Effects of Partial Crystallization on the Glassy Slowdown of Aqueous Ethylene Glycol Solutions

Author(s):  
Melanie Reuhl ◽  
Philipp Monnard ◽  
Michael Vogel
1979 ◽  
Vol 57 (14) ◽  
pp. 1801-1803 ◽  
Author(s):  
Tibor Rabockai

The electrochemical behavior of the Pb2+/Pb(Hg) system in aqueous and aqueous ethylene glycol solutions is studied in the temperature range of 20.0 to 50.0 °C by means of current reversal chronopotentiometry. It is shown that the reduction of Pb2+ ion is reversible and that kinetic or catalytic complications are not present. The value of dE1/2/dT is −0.6 mV/deg in the aqueous solution and −0.5 mV/deg in the solution with 56% (w/w) or higher concentrations of the organic solvent. In the above concentration range of ethylene glycol the activation energies of diffusion and viscosity vary from 4.3 × 103 to 7.2 × 103 cal mol−1 and from 3.7 × 103 to 6.7 × 103 cal mol−1, respectively. For all solutions the solvodynamic mean radius of the diffusing species remains constant within the experimental error, suggesting that the diffusing species is always the hydrated Pb2+ ion.


2013 ◽  
Vol 99 ◽  
pp. 184-190 ◽  
Author(s):  
Minjun Cha ◽  
Kyuchul Shin ◽  
Juneyoung Kim ◽  
Daejun Chang ◽  
Yutaek Seo ◽  
...  

Author(s):  
Deepti Tikariha ◽  
Kallol K. Ghosh ◽  
Nadia Barbero ◽  
Pierluigi Quagliotto ◽  
Soumen Ghosh

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