Thermal Desorption Temperature Affects Water Retention and Hydraulic Conductivity of Three Contrasting Soils

Author(s):  
Jake Mowrer ◽  
Tony Provin ◽  
Binita Thapa ◽  
Steven Perkins
Author(s):  
Shaoyang Dong ◽  
Yuan Guo ◽  
Xiong (Bill) Yu

Hydraulic conductivity and soil-water retention are two critical soil properties describing the fluid flow in unsaturated soils. Existing experimental procedures tend to be time consuming and labor intensive. This paper describes a heuristic approach that combines a limited number of experimental measurements with a computational model with random finite element to significantly accelerate the process. A microstructure-based model is established to describe unsaturated soils with distribution of phases based on their respective volumetric contents. The model is converted into a finite element model, in which the intrinsic hydraulic properties of each phase (soil particle, water, and air) are applied based on the microscopic structures. The bulk hydraulic properties are then determined based on discharge rate using Darcy’s law. The intrinsic permeability of each phase of soil is first calibrated from soil measured under dry and saturated conditions, which is then used to predict the hydraulic conductivities at different extents of saturation. The results match the experimental data closely. Mualem’s equation is applied to fit the pore size parameter based on the hydraulic conductivity. From these, the soil-water characteristic curve is predicted from van Genuchten’s equation. The simulation results are compared with the experimental results from documented studies, and excellent agreements were observed. Overall, this study provides a new modeling-based approach to predict the hydraulic conductivity function and soil-water characteristic curve of unsaturated soils based on measurement at complete dry or completely saturated conditions. An efficient way to measure these critical unsaturated soil properties will be of benefit in introducing unsaturated soil mechanics into engineering practice.


2020 ◽  
Vol 195 ◽  
pp. 01004
Author(s):  
Ali Kolahdooz ◽  
Hamed Sadeghi ◽  
Mohammad Mehdi Ahmadi

Dispersive soils, as one of the main categories of problematic soils, can be found in some parts of the earth, such as the eastern-south of Iran, nearby the Gulf of Oman. One of the most important factors enhancing the dispersive potential is the existence of dissolved salts in the soil water. The main objective of this study is to explore the influence of water salinity on the instability of a railway embankment due to rainfall infiltration. In order to achieve this goal, the embankment resting on a dispersive stratum is numerically modeled and subjected to transient infiltration flow. The effect of dispersion is simplified through variations in the soil-water retention curve with salinity. The measured water retention curves revealed that by omitting the natural salinity in the soil-water, the retention capability of the soil decreases; therefore, the unsaturated hydraulic conductivity of the soil stratum will significantly decline. According to the extensive decrease in the hydraulic conductivity of the desalinated materials, the rainfall cannot infiltrate in the embankment and the rainfall mostly runs off. However, in the saline embankment, the infiltration decreases the soil suction; and consequently, the factor of safety of the railway embankment decreases.


2019 ◽  
Vol 19 (6) ◽  
pp. 4061-4073 ◽  
Author(s):  
Angela Buchholz ◽  
Andrew T. Lambe ◽  
Arttu Ylisirniö ◽  
Zijun Li ◽  
Olli-Pekka Tikkanen ◽  
...  

Abstract. The volatility of oxidation products of volatile organic compounds (VOCs) in the atmosphere is a key factor to determine if they partition into the particle phase contributing to secondary organic aerosol (SOA) mass. Thus, linking volatility and measured particle composition will provide insights into SOA formation and its fate in the atmosphere. We produced α-pinene SOA with three different oxidation levels (characterized by average oxygen-to-carbon ratio; O:C‾=0.53, 0.69, and 0.96) in an oxidation flow reactor. We investigated the particle volatility by isothermal evaporation in clean air as a function of relative humidity (RH <2 %, 40 %, and 80 %) and used a filter-based thermal desorption method to gain volatility and chemical composition information. We observed reduced particle evaporation for particles with increasing O:C‾ ratio, indicating that particles become more resilient to evaporation with oxidative aging. Particle evaporation was increased in the presence of water vapour and presumably particulate water; at the same time the resistance of the residual particles to thermal desorption was increased as well. For SOA with O:C‾=0.96, the unexpectedly large increase in mean thermal desorption temperature and changes in the thermogram shapes under wet conditions (80 % RH) were an indication of aqueous phase chemistry. For the lower O:C‾ cases, some water-induced composition changes were observed. However, the enhanced evaporation under wet conditions could be explained by the reduction in particle viscosity from the semi-solid to liquid-like range, and the observed higher desorption temperature of the residual particles is a direct consequence of the increased removal of high-volatility and the continued presence of low-volatility compounds.


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