The influence of pressure on electrolytic conduction in alkali silicate glasses

1965 ◽  
Vol 18 (1) ◽  
pp. 1 ◽  
Author(s):  
SD Hamann

This paper reports measurements of the electrical resistances of some lithium, sodium, and potassium silicate glasses between 1 and 2000 atm and from 15 to 35�C. The resistances of all the glasses increased with increasing pressure, and the change was greatest for the potassium glass. The apparent volumes of activation for the conduction process were found to be slightly greater than the volumes of the alkali metal ions that carried the current.

2012 ◽  
Vol 8 ◽  
pp. 951-957 ◽  
Author(s):  
Marco Marradi ◽  
Stefano Cicchi ◽  
Francesco Sansone ◽  
Alessandro Casnati ◽  
Andrea Goti

The preparation of low-generation dendrimers based on a simple calix[4]arene scaffold by insertion of the iminosugar-analogue C 2-symmetric 3,4-dihydroxypyrrolidine is described. This methodology allows a rapid incorporation of a considerable number of iminosugar-like moieties in a reduced volume and in a well-defined geometry. The inclusion of alkali-metal ions (sodium and potassium) in the polar cavity defined by the acetamide moieties at the lower rim of the calixarene was demonstrated, which allows also the rigidification of the dendrimer structure and the iminosugar presentation in the clusters. The combination of the supramolecular properties of calixarenes with the advantage of a dendrimeric presentation of repetitive units opens up the possibility of generating well-defined multivalent and multifaceted systems with more complex and/or biologically relevant iminosugars.


2019 ◽  
Vol 21 (2) ◽  
pp. 561-571 ◽  
Author(s):  
Shun-ichi Ishiuchi ◽  
Yuta Sasaki ◽  
James M. Lisy ◽  
Masaaki Fujii

Differentiating K+ and Na+ binding patterns in peptide sequences.


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