A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple‐Point Temperature to 1100 K at Pressures up to 800 MPa

1996 ◽  
Vol 25 (6) ◽  
pp. 1509-1596 ◽  
Author(s):  
Roland Span ◽  
Wolfgang Wagner
2020 ◽  
Vol 66 (5 Sept-Oct) ◽  
pp. 656
Author(s):  
J. M. Marín-García ◽  
A. Romero-Martínez ◽  
F. De J. Guevara-Rodríguez

A non-cubic equation of state is used to predict the solid-liquid, solid-vapor and liquid-vapor coexistences of pure substances. The equation of state is obtained using as input data the critical point, the boiling temperature, the triple point temperature and the acentric factor of the substance. In this work, some examples of phase diagrams predicted with the equation of state are reported in order to show its capabilities. Finally, a database with the parameters for different pure substances is presented.


2022 ◽  
Vol 43 (3) ◽  
Author(s):  
Monika Thol ◽  
Florian Fenkl ◽  
Eric W. Lemmon

AbstractA fundamental equation of state in terms of the Helmholtz energy is presented for chloroethene (vinyl chloride). Due to its fundamental nature, it can be used to consistently calculate all thermodynamic state properties in the fluid region. Based on the underlying experimental database, it is valid from the triple-point temperature 119.31 K to 430 K with a maximum pressure of 100 MPa. In addition to the accurate reproduction of experimental data, correct extrapolation behavior during the development of the equation was attained. This enables the equation to be applied in modern mixture frameworks.


1983 ◽  
Vol 29 (7) ◽  
pp. 1380-1384 ◽  
Author(s):  
B W Mangum

Abstract In an investigation of the melting and freezing behavior of succinonitrile, the triple-point temperature was determined to be 58.0805 degrees C, with an estimated uncertainty of +/- 0.0015 degrees C relative to the International Practical Temperature Scale of 1968 (IPTS-68). The triple-point temperature of this material is evaluated as a temperature-fixed point, and some clinical laboratory applications of this fixed point are proposed. In conjunction with the gallium and ice points, the availability of succinonitrile permits thermistor thermometers to be calibrated accurately and easily on the IPTS-68.


2016 ◽  
Vol 73 (6) ◽  
pp. 2577-2583
Author(s):  
David M. Romps

Abstract A standard convention in moist thermodynamics, adopted by D. M. Romps and others, is to set the specific energy and entropy of dry air and liquid water to zero at the triple-point temperature and pressure. P. Marquet claims that this convention leads to physically incorrect results. To support this claim, Marquet presents numerical calculations of a lifted parcel. It is shown here that the claim is false and that the numerical calculations of Marquet are in error. In the context of a simple two-phase thermodynamic system, an analysis is presented here of the freedoms one has to choose additive constants in the definitions of energy and entropy. Many other misconceptions are corrected as well.


2017 ◽  
Vol 38 (6) ◽  
Author(s):  
B. Kołodziej ◽  
A. Kowal ◽  
L. Lipiński ◽  
H. Manuszkiewicz ◽  
A. Szmyrka-Grzebyk

2013 ◽  
Vol 62 (16) ◽  
pp. 163301
Author(s):  
Liu Jiang-Ping ◽  
Bi Peng ◽  
Lei Hai-Le ◽  
Li Jun ◽  
Wei Jian-Jun

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