This study, in southern New South Wales (NSW), examined the chemical properties of ~4700 surface soils in agricultural paddocks and recorded lime and gypsum inputs. The area was bounded approximately by Cootamundra in the north, the NSW/Victorian border in the south, extending to Tumbarumba in the east and to near Berrigan in the west. The long-term average annual rainfall ranged from ~420 mm in the west to a maximum of 1175 mm in the east. The data, collected between 1997 and 2003, were for the surface 20 cm of soil, in two 10-cm layers. The data were generated from a soil testing program conducted with farmers in the region. We grouped the soils into three zones based on a GPS location taken at the time of sampling. These zones were 1 (lower rainfall mixed farming), 2 (higher rainfall mixed farming) and 3 (long-term pasture). Acidic soils occurred across all three zones; however, the soils in zone 1 appeared to be less acidic than soils in the other two zones. We found that surface soils (0–10 cm) with soil pH in 1 : 5 soil : 0.01 mol/L calcium chloride (pHCa) ≤4.5 represented 27%, 57% and 54% for zones 1, 2 and 3, respectively. In addition, zone 1 had 74% of surface soils with a pHCa ≤ 5.0, and this was more acidic than previously reported. However, the surface soils in zone 1 had relatively low exchangeable aluminium (Alex) and had less acidic subsurface soils (10–20 cm), so that responses to lime application by pastures and crops may be less frequent or smaller than the surface soil pHCa alone may indicate. There was a higher frequency of acidic soils (pHCa ≤ 4.5) in the subsurface soils than in the surface soils in zones 2 (62 cf. 57%) and 3 (64 cf. 54%), suggesting that the acidity problem at this depth was a major problem. Low pHCa in the subsurface soil is known to be a constraint on crop yield. We found no evidence of the amendment of this soil depth when lime was applied and incorporated into the 0–10 cm depth, and economic amendment of acidity in the 10–20 cm depth remains unresolved.
Increased adoption of liming occurred in the late 1990s, and by 1997 the percentage of paddocks limed was 14.3%, 21.3% and 13.6% in zones 1 to 3, respectively. Soil pH buffering and long-term pHCa decline after liming were similar to rates reported in field experiments. The total quantities of lime applied were insufficient for soil amendment and maintenance of soil pHCa, particularly in the long-term pasture areas. The rate of soil acidification in the 0–20 cm depth in the average annual rainfall range of 525–625 mm was estimated to be 1.52 kmol H+/ha.year. This would require 76 kg lime/ha.year to neutralise. Sodic and saline soils occurred mainly in the lower rainfall cropping areas, and were more frequent in an area around the township of Lockhart. Half the gypsum applications were at low rates (≤0.5 t/ha), and were probably for sulfur application to canola. Some of the sodic soils were acidic (34% ≤ pHCa 4.5) so that the application of lime/gypsum mixes could be appropriate in the amendment of these soils. Soils in the pasture system had mean organic carbon content (OC%) of 2.42, compared to the cropping zones at 1.65 and 1.75%. OC% was related to annual average rainfall; the increase in OC% was 0.19% and 0.08% for each 100 mm of average annual rainfall for the surface and subsurface soil, respectively. A group of soils in the cropping areas had surface OC% ≤ 1.25% OC (zone 1, 12%; zone 2, 20%) and this could be the result of intensive cropping. Most soils (55–63%) were of moderate P status (P(Colwell), 21–60 µg/g). However, there was still a substantial group of soils (31–43%) of low P status (P ≤ 20 µg/g). Most surface soils in all zones (72–80%) were low to marginal in sulfur status (KCl 40, ≤10 mg S/kg). Sulfur deficiency has been identified in canola, and current practice in the cropping areas is for inputs of gypsum at low rates.