Powder samples of (Ca,Sr)TiO3:Er were prepared by a solid-state reaction method. Photoluminescence due to f-f transitions of Er3+ was not induced by band-gap excitation of (Ca,Sr)TiO3 but by f-f transitions of Er3+. An electroluminescent device in which thin films of Ca0.6Sr0.4TiO3:Er and SnO2:Sb are stacked alternately was prepared by sol-gel and spin-coating methods. Very weak electroluminescence due to f-f transition of Er3+ was observed in the device.