CaCu3(Ti1-xZrx)O12 ceramics (x = 0.02, 0.04, 0.06, 0.08) were prepared by the conventional
solid-state reaction method. Phase compositions, microstructure and dielectric properties were examined
by XRD, SEM and impedance spectroscopy, respectively. The experimental results indicated that there is
no obvious effect on microstructure characteristic by substituting Zr4+ for Ti4+. It was found that the
values of the dielectric constant for all of the samples dropped into the order of 102, which is significantly
lower than the order of 105 that of normally reported in the literature. It was suggested that the presence of
impurity phases played an important role for the degeneracy of dielectric properties.