It is proposed to use the methods of applied optical spectroscopy to solve the problem of control and diagnostics of gaseous hydrocarbon fuel combustion in this work. The results of an experimental study of spectroscopic informative parameters characterizing the propane combustion process are presented for three modes: combustion of pure propane without air supply, stoichiometric combustion and combustion with a change in the amount of supplied air relative to stoichiometric combustion. As a result of the experiment, it was found that the most intense bands in the emission spectrum of the flame arising from the combustion of propane correspond to the spectral bands of radicals of combustion products: OH, CH, and C2. While the intensities of various systems of bands in the flame spectrum depend significantly on the composition of the combustible mixture.