c9nj03124c ◽

2019 ◽

Vol 43 (42) ◽

pp. 16621-16628 ◽

Cited By ~ 2

Author(s):

Prasanta Bandyopadhyay ◽

Rajkumar Jana ◽

Kalishankar Bhattacharyya ◽

Oleg I. Lebedev ◽

Uma Dutta ◽

...

Keyword(s):

Transition Metal ◽

Metal Oxide ◽

Metal Oxides ◽

Transition Metal Oxides ◽

Theoretical Studies ◽

Schematic Diagram ◽

Bioactive Molecule ◽

Experimental And Theoretical Studies

Schematic diagram of metal oxide–BTT interaction and the associated changes in experimental UV-Vis spectra. BTT adsorbed α-Fe2O3 is represented by red spectra, while green spectra represent BTT adsorbed NiO. Black spectra represent pure BTT spectra.

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