scholarly journals A tubular electrode assembly reactor for enhanced electrochemical wastewater treatment with a Magnéli-phase titanium suboxide (M-TiSO) anode and in situ utilization

RSC Advances ◽  
2021 ◽  
Vol 11 (40) ◽  
pp. 24976-24984
Author(s):  
Jiabin Liang ◽  
Shijie You ◽  
Yixing Yuan ◽  
Yuan Yuan

A stainless steel pipe (SSP) was used as a cathode. A tubular Magnéli-phase titanium suboxide (M-TiSO) anode was posited in the center. A spiral static mixer was used to process intensification.

2020 ◽  
Vol 1 (4) ◽  
Author(s):  
Peizeng Yang ◽  
Yaye Wang ◽  
Junhe Lu ◽  
Viktor Tishchenko ◽  
Qingguo Huang ◽  
...  

This study examined the degradation of perfluorooctanesulfonate (PFOS) in electrochemical oxidation (EO) processes in the presence of trichloroethylene (TCE). The EO experiment was performed in a gas-tight reactor using Magnéli phase titanium suboxide (Ti4O7) as the anode. The experimental data demonstrated that 75% of PFOS (2 μM) was degraded at 10 mA/cm2 current density in 30 min without TCE present in the solution, while the presence of 76 μM TCE apparently inhibited the degradation of PFOS, reducing its removal down to 53%. Defluorination ratio suggested that PFOS was significantly mineralized upon EO treatment, and it appeared to be not influenced by the presence of TCE. The respective pseudo-first order rate constants (kobs) of PFOS removal were 0.0471 and 0.0254 min-1 in the absence and presence of TCE. The degradation rates of both PFOS and TCE increased with current density rising from 2.5 to 20 mA/cm2. In the presence of TCE, chloride, chlorate, and perchlorate were formed that accounted for 79.7 %, 5.53%, and 1.51% of the total chlorine at 60 min. This work illustrates the promise of the Magnéli phase Ti4O7 electrode based electrochemical oxidation technology for degrading per- and polyfluoroalkyl substances (PFASs) and co-contaminants in groundwaters.


2019 ◽  
Vol 12 (2) ◽  
pp. 2539-2547 ◽  
Author(s):  
Masanori Nagao ◽  
Sayaka Misu ◽  
Jun Hirayama ◽  
Ryoichi Otomo ◽  
Yuichi Kamiya

1978 ◽  
Vol 22 ◽  
pp. 247-249 ◽  
Author(s):  
C. O. Ruud ◽  
C. S. Barrett

Residual stresses on the inner surface of stainless steel pipe used in nuclear reactors are of exceptional importance. Apparatus for measuring these in situ, in welded lengths of 10-inch diameter austenitic (304) stainless pipe has been developed at the University of Denver Research Institute under the sponsorship of the Electric Power Research Institute.


2021 ◽  
Vol 69 (2) ◽  
pp. 45-52
Author(s):  
Attila TOKOS ◽  
Monica JIPA ◽  
Virgil MARINESCU ◽  
Csaba BARTHA ◽  
Alina-Ruxandra CARAMITU ◽  
...  

A system for electromagnetic stimulation of microorganisms' activity from the active sludge of wastewater treatment plants was developed and preliminarily tested. Through electrochemical, gravimetric, XRD, and SEM-EDAX measurements, it was found that austenitic stainless steel 18/8 presents good stability to AC polarization in wastewater. Preliminary determinations performed through the dielectric spectroscopy technique indicated that the activated sludge's microbial flora is sensitive to 50 ± 0.1 Hz. The stimulation system developed and put into service on the biological aerobic treatment bioreactor consists of a pair of polarizing electrodes, made of perforated 18/8 stainless steel sheet, electrically connected to a power supply, which at 50 Hz is capable of debiting adjustable voltages between 5 and 24 Vrms at a maximum current of 5 A. Preliminary in situ measurements showed that following the stimulation of the microorganisms from the sludge suspension, as a result of an applied electromagnetic field of approximately 4.5 V/m at 50 Hz, the metabolism of residues is accelerated substantially (organic residues determined by oxygen demand decrease by about 42 %, nitrogen/ammonium content by about 44% and total phosphorus by about 50 % which results in an increase in free oxygen concentration by about 71 %).


Author(s):  
Pengchao Si ◽  
Mengqi Li ◽  
Xiang Wang ◽  
Feifei Sun ◽  
Jingjing Liu ◽  
...  

2019 ◽  
Vol 10 (5) ◽  
pp. 459-465
Author(s):  
Yoshiyuki Kuroda ◽  
Hikaru Igarashi ◽  
Takaaki Nagai ◽  
Teko W. Napporn ◽  
Koichi Matsuzawa ◽  
...  

2019 ◽  
Vol 53 (24) ◽  
pp. 14528-14537 ◽  
Author(s):  
Huanhuan Shi ◽  
Yaye Wang ◽  
Chenguang Li ◽  
Randall Pierce ◽  
Shixiang Gao ◽  
...  

2012 ◽  
Vol 53 (6) ◽  
pp. 1069-1074 ◽  
Author(s):  
Mitsuharu Shiwa ◽  
Hiroyuki Masuda ◽  
Hisashi Yamawaki ◽  
Kaita Ito ◽  
Manabu Enoki

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