Experimental Analyses of the Additive Effect of TiO2 Nanoparticles on the Tribological Properties of Lubricating Oil

Titanium dioxide (TiO2) is a promising lubricant additive for enhanced engine efficiency. In this study, pure base engine oil 10 W-30 was improved with titanium dioxide (TiO2) nanoparticles at different concentrations and experimentally evaluated with the scope of tribological behavior improvement. The tribological tests were performed at ambient temperature as well as at 75°C using a four ball tribometer for 30 minutes. Due to their small particle size (approx. 21 nm), the TiO2 nanoparticles were properly dispersed in oil based on optical microscopy evaluation. The tribological results indicate that the friction coefficient of engine oil with 0.075 wt.% TiO2 reached 0.05 at 75°C, which was much lower that of pure oil (1.20), and at room temperature (23°C), it decreased from 1.8 for pure oil to 0.4 for oil with 0.075 wt.% TiO2 due to the formation of a stable tribofilm formed by the MoS2, MoO3, FeS, and FeSO4 composite within the wear track. The lowest wear volume was measured on samples tested at 75°C for the oil with 0.075 wt.% TiO2. The TiO2 additive lubricant effect on the tribofilm properties led to a decrease in friction and wear at an operating temperature of 75°C. The main objective of the paper is to present the recent progress and, consequently, to develop a comprehensive understanding of the tribological behavior of engine oil mixed with TiO2 nanoparticles.

Design, Actuation, Experimental Setup and Testing of a 4-Cylinder Gasoline Spark Ignited Variable Compression Ratio Engine

The thermal efficiency of an Otto cycle engine is directly related to the compression ratio (CR). However, in a spark-ignited engine, the CR is often restricted by full load knock, thus limiting part load efficiency. A proof of concept design and experimental study has been conducted on a 4-cylinder naturally aspirated spark-ignited (SI) engine whereby a four-bar linkage mechanism has been implemented to vary the CR. The base engine selected was a production 2.0L GM-LNF SI 4-cylinder engine with a stock CR of 9.2:1 and with a bore and stroke of 86mm and 86mm, respectively. The engine was modified to allow the centerline axis of rotation of the crankshaft to translate in an arc about a fixed point. With the use of the four-bar mechanism, and larger dome volume pistons, a range of 8:1 to 11.5:1 CR was achieved. The prototype VCR engine was tested and analyzed at three different CR’s at a fixed load of 600 kPa net indicated mean effective pressure gross (IMEPGROSS) at an engine speed of 1000 revolutions per minute (RPM). At this condition, a sweep of combustion phasing was conducted. with a stoichiometric air to fuel mixture for each case. The CR’s selected for engine testing were 8.7:1, 10.2:1, and 11.1:1. The processed data includes averaged cycle analysis of each of the test conditions including combustion phasing, combustion duration, and cycle variation. The combustion data was also analyzed to determine overall heat release, indicated gross, net, pumping mean effective pressures, and indicated fuel conversion efficiency for each of the CR’s. The studies show an indicated fuel conversion efficiency of 31.2% for the 8.7:1 CR. As the CR was increased to 10.2:1 and 11.1:1 the relative increase in efficiency was 7.1% and 9.7% respectively at MBT combustion phasing.

Conceptual Approach on Feasible Hydrogen Contents for Retrofit of CNG to HCNG under Heavy-Duty Spark Ignition Engine at Low-to-Middle Speed Ranges

Hydrogen-based engines are progressively becoming more important with the increasing utilization of hydrogen and layouts (e.g., onboard reforming systems) in internal combustion engines. To investigate the possibility of HICE (hydrogen fueled internal combustion engine), such as an engine with an onboard reforming system, which is introduced as recent technologies, various operating areas and parameters should be considered to obtain feasible hydrogen contents itself. In this study, a virtual hydrogen-added compressed natural gas (HCNG) model is built from a modified 11-L CNG (Compressed Natural Gas) engine, and a response surface model is derived through a parametric study via the Latin hypercube sampling method. Based on the results, performance and emission trends relative to hydrogen in the HCNG engine system are suggested. The operating conditions are 1000, 1300, and 1500 rpm under full load. For the Latin hypercube sampling method, the dominant variables include spark timing, excess air ratio (i.e., λCH4+H2), and H2 addition. Under target operating conditions of 1000, 1300, and 1500 rpm, the addition of 6–10% hydrogen enables the virtual HCNG engine to reach similar levels of torque and BSFC (brake specific fuel consumption) compared to same lambda condition of λCH4. For the relatively low 1000 rpm speed under conditions similar to those of the base engine, NOx formation is greater than base engine condition, while a similar NOx level can be maintained under the middle speed range (1300 and 1500 rpm) despite hydrogen addition. Upon addition of 6–10% hydrogen under the middle speed operation range, the target engine achieves performance and emission similar to those of the base engine.