Structural and Dielectric Properties of BaBi2Nb2O9Ferroelectric Ceramic Powders by a Solid State Reaction Method

2014 ◽  
Vol 460 (1) ◽  
pp. 57-67 ◽  
Author(s):  
R. Ramaraghavulu ◽  
S. Buddhudu
2019 ◽  
Vol 13 (2) ◽  
pp. 164-172
Author(s):  
Rashmi Negi ◽  
Mallam Chandrasekhar ◽  
Pavan Kumar

(1-x)BaTiO3-xCaCu3Ti4O12 ceramic powders (where x = 0, 0.02, 0.04, 0.06, 0.08 and 1) were synthesized by solid state reaction method and sintered at up to 1250?C. Phase formation, elemental composition and microstructure of all the samples were investigated by XRD, EDX and FESEM, respectively. The BT-CCTO ceramic samples corresponding to x = 0.04 content showed the best dielectric properties. The improvement of dielectric properties was attributed to the presence of oxygen vacancies. Ferroelectricity was retained for CCTO content up to x = 0.06.


2007 ◽  
Vol 336-338 ◽  
pp. 272-274
Author(s):  
S.S. Cheng ◽  
J. Luo ◽  
Zhao Xian Xiong

Microwave ceramics of Ba(Mg0.2/3Zn0.8/3Nb2/3)O3 and Ba1-xSrx(Mg0.2/3Zn0.8/3Nb2/3)O3 were synthesized with conventional solid-state reaction method. Dielectric properties of the samples were studied as functions of compositions and sintering temperatures. Experimental results show that a higher Q×f value is reached by substituting Zn ions with Mg ions and a near-zero temperature coefficient of resonant frequency is obtained by replacing Ba ions with Sr ions.


2013 ◽  
Vol 675 ◽  
pp. 200-204
Author(s):  
Fei Shi ◽  
Peng Cheng Du ◽  
Jing Xiao Liu ◽  
Ji Wei Wu ◽  
De Qing Chen ◽  
...  

The Mg2SiO4-MgTiO3-CaTiO3 composite dielectric ceramics with different Mg2SiO4 addition amounts were prepared by solid state reaction method. The effects of Mg2SiO4 addition amounts on the microstructure and dielectric properties as well as sintering temperature of xMg2SiO4-(0.95-x)MgTiO3-0.05CaTiO3 (abbreviated as xMSTC, 0.25≦x≦0.75) composite ceramics were investigated. The results indicated that the sintering temperature of MgTiO3-CaTiO3 based ceramics with Mg2SiO4 addition could be lowered effectively to 1320~1340°C, and the dielectric constant decreased and dielectric loss increased gradually with the increase of Mg2SiO4 content. The 0.45MSTC ceramics containing 45 wt% Mg2SiO4 and sintered at 1340°C showed desirable dielectric properties with dielectric constant εr=13.3,dielectric loss tanδ=4.5×10-4 and temperature coefficient of relative permittivity τε =10 ppm/°C.


2019 ◽  
Vol 48 (27) ◽  
pp. 9925-9929 ◽  
Author(s):  
Guobiao Li ◽  
Shouqiang Huang ◽  
Yanwen Shen ◽  
Ziyang Lou ◽  
Haiping Yuan ◽  
...  

A novel efficient near-infrared photocatalyst of glass-ceramic/TiO2 was synthesized by a completely waterless solid-state reaction method, with optically active center CaF2 in glass-ceramic powders and anatase-TiO2 as the superficial coating.


2010 ◽  
Vol 2010 ◽  
pp. 1-6 ◽  
Author(s):  
Xiangyu Mao ◽  
Wei Wang ◽  
Hui Sun ◽  
Xiaobing Chen

The grain-oriented Bi4Ti3O12(BIT) samples were prepared by the solid-state reaction method with a multicalcination process. The grain-oriented BIT samples exhibit anisotropic structural, ferroelectric, piezoelectric, and dielectric properties. The remanent polarization (2Pr) and the piezoelectric constant (d33) ofa/b- andc-direction BIT ceramics are 49.5 μC cm−2, 22.2 pC N−1and 6.7 μC cm−26.9 pC N−1, respectively. The dielectric anomalies of samples are observed around 157 K and 232 K. The dielectric anomalies at around 157 K are related to oxygen vacancies. The activation energy of the dielectric relaxation of this anomaly is estimated to be 1.36 eV. Another dielectric anomaly at around 232 K is related to polarizable domains and the viscous motion of domain walls.


2008 ◽  
Vol 368-372 ◽  
pp. 129-131
Author(s):  
Yong He ◽  
Ke Pi Chen ◽  
Dong Yu Liu ◽  
Zong De Liu

CaCu3(Ti1-xZrx)O12 ceramics (x = 0.02, 0.04, 0.06, 0.08) were prepared by the conventional solid-state reaction method. Phase compositions, microstructure and dielectric properties were examined by XRD, SEM and impedance spectroscopy, respectively. The experimental results indicated that there is no obvious effect on microstructure characteristic by substituting Zr4+ for Ti4+. It was found that the values of the dielectric constant for all of the samples dropped into the order of 102, which is significantly lower than the order of 105 that of normally reported in the literature. It was suggested that the presence of impurity phases played an important role for the degeneracy of dielectric properties.


RSC Advances ◽  
2014 ◽  
Vol 4 (87) ◽  
pp. 46704-46709 ◽  
Author(s):  
Xuzhong Zuo ◽  
Jie Yang ◽  
Bin Yuan ◽  
Dongpo Song ◽  
Xianwu Tang ◽  
...  

The n = 5 Aurivillius phase ceramics Bi6Fe2−xMnxTi3O18 (BFMTO) (0 ≤ x ≤ 0.8) were synthesized with a conventional solid-state reaction method.


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