scholarly journals Selective Separation of Amines from Continuous Processes using Automated pH Controlled Extraction

2021 ◽  
Author(s):  
Luke Power ◽  
Adam D. Clayton ◽  
William Reynolds ◽  
David Hose ◽  
Caroline Ainsworth ◽  
...  
Keyword(s):  
Liquid Extraction ◽  
Selective Separation ◽  
Continuous Processing ◽  
Online Analysis ◽  
Continuous Processes ◽  
Liquid Liquid Extraction ◽  
Ph Controlled

We present a rapid continuous processing methodology to screen for the optimal, selective, liquid-liquid extraction conditions, from a typical post-reaction mixture of amines, using both inline and online analysis to...

scholarly journals Homogeneous Liquid-Liquid Extraction Method for Selective Separation and Preconcentration of Trace Amounts of Palladium

2009 ◽  
Vol 6 (4) ◽  
pp. 1077-1084 ◽  
Author(s):  
Mohammad Reza Jamali ◽  
Yaghoub Assadi ◽  
Reyhaneh Rahnama Kozani ◽  
Farzaneh Shemirani
Keyword(s):  
Extraction Method ◽  
Limit Of Detection ◽  
Liquid Extraction ◽  
Selective Separation ◽  
Complexing Agent ◽  
Homogeneous Liquid ◽  
Liquid Liquid Extraction ◽  
Relative Standard ◽  
Separation And Preconcentration ◽  
Ternary Component System

A simple and effective homogeneous liquid-liquid extraction method for selective separation, preconcentration and spectrophotometric determination of palladium(II) ion was developed by using a ternary component system (water / tetrabutylammonium ion (TBA+) / chloroform). The phase separation phenomenon occurred by an ion–pair formation of TBA+and perchlorate ion. Thio-Michler’s ketone (TMK), 4, 4ˊ-bis (dimethylamino) thiobenzophenone, was used as a complexing agent. After optimization of complexation and extraction conditions ([TMK]=5.0x10-2mol L-1, [TBA+] = 2.0×10-2mol L-1, [CHCl3] = 60.0 µL, [ClO4-] = 2.5×10-2mol L-1and pH= 3.0), a preconcentration factor 10 was obtained for 10 mL of sample. The analytical curve was linear in the range of 2-100 ng mL-1and the limit of detection was 0.4 ng mL-1. The relative standard deviation was 3.2% (n=10). Accuracy and application of the method was estimated by using test samples of natural and synthetic water spiked with different amounts of palladium(II) ion. The method is very simple and inexpensive.

scholarly journals Separation Studies of Pd(II) from Acidic Chloride Solutions of Pt(IV), Ni(II) and Rh(III) by Using 4-Aroyl-3-Phenyl-5-Isoxazolones

2012 ◽  
Vol 9 (2) ◽  
pp. 756-765
Author(s):  
Koduru Janardhan Reddy ◽  
Kap Duk Lee
Keyword(s):  
Metal Ions ◽  
Water Samples ◽  
Liquid Extraction ◽  
Selective Separation ◽  
Extraction Mechanism ◽  
Chloride Solutions ◽  
Liquid Liquid Extraction ◽  
Separation Factors ◽  
Acidic Chloride ◽  
Synthetic Water

This study examined the effect influence of various factors on the extraction of Pd(II) to develop a new liquid-liquid extraction mechanism for the selective separation of palladium(II) from its acidic chloride solutions using 4-aroyl-3-phenyl-5-isoxazolones (HA), such as 3-phenyl-4-(4-fluorobenzoyl)-5- isoxazolone (HFBPI), 3-phenyl-4-benzoyl-5-isoxazolone (HPBI) and 3-phenyl-4- (4-toluoyl)-5-isoxazolone (HTPI). The extraction strength of Pd(II) with HA were in the following order: HFBPI > HPBI > HTPI, which is opposite to that observed with their pKavalues. HPBI was used to separate Pd(II) from Pt(IV), Ni(II) and Rh(III) metal ions and calculated their separation factors (S.F.) were followed in the order: Pd/Ni (40±0.4) > Pd/Pt (25±0.2) > Pd/Rh (15±0.3 > Rh/Ni (2.7±0.3) > Pt/Ni ≈ Rh/Pt (1.7±0.2). The loading and striping of Pd(II) (1.12×10-4mol L-1) were also examined using 1.0×10-3mol L-1HPBI in CHCl3and 1.0 mol L-1HCl, respectively. The results demonstrated that the maximum (97.5%) extraction and desorption (89%) of metal required at least 3.0 cycles. The developed method was applied successfully to the separation of palladium from synthetic water samples.

Selective Separation of Tocopherol Homologues by Liquid−Liquid Extraction Using Ionic Liquids

2009 ◽  
Vol 48 (13) ◽  
pp. 6417-6422 ◽  
Author(s):  
Qiwei Yang ◽  
Huabin Xing ◽  
Yifeng Cao ◽  
Baogen Su ◽  
Yiwen Yang ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Liquid Extraction ◽  
Selective Separation ◽  
Liquid Liquid Extraction

Selective Separation of Hydroxide from Alkaline Nuclear Tank Waste by Liquid−Liquid Extraction with Weak Hydroxy Acids

2002 ◽  
Vol 36 (8) ◽  
pp. 1861-1867 ◽  
Author(s):  
C. Kevin Chambliss ◽  
Tamara J. Haverlock ◽  
Peter V. Bonnesen ◽  
Nancy L. Engle ◽  
Bruce A. Moyer
Keyword(s):  
Liquid Extraction ◽  
Selective Separation ◽  
Hydroxy Acids ◽  
Liquid Liquid Extraction ◽  
Tank Waste
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