Long-Aged Parmigiano Reggiano PDO: Trace Element Determination Targeted to Health

The concentrations of four health-related trace elements were measured using Atomic Absorption Spectroscopy in long-ripened (24- and 40-months) Parmigiano Reggiano (PR) PDO cheese, obtained from both summer and winter milk. To date, there are limited data on PR trace element concentrations, and no data about long-ripened cheese, especially when ripened for 40 months. Thus, the aim of this investigation is to determine chromium, manganese, selenium, and zinc concentrations, improving the available data on these trace elements and increasing knowledge of the biological properties of PR linked to their content in this cheese. The results show that 40-month ripened PR is a source of selenium and chromium, according to definitions under the European Regulation 1924/2006, as a 30 g cheese portion contains 11 ± 2 μg (summer milk) and 10 ± 1 μg (winter milk) of selenium and 8 ± 1 μg (summer and winter milk) of chromium, providing in excess of 8.25 and 6 μg per portion, respectively. This represents 15% of nutrient reference intake values for adults. These findings allow for the claim to be made that PR possesses the health properties ascribed to food sources of selenium and chromium according to European Regulation 432/2012.

STRUCTURAL FEATURES OF THE ASSEMBLIES OF THE JOINING OF TRAM RAILS TO ROAD COVERAGE

In the modern world, the priority is the development of clean urban electric transport. The constructive solutions used in the construction of the tram wheel in the past years are outdated and do not meet modern requirements. One of these problems is the destruction of asphalt coating in the places of road coverage to tram rails, which worsens the operational characteristics of tram crossings. The reasons for this problem can be attributed to the following: Not enough asphalt concrete near the rails; low adhesion of asphalt and metal from which rails are made; dynamic loads and vibrations arising from trams and motor transport; bad base of tram train and others. One of the options for increasing reliability and durability is to use as a road covering of tram plates. This solution is used in Ukraine and the European Union. German company RailBeton developed solutions for railway crossings - BetoCross. This system is a modular construction of reinforced concrete slabs, which are pulled together by steel strips. With the help of a system of fastenings and bearings, the flooring is fastened to rails, which provides vertical and horizontal stability of their position and stabilization under the influence of loading. To reduce the dynamic influence, the plates are based on reinforced concrete sleepers through the intermediate layers of the elastostomer. The load from the automobile transport is transferred to the broken beam. In addition to the positive features, the BetoCross system, due to the large number of connections, ties and bearings, requires frequent maintenance and maintenance. The Ukrainian state enterprise "Starokostiantyniv plant ZBSH" developed a similar technology, reinforced concrete plates with the help of a screw fastening through rubber gasket fixed to a special bridge type wallpaper. At a step of wallpaper 0,6 m the plate is attached to each wallpaper from two sides, with the length of the plate itself is 2,7 m. that is, on one plate there are five points of fastening on each side. Loads from the automobile transport, similar to the German technology, are transferred to the rubble balast and the basis. These technological solutions have found their application on railway crossings, and need some improvement for use in urban electric transport. The article reviews the constructive decision on the organization of the mentioned site, which is proposed by RS ENGINEERING in Kharkov. In the proposed solution instead of the crushed balast used monolithic reinforced concrete slab with supporting elements. The arising loads from the rolling stock and transport are transferred through the supporting elements to the concrete slab, which redistributes them on the rubble basis. As a road cover are used reinforced concrete plates covering RS-Slab. The plates are divided into 3 types: Road, interroad and external, which in turn have several sizes. The plates are bound to the supporting elements by means of screws in four points. To reduce dynamic influence between the film and the reference element, a rubber elastomer is laid. Depending on the size of the plates have different number of cutting sites. Also because of the design features possible option when the slab simultaneously relies not on all the supporting sites, these options should be taken into account when calculating the scale and choosing a class of concrete. This solution allows to solve the problems of road surface destruction on the side of the rails, keeps more load from transport, compared to asphalt. At the same time, there are factors that need to be studied in detail when designing and before implementing the solution in mass production. These include: Investigation of the influence of violation of standard assembly plates on the stress-deformed state of the element; determination of thickness and acceptable physical characteristics of the gasket on the plate supports; detailed development of a node for fixing plates. The use of reinforced concrete plates as a road coating has a number of advantages before asphalt concrete: Resistance to destruction on the rails; installation regardless of weather and temperature conditions; resistance to loads from trucks. At the same time, this decision has certain peculiarities that require detailed study, which is a branch of further research.

An overview of Structured Biosensors for Metal Ions Determination

The determination of metal ions is important for nutritional and toxicological assessment. Atomic spectrometric techniques are highly efficient for the determination of these species, but the high costs of acquisition and maintenance hinder the application of these techniques. Inexpensive alternatives for metallic element determination are based on dedicated biosensors. These devices mimic biological systems and convert biochemical processes into physical outputs and can be used for the sensitive and selective determination of chemical species such as cations. In this work, an overview of the proposed biosensors for metal ions determination was carried out considering the last 15 years of publications. Statistical data on the applications, response mechanisms, instrumentation designs, applications of nanomaterials, and multielement analysis are herein discussed.

Sampling and analysis of coarsely shredded mixed commercial waste. Part II: particle size-dependent element determination

In contemporary waste management, sampling of waste is essential whenever a specific parameter needs to be determined. Although sensor-based continuous analysis methods are being developed and enhanced, many parameters still require conventional analytics. Therefore, sampling procedures that provide representative samples of waste streams and enable sufficiently accurate analysis results are crucial. While Part I estimated the relative sampling variabilities for material classes in a replication experiment, Part II focuses on relative sampling variabilities for 30 chemical elements and the lower heating value of the same samples, i.e., 10 composite samples screened to yield 9 particle size classes (< 5 mm–400 mm). Variabilities < 20% were achieved for 39% of element-particle size class combinations but ranged up to 203.5%. When calculated for the original composite samples, variabilities < 20% were found for 57% of the analysis parameters. High variabilities were observed for elements that are expectedly subject to high constitutional heterogeneity. Besides depending on the element, relative sampling variabilities were found to depend on particle size and the mass of the particle size fraction in the sample. Furthermore, Part I and Part II results were combined, and the correlations between material composition and element concentrations in the particle size classes were interpreted and discussed. For interpretation purposes, log-ratios were calculated from the material compositions. They were used to build a regression model predicting element concentration based on material composition only. In most cases, a prediction accuracy of ± 20% of the expected value was reached, implying that a mathematical relationship exists.

Applications of Metal Complexes Dyes in Analytical Chemistry

Trace elements, especially heavy metals, are considered to be one of the main sources of pollution in the environment since they have a significant effect on ecological quality. Commonly, the analytical methods for the determination of trace metals are the spectrometry techniques. While, the electroanalytical methods are recognized as a powerful technique for trace metals owing to its remarkable sensitivity, relatively inexpensive instrumentation, ability for multi-element determination at trace and ultra trace level. New alternative electrode materials are highly desired to develop sensitive stripping sensors for meeting the growing demands for on-site environmental monitoring. Dyes aromatic heterocyclic compound, used in food, textile and cosmetic industries has been used for spectrophotometric determination of metals. In electrochemitry, methods for metals determination based on their complexation with dyes were proposed. In this chapter, a brief summary of spectrometry methods and electrochemical sensors for heavy metals detection based on the formation of metals dyes complexes is presented.

Case study: Correlation between boundary and finite element determination of large silencer transmission loss

Silencers used in the power generation industry generally have large ducts entering and leaving the silencer. With large cross-sectional dimensions, the plane wave cutoff frequency will be exceeded at a low frequency so that transmission loss can no longer be evaluated by assuming constant sound pressure over a cross-section. More sophisticated calculation and processing approaches are necessary. In this research, the boundary element method is used in conjunction with a reciprocal identity method to determine the transmission loss for rectangular and circular cross-sections: the two configurations that cover most real-world designs. The boundary element method is compared to a finite element method strategy where the transmission loss is determined using an automatically matched layer boundary condition at the inlet and outlet. This approach can be used in most commercial software. Although these two approaches have little in common, transmission loss results compare well with one other. Validation by comparison is helpful because analytical solutions are only available for simple axisymmetric cases. Methods are compared for practical configurations like parallel-baffle silencers and reactive silencers.