We propose the solitary wave model of superfluidity. According to harmonic oscillator model of quasi-lattice of liquid, it is proven that superfluid domains (SD) exist in He liquid, in which the resistanceless motion of liquid molecules (LM) can be carry out. At temperature lower than T c, all SD connect with each other and superflow in whole liquid takes place. Applying Toda's potential, under continuous conditions, we obtain the motion equation of LM, and its exact solution. Substituting these results into Schrödinger equation of LM, we can prove the existence of solitary waves of LM and the non-linear Schrödinger equation of LM. The motion of solitons of LM leads to a superflow. On the basis of coherent condition of wave of LM, we derive the formula of transition temperature Tc of superfluidity. From the formula, the relation of the onset temperature Tc of superflow on inert layers is explained.