scholarly journals Paleoenvironmental considerations based on geochemistry and mineralogy of a Miocene lacustrine calcrete, southern Portugal

2019 ◽  
Vol 98 ◽  
pp. 06012
Author(s):  
Ana Luísa Rodrigues ◽  
Maria Isabel Dias ◽  
Maria Isabel Prudêncio ◽  
Fernando Rocha ◽  
Francisco Ruiz Muñoz ◽  
...  

A lacustrine carbonate facies has been investigated in Middle Miocene successions of the western side of the Moura-Marmelar basin, Southern Portugal in order to evaluate paleoenvironments in which carbonates formed, by using geochemistry and mineralogy. The studied formation corresponds to a recent unearthed section of a calcrete with an homogeneous carbonate facies comprising fine, whitish, and powdery material, and the only detected difference is a slightly hardness decrease towards the top, as well as an increase of weathered rock fragments (schist). The calcrete is calcium rich, even some magnesium enrichment was observed at the middle level, which is differentiated by a general depletion of all chemical elements, particularly REE, in both the bulk and clay-size fraction. Regarding the mineralogy, calcite prevails, and dolomite is only present in the middle level of the calcrete, together with a smectite enrichment, suggesting changes to more alkaline and low drainage, lacustrine and arid to semi-arid conditions.

Clay Minerals ◽  
2010 ◽  
Vol 45 (3) ◽  
pp. 353-370 ◽  
Author(s):  
R. Marques ◽  
A. Jorge ◽  
D. Franco ◽  
M. I. Dias ◽  
M. I. Prudêncio

AbstractMineralogical and chemical compositions of residual and sedimentary clays (bulk and <2 μm fraction) from the Nelas region (schist, aplite-pegmatites, granites and Tertiary sediments from both Mondego River margins), Portugal, were studied, aiming to establish indicators for raw materials in ancient ceramic provenance studies. The mineralogy of bulk material does not provide a clear distinction between samples. Among clay minerals, kaolinite dominates, except in the aplite-pegmatites where illite prevails. Smectite was only found in sediments of the left river bank.A more successful result was the geochemical differentiation of clay types. The weathered schist presents greater enrichment in Cr, whereas the clay fraction of aplite-pegmatites shows enrichment in all the chemical elements studied. The sediments and weathered granites are not easy to differentiate; the best geochemical indicators are U (lower contents in clay-size fraction of sediments) and REE patterns in both bulk and clay-size fraction.


2021 ◽  
Author(s):  
Catherine Breislin ◽  
Laura Galluccio ◽  
Kate Al Tameemi ◽  
Riaz Khan ◽  
Atef Abdelaal

Abstract Understanding reservoir architecture is key to comprehend the distribution of reservoir quality when evaluating a field's prospectivity. Renewed interest in the tight, gas-rich Middle Miocene anhydrite intervals (Anh-1, Anh-2, Anh-3, Anh-4 and Anh-6) by ADNOC has given new impetus to improving its reservoir characterisation. In this context, this study provides valuable new insights in geological knowledge at the field scale within a formation with limited existing studies. From a sedimentological point of view, the anhydrite layers of the Miocene Formation, Anh-1, Anh-2, Anh-3, Anh-4 and Anh-6 (which comprise three stacked sequences: Bur1, Bur2 and Bur3; Hardenbol et al., 1998), have comparable depositional organisation throughout the study area. Bur1 and Bur2 are characterised by an upward transition from intertidal-dominated deposits to low-energy inner ramp-dominated sedimentation displaying reasonably consistent thickness across the area. Bur3 deposits imply an initial upward deepening from an argillaceous intertidal-dominated to an argillaceous subtidal-dominated setting, followed by an upward shallowing into intertidal and supratidal sabkha-dominated environments. This Bur3 cycle thickens towards the south-east due to a possible deepening, resulting in the subtle increase in thickness of the subtidal and intertidal deposits occurring around the maximum-flooding surface. The interbedded relationship between the thin limestone and anhydrite layers within the intertidal and proximal inner ramp deposits impart strong permeability anisotropy, with the anhydrite acting as significant baffles to vertical fluid flow. A qualitative reservoir quality analysis, combining core sedimentology data from 10 wells, 331 CCA data points, 58 thin-sections and 10 SEM samples has identified that reservoir layers Anh-4 and Anh-6 contain the best porosity and permeability values, with the carbonate facies of the argillaceous-prone intertidal and distal inner ramp deposits hosting the best reservoir potential. Within these facies, the pore systems within the carbonate facies are impacted by varying degrees of dolomitisation and dissolution which enhance the pore system, and cementation (anhydrite and calcite), which degrade the pore system. The combination of these diagenetic phases results in the wide spread of porosity and permeability data observed. The integration of both the sedimentological features and diagenetic overprint of the Middle Miocene anhydrite intervals shows the fundamental role played by the depositional environment in its reservoir architecture. This study has revealed the carbonate-dominated depositional environment groups within the anhydrite stratigraphic layers likely host both the best storage capacity and flow potential. Within these carbonate-dominated layers, the thicker, homogenous carbonate deposits would be more conducive to vertical and lateral flow than thinner interbedded carbonates and anhydrites, which may present as baffles or barriers to vertical flow and create significant permeability anisotropy.


2019 ◽  
Vol 38 (5) ◽  
pp. 342-348 ◽  
Author(s):  
Guilherme Fernandes Vasquez ◽  
Marcio José Morschbacher ◽  
Camila Wense Dias dos Anjos ◽  
Yaro Moisés Parisek Silva ◽  
Vanessa Madrucci ◽  
...  

The deposition of the presalt section from Santos Basin began when Gondwana started to break up and South America and Africa were separating. Initial synrift carbonate deposits affected by relatively severe tectonic activity evolved to a lacustrine carbonate environment during the later stages of basin formation. Although the reservoirs are composed of carbonate rocks, the occurrence of faults and the intense colocation of igneous rocks served as a source of chemical elements uncommon in typical carbonate environments. Consequently, beyond the presence of different facies with complex textures and pore geometries, the presalt reservoir rocks present marked compositional and microstructural variability. Therefore, rock-physics modeling is used to understand and interpret the extensive laboratory measurements of P-wave velocities, S-wave velocities, and density that we have undertaken on the presalt carbonate cores from Santos Basin. We show that quartz and exotic clay minerals (such as stevensite and other magnesium-rich clay minerals), which have different values of elastic moduli and Poisson's ratio as compared to calcite and dolomite, may introduce noticeable “Poisson's reflectivity anomalies” on prestack seismic data. Moreover, although the authors concentrate their attention on composition, it will become clear that pore-space geometry also may influence seismic rock properties of presalt carbonate reservoirs.


1970 ◽  
Vol 14 ◽  
pp. 29-34
Author(s):  
Naresh Kazi Tamrakar

Seven fine aggregate samples from test pits driven at the river banks of the Kaligandaki River and banks of the contributingstreams around Kokethanti-Chhyo Bagar area were petrographically analysed as these will be used for concrete aggregates. Theaggregates had median grains size of 0.45-1.00 mm and were well graded. They were dominantly composed of carbonate rockfragments and the total QFL modes being Q14.81–28.87F0.63–4.58L66.55–84.15. All the samples were classified as medium-grainedcalc-lithic sands. Quartz grains were dominantly megaquartz. Some chert grains and few quartz grains occurring in siliceouslimestones were of microquartz.Considering deletereous constituents, the sample T1 had chert fragments. The sample T2 had high amount of micas suggestingits low workability. Silt/clay-grade size fraction was the deletereous material to all the samples and this fraction should be removedduring processing. The samples T2, T6 and T7 showed greater preferability among the samples as these had lower amount ofunsound rock fragments such as carbonaceous schists/phyllite, and other deletereous materials.DOI: http://dx.doi.org/10.3126/bdg.v14i0.5436Bulletin of the Department of Geology Vol.14 2011, pp. 29-34  


Author(s):  
S. A. Viczek ◽  
L. Kandlbauer ◽  
K. Khodier ◽  
A. Aldrian ◽  
R. Sarc

AbstractIn contemporary waste management, sampling of waste is essential whenever a specific parameter needs to be determined. Although sensor-based continuous analysis methods are being developed and enhanced, many parameters still require conventional analytics. Therefore, sampling procedures that provide representative samples of waste streams and enable sufficiently accurate analysis results are crucial. While Part I estimated the relative sampling variabilities for material classes in a replication experiment, Part II focuses on relative sampling variabilities for 30 chemical elements and the lower heating value of the same samples, i.e., 10 composite samples screened to yield 9 particle size classes (< 5 mm–400 mm). Variabilities < 20% were achieved for 39% of element-particle size class combinations but ranged up to 203.5%. When calculated for the original composite samples, variabilities < 20% were found for 57% of the analysis parameters. High variabilities were observed for elements that are expectedly subject to high constitutional heterogeneity. Besides depending on the element, relative sampling variabilities were found to depend on particle size and the mass of the particle size fraction in the sample. Furthermore, Part I and Part II results were combined, and the correlations between material composition and element concentrations in the particle size classes were interpreted and discussed. For interpretation purposes, log-ratios were calculated from the material compositions. They were used to build a regression model predicting element concentration based on material composition only. In most cases, a prediction accuracy of ± 20% of the expected value was reached, implying that a mathematical relationship exists.


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