Unimolecular decomposition of tetrazine-N-oxide based high nitrogen content energetic materials from excited electronic states

2009 ◽  
Vol 131 (19) ◽  
pp. 194304 ◽  
Author(s):  
A. Bhattacharya ◽  
Y. Q. Guo ◽  
E. R. Bernstein
2020 ◽  
Vol 8 (47) ◽  
pp. 25035-25039
Author(s):  
Zhen Dong ◽  
Zhiwen Ye

Three types of energetic materials with high nitrogen content, high decomposition temperature and good detonation properties were obtained.


2011 ◽  
Vol 2011 ◽  
pp. 1-5 ◽  
Author(s):  
Bo Tang ◽  
Jia-Hai Ye ◽  
Xue-Hai Ju

Density functional computations were performed on two tetracoordinated Ni(II) complexes as high nitrogen content energetic materials (1: dinickel bishydrazine ter[(1H-Tetrazol-3-yl)methan-3yl]-1H-tetrazole and 2: dinickel tetraazide ter[(1H-Tetrazol-3-yl)methan-3yl]-1H-tetrazolate). The geometrical structures, relative stabilities and sensitivities, and thermodynamic properties of the complexes were investigated. The energy gaps of frontier molecular orbital (HOMO and LUMO) and vibrational spectroscopies were also examined. There are minor Jahn-Teller distortions in both complexes 1 and 2, with two long Ni–N bond lengths and two short ones. The enthalpies of combustion for both complexes are over 3600 kJ/mol. The N–N bond lengths in the moieties of hydrazine and azide ligands increase in the coordination process compared to those of the isolated molecules.


RSC Advances ◽  
2020 ◽  
Vol 10 (22) ◽  
pp. 13185-13195 ◽  
Author(s):  
Keyu Pu ◽  
Linyuan Wang ◽  
Jian Liu ◽  
Kai Zhong

Bis-azole derivatives are a new class of energetic materials with features that include high nitrogen content, high heat of formation (HOF), high detonation performance and insensitivity to external stimuli.


EDIS ◽  
2013 ◽  
Vol 2013 (11) ◽  
Author(s):  
Michael A. Davis ◽  
Doug R. Sloan ◽  
Gerald Kidder ◽  
R. D. Jacobs

Animal manures have been used as natural crop fertilizers for centuries. Because of poultry manure’s high nitrogen content, it has long been recognized as one of the most desirable manures. Besides fertilizing crops, manures also supply other essential plant nutrients and serve as a soil amendment by adding organic matter, which helps improve the soil’s moisture and nutrient retention. Organic matter persistence will vary with temperature, drainage, rainfall, and other environmental factors. This 2-page fact sheet was written by Michael A. Davis, D.R. Sloan, Gerald Kidder, and R.D. Jacobs, and published by the UF Department of Animal Science, November 2013. http://edis.ifas.ufl.edu/aa205


2019 ◽  
Vol 33 (2) ◽  
pp. 1467-1472 ◽  
Author(s):  
Minh-Tuan Nguyen ◽  
Gerhard D. Pirngruber ◽  
Florian Albrieux ◽  
Fabien Chainet ◽  
Melaz Tayakout-Fayolle ◽  
...  

2005 ◽  
Vol 128 (2) ◽  
pp. 99-103 ◽  
Author(s):  
Alberto Bahillo ◽  
Lourdes Armesto ◽  
Andrés Cabanillas ◽  
Juan Otero

Transformation of hide (animal skins) into leather is a complicated process during which significant amounts of wastes are generated. Fluidized bed combustion has been extended to burn different wastes that have problems with their disposal showing its technical feasibility. Considering the characteristics of the leather waste, especially the heating value (12.5-21MJ∕kg), it is a fairly good fuel. Moreover, leather waste has a high volatile matter, 65%, similar to other biomasses and unusual high nitrogen content, 14%. The aim of this work was to study leather wastes combustion in fluidized bed presenting experimental results regarding NOx and N2O emissions. A series of experiments were carried out in a fluidized bed pilot plant to understand the importance of operating parameters such as furnace temperature, oxygen content in gases, staged combustion and residence time on the NOx and N2O emission level. Despite having high nitrogen content, low conversion of N-fuel to NOx and N2O was measured during the combustion of leather waste in BFB. Bed temperature and oxygen content were found as the most important single parameters on N2O emission and only oxygen content has a significant influence on NOx emission. Leather waste exhibits a great NOx∕O2 trend; NOx emission decreases as the oxygen concentration decreases while the effect of combustion temperature on NOx is insignificant. Staged combustion does not give a reduction in NOx.


1985 ◽  
Vol 65 (4) ◽  
pp. 897-903 ◽  
Author(s):  
D. M. VEIRA ◽  
M. IVAN ◽  
G. BUTLER ◽  
J. G. PROULX

Following weaning at 6–7 mo of age, 36 beef steers were used to determine production responses when grass silage was supplemented with barley or fishmeal. The silage was made from direct-cut, formic- acid-treated grass harvested from a mixed sward and had a high nitrogen content but poor fermentation characteristics. The silage was fed ad libitum for 98 days either alone or supplemented with 500 g fishmeal or 500 g barley per day. Both fishmeal and barley increased total dry matter intake (P < 0.01) by an amount equivalent to the quantity of supplement offered but had no effect on silage intake (P > 0.05). Steers fed the fishmeal grew substantially faster than either the barley (0.53 kg/day) or unsupplemented (0.54 kg/day) groups (P < 0.01). Fishmeal supplementation resulted in a large reduction (35%) in the amount of feed required per kilogram of gain. Key words: Cattle, grass silage, fishmeal, growth


2009 ◽  
Vol 48 (42) ◽  
pp. 7884-7887 ◽  
Author(s):  
Xin Jin ◽  
Veerappan V. Balasubramanian ◽  
Sakthivel T. Selvan ◽  
Dhanashri P. Sawant ◽  
Murugulla A. Chari ◽  
...  

2010 ◽  
Vol 2010 (4) ◽  
pp. 346-353
Author(s):  
V. F. Terent’ev ◽  
I. O. Bannykh ◽  
E. V. Blinov ◽  
M. E. Prutskov ◽  
A. G. Kolmakov ◽  
...  

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