scholarly journals Sodium Persulfate (Na2S2O8)

SynOpen ◽  
2021 ◽  
Author(s):  
Tereza Cristina Santos Evangelista ◽  
Sabrina B. Ferreira

Sodium persulfate is an environmentally friendly inorganic compound commonly used as an oxidizing agent in chemistry. This reagent undergoes homolytic cleavage in solutions, affording sulfate radical anions that can present several applications. Recently, the SO4.- has been applied in diverse processes, such as the degradation of antibiotics and dyes in wastewater treatment. 1 In organic synthesis, sodium persulfate can be used as an oxidant in transition-metal catalyzed reactions or as an oxidative species in crucial steps in metal-free reactions.2,3 Na2S2O8 is an inexpensive oxidant that is stable and easy to handle, making it a good reagent choice for several strategic synthetic transformations.4 It is synthesized industrially through an electrolytic oxidation process from sodium hydrogen sulfate,5 and recent applications for this compound are presented herein.

2006 ◽  
Vol 78 (2) ◽  
pp. vi
Author(s):  
Alexandre Alexakis

The 13th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-13<http://omcos13.unige.ch/>) was held in Geneva, Switzerland, from 17-21 July 2005.The aim of this series of symposia is to bring together chemists from academia and industry to define and discuss the most recent developments in the areas of catalysis, new organometallic reagents and reactions, and new materials chemistry. In 2001, Sharpless, Noyori, and Knowles received the Nobel Prize for their work in this area of chemistry; and the high profile has been maintained by the award of the 2005 Nobel Prize in Chemistry to Chauvin, Grubbs, and Schrock for the development of the metathesis method in organic synthesis.OMCOS-13 had a record number of nearly 1200 participants from 41 countries, and there was an encouragingly high proportion of young scientists in attendance. Very strong Asian participation at this conference reflected the outstanding level of research and leadership in this field from countries such as Japan, China, South Korea, and Taiwan.Prof. Shengming Ma, from the Shanghai Institute of Organic Chemistry of the Chinese Academy of Science and the Department of Chemistry, Zhejiang University, China received the OMCOS-13 Award (sponsored by the Yen Chuang Foundation and Springer Verlag). The prize was awarded for his creative research contributions in the field of transition-metal-catalyzed reactions of allenes.Apart from the OMCOS-13 Award lecture, there were 23 plenary lectures and 20 oral communications that dealt with aspects of reactivity and chemoselectivity of main group and transition-metal organometallics. Stereoselectivity issues also figured prominently with a particular emphasis on asymmetric synthesis and catalysis. Mechanistic insights, new reagents for synthesis, new catalyst and ligand design, and ligand effects were other important topics.The quality of the 620 posters that were on display during the entire conference was also outstanding. This extraordinary poster session was highlighted with the Monday evening "poster party" and culminated in the awarding of 37 poster prizes.OMCOS-13 was held as a single session conference in an impressive lecture theater and a large exhibition area in the center of Geneva at a superb lakefront location. It was a fitting venue for the firstclass science that was presented.Thirty-seven lecturers of OMCOS-13 present their chemistry in this issue of Pure and Applied Chemistry and provide a fine recollection of last summer's conference. The 14th edition of OMCOS will be held in Nara, Japan (2-6 August 2007) under the chairmanship of Prof. Koichiro Oshima.Alexandre AlexakisOMCOS-13 Co-chairE. Peter KündigOMCOS-13 Co-chair


2017 ◽  
Vol 14 (6) ◽  
pp. 810-864 ◽  
Author(s):  
Hamideh Aghahosseini ◽  
Ali Ramazani ◽  
Farideh Gouranlou ◽  
Sang Woo Joo

Background: Nanoreactors technology represents a promising tool for efficient and selective organic synthesis typically under “green” and sustainable reaction conditions. These structures with generating a confined reaction environment to accommodate that both reactants and catalysts can change the reaction pathways and induce new activities and selectivities. Objective: The paper reviews literature examples in which nanoreactors were employed in various types of organic and metal catalyzed reactions including multicomponent reactions, palladium-catalyzed coupling reactions, olefin metathesis, aza-Cope rearrangement, allylic alcohol isomerization, cyclization reactions, ring opening reactions, halogenation reactions, hydrolysis reactions, hydroformylation reactions, cascade reactions, addition reactions, oxidation reactions and reduction reactions. The reactions&apos; survey is accompanied with the explanation of structure and performance of nanoreactors that are applied there. Conclusion: The availability of comprehensive information about the role of nanoreactors technology in green organic synthesis and investigation of different aspects of them such as their structures, mechanisms and synthetic utility can assist researchers in designing the greener approaches in organic synthesis.


2021 ◽  
Author(s):  
Jay Soni ◽  
Pankaj Teli ◽  
Nusrat Sahiba ◽  
Ayushi Sethiya ◽  
Shikha Agarwal

Oxidation of alkenes is an important reaction in academia, industry and science as it is used to develop epoxides, carbonyls, allylic compounds, 1,2-diols, etc. Metal catalyzed oxidation of alkenes has aroused as a significant tool in modern organic synthesis. Several techniques are available; however some of them suffer from few shortcomings viz. high cost, toxic nature, harsh reaction condition, solid waste generation, etc. In view of these drawbacks, green oxidants i.e. O2, H2O2, TBHP, etc. have shown noteworthy prospects due to their nature, low cost, high atom economy and high sustainability in metal catalyzed reactions. This chapter highlights the metal catalyzed green oxidation of alkenes and shall provide new strategies for the functionalization and transformation of alkenes.


2016 ◽  
Vol 14 (24) ◽  
pp. 5377-5389 ◽  
Author(s):  
Adriana S. Grossmann ◽  
Thomas Magauer

Trihaloethenes are versatile C2-building blocks that can be simply modified via addition, elimination and transition metal-catalyzed reactions.


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