Synthesis, structures, and catalytic efficiency in ring opening polymerization of rac-lactide with tridentate vs. bidentate cobalt(ii), zinc(ii), and cadmium(ii) complexes containing N-substituted N,N-bis((3,5-dimethyl-1H-pyrazol-1-yl)methyl)amine ligands
Keyword(s):
Co(ii), Zn(ii), and Cd(ii) complexes supported by bis-pyrazolyl ligands were applied to the ring-opening polymerization of rac-lactide to produce heterotactic polylactides (PLAs) with superior heterotactic bias i.e. Pr up to 0.94 at −25 °C.
2013 ◽
Vol 731
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pp. 23-28
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Keyword(s):
2020 ◽
1985 ◽
Vol 30
(5)
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pp. 2041-2049
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1993 ◽
Vol 115
(15)
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pp. 7035-7036
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