Effects of Flame Temperature and Fuel Composition on Soot Formation in Gas Turbine Combustors

1983 ◽  
Vol 35 (1-4) ◽  
pp. 117-131 ◽  
Author(s):  
David W. Naegeli ◽  
Lee G. Dodge ◽  
Clifford A. Moses
Author(s):  
Yonatan Cadavid ◽  
Andres Amell ◽  
Juan Alzate ◽  
Gerjan Bermejo ◽  
Gustavo A. Ebratt

The wet compressor (WC) has become a reliable way to reduce gas emissions and increase gas turbine efficiency. However, fuel source diversification in the short and medium terms presents a challenge for gas turbine operators to know how the WC will respond to changes in fuel composition. For this study, we assessed the operational data of two thermal power generators, with outputs of 610 MW and 300 MW, in Colombia. The purpose was to determine the maximum amount of water that can be added into a gas turbine with a WC system, as well as how the NOx/CO emissions vary due to changes in fuel composition. The combustion properties of different gaseous hydrocarbon mixtures at wet conditions did not vary significantly from each other—except for the laminar burning velocity. It was found that the fuel/air equivalence ratio in the turbine reduced with lower CH4 content in the fuel. Less water can be added to the turbine with leaner combustion; the water/fuel ratio was decreased over the range of 1.4–0.4 for the studied case. The limit is mainly due to a reduction in flame temperature and major risk of lean blowout (LBO) or dynamic instabilities. A hybrid reaction mechanism was created from GRI-MECH 3.0 and NGIII to model hydrocarbons up to C5 with NOx formation. The model was validated with experimental results published previously in literature. Finally, the effect of atmospheric water in the premixed combustion was analyzed and explained.


Author(s):  
Thijs Bouten ◽  
Martin Beran ◽  
Lars-Uno Axelsson

The OPRA OP16 gas turbine is an all radial single-shaft gas turbine rated at 1.9 MW with a successful track record from oil and gas applications as well as industrial and commercial CHP applications. To meet the growing demand for alternative fuels, OPRA Turbines has developed a new tubular combustor for the OP16 gas turbine fleet. The combustor has been successfully tested on a wide variety of (ultra-) low-calorific gaseous fuels in an atmospheric combustion test rig. This paper presents an experimental investigation of syngas combustion in the low-calorific fuel combustor. The effect of the variation in fuel composition on the combustion characteristics has been investigated extensively. This includes the effect of variable heating values and variations in the ratio between hydrogen and carbon monoxide and between syngas and hydrocarbons. The effects of these variations on the combustor performance, emissions and lean blowout limits will be discussed and compared to the results obtained from the combustion of propane. Major differences in emissions have been found, mainly influenced by the flame temperature and presence of hydrogen in the fuel. Lean blowout of the combustor is largely determined by the presence of hydrogen, whereas other components are found to have less influence. Theoretical calculation, based on le Chatelier’s rule and a method based on heat release, of the lean blowout limit has been compared to the experiments. It was found that the heat release method predicts the flammability limit more accurately than le Chatelier’s rule. This is caused by the inaccuracy of the latter to handle fuels with a large amount of hydrogen.


1987 ◽  
Vol 5 (4) ◽  
pp. 373-386 ◽  
Author(s):  
Yousef S.H. Najjar ◽  
Riad M. Droubi

2018 ◽  
Vol 2 ◽  
pp. C3N5OA ◽  
Author(s):  
Noah Klarmann ◽  
Benjamin Timo Zoller ◽  
Thomas Sattelmayer

A numerical model is presented for the precise prediction of carbon monoxide (CO) emissions in gas turbine combustors. All models are based on Computational Fluid Dynamics (CFD). This work starts with an introduction of fundamental mechanisms, which are responsible for CO emissions. As we will show, there is a need of CO-models as standard combustion models fail to predict CO-emissions precisely. For the purpose of validation, experiments are conducted. High ratios of secondary air is bypassing the burner in order to induce interaction of the flame front with secondary air, as the flame brush gets diluted and decreases in reactivity. Note, this is an important mechanism for elevated CO emissions in multi-burner systems with high staging ratio. Five operating points with each having a different adiabatic flame temperature were measured. They include equilibrium (complete burnout) and superequilibrium CO (incomplete burnout). In summary, it is shown that the prediction of CO with the presented models lead to a significant improvement as it captures the transition from equilibrium to superequilibrium CO. Furthermore, the strong underestimation of CO predicted by standard combustion models is shown.


Author(s):  
Anil K. Tolpadi ◽  
Allen M. Danis ◽  
Hukam C. Mongia ◽  
R. Peter Lindstedt

A method is presented for predicting soot in gas turbine combustors. A soot formation/oxidation model due to Fairweather et al [1992] has been employed. This model has been implemented in the CONCERT code which is a fully elliptic three-dimensional (3-D) body-fitted computational fluid dynamics (CFD) code based on pressure correction techniques. The combustion model used here is based on an assumed probability density function (PDF) parameterized by the mean and variance of the mixture fraction and a β-PDF shape. In the soot modeling, two additional transport equations corresponding to the soot mass fraction and the soot number density are solved. As an initial validation, calculations were performed in a simple propane jet diffusion flame for which experimental soot concentration measurements along the centerline and along the radius at various axial downstream stations were available from the literature. Soot predictions were compared with measured data which showed reasonable agreement. Next, soot predictions were made in a 3-D model of a CF6-80LEC engine single annular combustor over a range of operating pressures and temperatures. Although the fuel in the combustor is Jet-A, the soot computations assumed propane to be the surrogate fuel. To account for this fuel change, the soot production term was increased by a factor of 10X. In addition, the oxidation term was increased by a factor of 4X to account for uncertainties in the assumed collision frequencies. The soot model was also tested against two other combustors, a CF6-80C and a CFM56-5B. Comparison of the predicted scot concentrations with measured smoke numbers showed fairly good correlation within the range of the soot model parameters studied. More work has to be performed to address several modeling issues including sensitivity to oxidation rate coefficients and scalar diffusion.


Author(s):  
Yeshayahou Levy ◽  
G. Arvind Rao ◽  
Valery Sherbaum

Flameless combustion is one of the most promising technologies that can meet the stringent demands of reduced pollution and increased reliability in future gas turbine engines. Although this new combustion technology has been successfully applied to industrial furnaces, there are inherent problems that prevent application of this promising technology in a gas turbine combustor. One of the main problems is the need for recirculating large amount of burnt gases with low oxygen content, within limited volume, and over a wide range of operating conditions. In the present paper, thermodynamic analysis of a novel combustion methodology operating in the flameless combustion regime for a gas turbine combustor is carried out from the first principles, with an objective to reduce oxygen concentration and temperature in the primary combustion zone. The present analysis shows that unlike in the conventional gas turbine combustor, transferring heat from primary combustion zone to secondary (annulus) cooling air can substantially reduce oxygen concentration in reactants and the combustion temperature, thus reducing NOx formation by a large margin. In addition, to reduce the peak temperature, the proposed methodology is conceptualised / designed such that energy from fuel is released in two steps, hence reducing the peak flame temperature substantially. The new proposed methodology with internal conjugate heat transfer is compared vis-a`-vis to other existing schemes and the benefits are brought out explicitly. It is found that transferring heat from the combustion zone reduces oxygen concentration and increases carbon-dioxide concentration in the combustor, thus creating an environment conducive for flameless combustion. In addition, a schematic of a practical engineering design working on the new proposed methodology is presented. This new methodology, which calls for transfer of heat from the primary combustion zone to alternative air streams, is expected to change the way gas turbine combustors will be designed in the future.


2001 ◽  
Author(s):  
Meredith B. Colket ◽  
Robert J. Hall ◽  
David Liscinsky ◽  
Mitchell D. Smooke

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