Fe ultra-small particles anchored on carbon aerogels to enhance the oxygen reduction reaction in Zn-air batteries

2021 ◽  
Author(s):  
Jinjin Shi ◽  
Xinxin Shu ◽  
Chensheng Xiang ◽  
Hong Li ◽  
Yang Li ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Active Sites ◽  
Carbon Aerogel ◽  
Reduction Reaction ◽  
Superior Performance ◽  
Carbon Aerogels ◽  
Small Particles

The Fe–N4–O–Fe–N4 moiety as active sites in ultra-small Fe particles anchored on carbon aerogel exhibited superior performance towards the oxygen reduction reaction.

Single iron atoms stabilized by microporous defects of biomass-derived carbon aerogels as high-performance cathode electrocatalysts for aluminum–air batteries

2019 ◽  
Vol 7 (36) ◽  
pp. 20840-20846 ◽  
Author(s):  
Ting He ◽  
Yaqian Zhang ◽  
Yang Chen ◽  
Zhenzhu Zhang ◽  
Haiyan Wang ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
High Performance ◽  
Carbon Aerogel ◽  
Reduction Reaction ◽  
Alkaline Media ◽  
Single Atom ◽  
Carbon Aerogels ◽  
Cathode Catalyst ◽  
Hierarchical Porosity

Biomass-derived carbon aerogel with hierarchical porosity and FeN4 single atom sites outperforms platinum towards the oxygen reduction reaction in alkaline media and can be used as the cathode catalyst for aluminium–air batteries.

Facile solution synthesis of FeNx atom clusters supported on nitrogen-enriched graphene carbon aerogels with superb electrocatalytic performance toward the oxygen reduction reaction

2019 ◽  
Vol 7 (44) ◽  
pp. 25557-25566 ◽  
Author(s):  
Min Hong ◽  
Jianhang Nie ◽  
Xiaohua Zhang ◽  
Pengfei Zhang ◽  
Qin Meng ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Specific Activity ◽  
Carbon Aerogel ◽  
Reduction Reaction ◽  
Alkaline Media ◽  
High Mass ◽  
Carbon Aerogels ◽  
Solution Synthesis ◽  
Atom Clusters

FeNx atom clusters anchored on N-enriched graphene carbon aerogel exhibited high mass specific activity (840 mA mgFe−1 at 0.80 V), positive E1/2 (0.90 V vs. RHE), excellent durability and strong tolerance to methanol and SCN− in alkaline media.

scholarly journals Degradation and regeneration of Fe-Nx active sites for oxygen reduction reaction: the role of surface oxidation, Fe demetallation and local carbon microporosity

2021 ◽  
Author(s):  
Dongsheng Xia ◽  
Chenchen Yu ◽  
Yinghao Zhao ◽  
Yinping Wei ◽  
Haiyan Wu ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Active Sites ◽  
Proton Exchange Membrane ◽  
Degradation Mechanism ◽  
Surface Oxidation ◽  
Reduction Reaction ◽  
Proton Exchange ◽  
Exchange Membrane

The severe degradation of Fe-N-C electrocatalysts during long-term oxygen reduction reaction (ORR) has become a major obstacle for application in proton-exchange membrane fuel cells. Understanding the degradation mechanism and regeneration...

scholarly journals Superior FexN electrocatalyst derived from 1,1′-diacetylferrocene for oxygen reduction reaction in alkaline and acidic media

2020 ◽  
Vol 9 (1) ◽  
pp. 843-852
Author(s):  
Hunan Jiang ◽  
Jinyang Li ◽  
Mengni Liang ◽  
Hanpeng Deng ◽  
Zuowan Zhou
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Current Density ◽  
Active Sites ◽  
Reduction Reaction ◽  
Alkaline Media ◽  
Acidic Media ◽  
Onset Potential ◽  
Acidic And Alkaline Media ◽  
The Stability

AbstractAlthough Fe–N/C catalysts have received increasing attention in recent years for oxygen reduction reaction (ORR), it is still challenging to precisely control the active sites during the preparation. Herein, we report FexN@RGO catalysts with the size of 2–6 nm derived from the pyrolysis of graphene oxide and 1,1′-diacetylferrocene as C and Fe precursors under the NH3/Ar atmosphere as N source. The 1,1′-diacetylferrocene transforms to Fe3O4 at 600°C and transforms to Fe3N and Fe2N at 700°C and 800°C, respectively. The as-prepared FexN@RGO catalysts exhibited superior electrocatalytic activities in acidic and alkaline media compared with the commercial 10% Pt/C, in terms of electrochemical surface area, onset potential, half-wave potential, number of electrons transferred, kinetic current density, and exchange current density. In addition, the stability of FGN-8 also outperformed commercial 10% Pt/C after 10000 cycles, which demonstrates the as-prepared FexN@RGO as durable and active ORR catalysts in acidic media.

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