Kinetics of the successive chlorination of 1,2-dichloroethane in the liquid phase

1969 ◽  
Vol 22 (6) ◽  
pp. 1177 ◽  
Author(s):  
DS Caines ◽  
RB Paton ◽  
DA Williams ◽  
PR Wilkinson

Liquid 1,2-dichloroethane has been chlorinated by dissolved chlorine to a succession of chloroethanes up to the ultimate hexachloroethane. The results of both batch and continuous stirred tank reactor systems have been analysed by computer techniques to give a set of relative rate constants from which one can predict the product composition for a given chlorine uptake, the aim in this work being to optimize the production of tetrachloroethanes. An unusual feature of the kinetics is that 1,1,1,2- and 1,1,2,2-tetrachloroethanes provide alternative pathways between 1,1,2-trichloroethane and pentachloroethane.


2018 ◽  
Vol 3 (3) ◽  
pp. 333-343
Author(s):  
Sourav Sengupta ◽  
Amit Jain ◽  
Sirshendu De

The depectinization kinetics of bael (Aegle marmelos) juice using the enzyme pectinase was evaluated and it was observed to follow the Michaelis–Menten model.





2018 ◽  
Vol 57 (48) ◽  
pp. 16201-16208 ◽  
Author(s):  
V. Russo ◽  
E. Santacesaria ◽  
R. Tesser ◽  
R. Turco ◽  
R. Vitiello ◽  
...  


2013 ◽  
Vol 29 (02) ◽  
pp. 57-65
Author(s):  
Guillermo J. Rincon ◽  
Enrique J. La Motta ◽  
Blake Mickler

Research on the electrocoagulation (EC) of hexane extractable materials (HEM) has been conducted at the University of New Orleans using a commercial bench-scale EC reactor. A series of EC experiments were performed using a synthetic emulsion with a HEM concentration of approximately 700 mg/L−1. It was confirmed that EC of HEM follows first-order kinetics, and kinetic constants of 0.0441 s−1 and 0.0443 s−1 were obtained from applying both the dispersion and tanks-in-series (TIS) models, respectively. In both cases, R2 was 0.97. Also, the TIS model indicated that each cell of the EC behaves as an independent continuous-stirred tank reactor.



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