Kinetics of the successive chlorination of 1,2-dichloroethane in the liquid phase
Keyword(s):
Liquid 1,2-dichloroethane has been chlorinated by dissolved chlorine to a succession of chloroethanes up to the ultimate hexachloroethane. The results of both batch and continuous stirred tank reactor systems have been analysed by computer techniques to give a set of relative rate constants from which one can predict the product composition for a given chlorine uptake, the aim in this work being to optimize the production of tetrachloroethanes. An unusual feature of the kinetics is that 1,1,1,2- and 1,1,2,2-tetrachloroethanes provide alternative pathways between 1,1,2-trichloroethane and pentachloroethane.
2007 ◽
Vol 22
(2)
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pp. 149-164
1972 ◽
Vol 22
(2)
◽
pp. 149-164
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2007 ◽
Vol 26
(1)
◽
pp. 527-535
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1977 ◽
pp. 708-716
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2018 ◽
Vol 57
(48)
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pp. 16201-16208
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2010 ◽
Vol 136
(10)
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pp. 1119-1127
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