Recent Advances on the Application of Electrocyclic Reactions in Complex Natural Product Synthesis
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The electrocyclic reaction is one of the most powerful tools for the construction of complex polycyclic scaffolds in a highly stereocontrolled fashion. In this review, recent advances in its application in the total synthesis of representative natural products are discussed, with the aim of providing a complement to existing reviews.1 Introduction2 4π Electrocyclization2.1 Neutral 4π Electrocyclization2.2 Cationic 4π Electrocyclization3 6π Electrocyclization3.1 All-Carbon 6π Electrocyclization3.2 Oxa-6π Electrocyclization3.3 Aza-6π Electrocyclization3.4 Retro-6π Electrocyclization4 8π Electrocyclization5 Conclusion and Outlook
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2019 ◽
Vol 17
(31)
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pp. 7270-7292
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2021 ◽
Vol 16
(10)
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pp. 1934578X2110498
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2015 ◽
Vol 13
(23)
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pp. 6419-6431
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