Determination of Perchlorate Rejection and Associated Inorganic Fouling (Scaling) for Reverse Osmosis and Nanofiltration Membranes under Various Operating Conditions

2005 ◽  
Vol 131 (5) ◽  
pp. 726-733 ◽  
Author(s):  
Jaekyung Yoon ◽  
Yeomin Yoon ◽  
Gary Amy ◽  
Namguk Her
Author(s):  
D. Goyal ◽  
A. H. King

TEM images of cracks have been found to give rise to a moiré fringe type of contrast. It is apparent that the moire fringe contrast is observed because of the presence of a fault in a perfect crystal, and is characteristic of the fault geometry and the diffracting conditions in the TEM. Various studies have reported that the moire fringe contrast observed due to the presence of a crack in an otherwise perfect crystal is distinctive of the mode of crack. This paper describes a technique to study the geometry and mode of the cracks by comparing the images they produce in the TEM because of the effect that their displacement fields have on the diffraction of electrons by the crystal (containing a crack) with the corresponding theoretical images. In order to formulate a means of matching experimental images with theoretical ones, displacement fields of dislocations present (if any) in the vicinity of the crack are not considered, only the effect of the displacement field of the crack is considered.The theoretical images are obtained using a computer program based on the two beam approximation of the dynamical theory of diffraction contrast for an imperfect crystal. The procedures for the determination of the various parameters involved in these computations have been well documented. There are three basic modes of crack. Preliminary studies were carried out considering the simplest form of crack geometries, i. e., mode I, II, III and the mixed modes, with orthogonal crack geometries. It was found that the contrast obtained from each mode is very distinct. The effect of variation of operating conditions such as diffracting vector (), the deviation parameter (ω), the electron beam direction () and the displacement vector were studied. It has been found that any small change in the above parameters can result in a drastic change in the contrast. The most important parameter for the matching of the theoretical and the experimental images was found to be the determination of the geometry of the crack under consideration. In order to be able to simulate the crack image shown in Figure 1, the crack geometry was modified from a orthogonal geometry to one with a crack tip inclined to the original crack front. The variation in the crack tip direction resulted in the variation of the displacement vector also. Figure 1 is a cross-sectional micrograph of a silicon wafer with a chromium film on top, showing a crack in the silicon.


2016 ◽  
pp. 377-380
Author(s):  
Marc André Théoleyre ◽  
Anne Gonin ◽  
Dominique Paillat

Regeneration of resins used for decolorization of sugar solutions is done with concentrated salt solutions. Nanofiltration membranes have been proven effective, in terms of industrial efficiency in decreasing salt consumption. More than 90% of the salt that is necessary for regeneration can be recycled through a combination of direct recycling of intermediate eluates, the separation of colored compounds by use of very selective nanofiltration membranes and a system to concentrate salty permeates. According to specific local conditions on energy supply and cost, the concentration of salty permeates can be either a multiple effect evaporator or a combination of electrodialysis and reverse osmosis. The desalted color compound solution is sent to the molasses, limiting considerably the effluent to be treated. Starting from a liquor of 800 IU, the water requirement is limited to less than 100 L/t of sugar and the amount of wastewater can be reduced to less than 40 L/t of sugar.


1996 ◽  
Vol 34 (9) ◽  
pp. 149-156 ◽  
Author(s):  
C. Ratanatamskul ◽  
K. Yamamoto ◽  
T. Urase ◽  
S. Ohgaki

The recent development of new generation LPRO or nanofiltration membranes have received attraction for application in the field of wastewater and water treatment through an increasingly stringent regulation for drinking purpose and water reclamation. In this research, the application on treatment of anionic pollutants (nitrate, nitrite, phosphate, sulfate and chloride ions) have been investigated as functions of transmembrane pressure, crossflow velocity and temperature under very much lower pressure operation range (0.49 to 0.03 MPa) than any other previous research used to do. Negative rejection was also observed under very much low range of operating pressure in the case of membrane type NTR-7250. Moreover, the extended Nernst-Planck model was used for analysis of the experimental data of the rejection of nitrate, nitrite and chloride ions in single solution by considering effective charged density of the membranes.


Author(s):  
W. Dempster ◽  
C. K. Lee ◽  
J. Deans

The design of safety relief valves depends on knowledge of the expected force-lift and flow-lift characteristics at the desired operating conditions of the valve. During valve opening the flow conditions change from seal-leakage type flows to combinations of sub-sonic and supersonic flows It is these highly compressible flow conditions that control the force and flow lift characteristics. This paper reports the use of computational fluid dynamics techniques to investigate the valve characteristics for a conventional spring operated 1/4” safety relief valve designed for gases operating between 10 and 30 bar. The force and flow magnitudes are highly dependent on the lift and geometry of the valve and these characteristics are explained with the aid of the detailed information available from the CFD analysis. Experimental determination of the force and flow lift conditions has also been carried out and a comparison indicates good correspondence between the predictions and the experiment. However, attention requires to be paid to specific aspects of the geometry modeling including corner radii and edge chamfers to ensure satisfactory prediction.


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