scholarly journals Complex refractive index, single scattering albedo, and mass absorption coefficient of secondary organic aerosols generated from oxidation of biogenic and anthropogenic precursors

2019 ◽  
Vol 53 (4) ◽  
pp. 449-463 ◽  
Author(s):  
Justin H. Dingle ◽  
Stephen Zimmerman ◽  
Alexander L. Frie ◽  
Justin Min ◽  
Heejung Jung ◽  
...  
Keyword(s):  
Refractive Index ◽  
Absorption Coefficient ◽  
Secondary Organic Aerosols ◽  
Complex Refractive Index ◽  
Organic Aerosols ◽  
Single Scattering ◽  
Single Scattering Albedo ◽  
Mass Absorption Coefficient ◽  
Mass Absorption

scholarly journals Optical properties of atmospheric fine particles near Beijing during the HOPE-J<sup>3</sup>A Campaign

2015 ◽  
Vol 15 (22) ◽  
pp. 33675-33730
Author(s):  
X. Xu ◽  
W. Zhao ◽  
Q. Zhang ◽  
S. Wang ◽  
B. Fang ◽  
...  
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Fine Particles ◽  
Complex Refractive Index ◽  
Single Scattering ◽  
Single Scattering Albedo ◽  
Organic Mass ◽  
Absorption Coefficients ◽  
Aerosol Composition ◽  
Inorganic Species

Abstract. The optical properties and chemical composition of PM1.0 (particulate with an aerodynamic diameter of less than 1.0 μm) particles in a suburban environment (Huairou) near the mega-city Beijing were measured during the HOPE-J3A (Haze Observation Project Especially for Jing-Jin-Ji Area) field campaign. The campaign covered the period November 2014 to January 2015 during the winter coal heating season. The average and standard deviations for the extinction, scattering, absorption coefficients, and the aerosol single scattering albedo (SSA) at λ = 470 nm during the measurement period were 201 ± 240, 164 ± 202, 37 ± 43 Mm-1, and 0.80 ± 0.08, respectively. The mean mass scattering (MSE) and absorption (MAE) efficiencies were 4.77 ± 0.01 and 0.87 ± 0.03 m2g-1, respectively. Highly time-resolved air pollution episodes clearly show the dramatic evolution of the PM1.0 size distribution, extensive optical properties (extinction, scattering, and absorption coefficients) and intensive optical properties (single scattering albedo and complex refractive index) during haze formation, development and decline. Time periods were classified into three different pollution levels (clear, slightly polluted, and polluted) for further analysis. It was found that: (1) The diurnal patterns of the aerosol extinction, scattering, absorption coefficients, and SSA differed for the three pollution classes. (2) The real and imaginary part of complex refractive index (CRI) increased, while the SSA decreased from clear to polluted days. (3) The relative contributions of organic and inorganic species to observed aerosol composition changed significantly from clear to polluted days: the organic mass fraction decreased (50 to 43 %) while the proportion of sulfates, nitrates, and ammonium increased strongly (34 to 44 %). (4) The fractional contribution of chemical components to extinction coefficients was calculated by using the modified IMPROVE algorithm. Organic mass was the largest contributor (58 %) to the total extinction of PM1.0. When the air quality deteriorated, the change of the relative contribution of sulfate aerosol to the total extinction was small, but the contribution of nitrate aerosol increased significantly (from 17 % on clear days to 23 % on polluted days). (5) The observed mass scattering efficiencies increased consistently with the pollution extent, however, the observed mass absorption efficiencies increased consistently with increasing mass concentration in slightly pollution conditions, but decreased under polluted conditions.

scholarly journals Vertical profiles of urban aerosol complex refractive index in the frame of ESQUIF airborne measurements

2008 ◽  
Vol 8 (4) ◽  
pp. 901-919 ◽  
Author(s):  
J.-C. Raut ◽  
P. Chazette
Keyword(s):  
Refractive Index ◽  
Complex Refractive Index ◽  
Single Scattering ◽  
In Situ Measurements ◽  
Single Scattering Albedo ◽  
Vertical Profiles ◽  
Airborne Measurements ◽  
Paris Area

Abstract. A synergy between lidar, sunphotometer and in situ measurements has been applied to airborne observations performed during the Etude et Simulation de la QUalité de l'air en Ile-de-France (ESQUIF), enabling the retrieval of vertical profiles for the aerosol complex refractive index (ACRI) and single-scattering albedo with a vertical resolution of 200 m over Paris area. The averaged value over the entire planetary boundary layer (PBL) for the ACRI is close to 1.51(±0.02)–i0.017(±0.003) at 532 nm. The single-scattering albedo of the corresponding aerosols is found to be ~0.9 at the same wavelength. A good agreement is found with previous studies for urban aerosols. A comparison of vertical profiles of ACRI with simulations combining in situ measurements and relative humidity (RH) profiles has highlighted a modification in aerosol optical properties linked to their history and the origin of the air mass. The determination of ACRI in the atmospheric column enabled to retrieve vertical profiles of extinction coefficient in accordance with lidar profiles measurements.

scholarly journals Vertical profiles of urban aerosol complex refractive index in the frame of ESQUIF airborne measurements

2007 ◽  
Vol 7 (4) ◽  
pp. 10799-10835 ◽  
Author(s):  
J.-C. Raut ◽  
P. Chazette
Keyword(s):  
Refractive Index ◽  
Complex Refractive Index ◽  
Single Scattering ◽  
In Situ Measurements ◽  
Single Scattering Albedo ◽  
Vertical Profiles ◽  
Airborne Measurements ◽  
Paris Area

Abstract. A synergy between lidar, sunphotometer and in situ measurements has been applied to airborne observations performed during the Etude et Simulation de la QUalité de l'air en Ile-de-France (ESQUIF), enabling the retrieval of vertical profiles for the aerosol complex refractive index (ACRI) and single-scattering albedo with a vertical resolution of 200 m over Paris area. The averaged value over the entire planetary boundary layer (PBL) for the ACRI is close to 1.51(±0.02)–i0.017(±0.003) at 532 nm. The single-scattering albedo of the corresponding aerosols is found to be ~0.9 at the same wavelength. A good agreement is found with previous studies for urban aerosols. A comparison of vertical profiles of ACRI with simulations combining in situ measurements and relative humidity (RH) profiles has highlighted a modification in aerosol optical properties linked to their history and the origin of the air mass. The determination of ACRI in the atmospheric column enabled to retrieve vertical profiles of extinction coefficient in accordance with lidar profiles measurements.

Evolution of the Complex Refractive Index of Secondary Organic Aerosols during Atmospheric Aging

2018 ◽  
Vol 52 (6) ◽  
pp. 3456-3465 ◽  
Author(s):  
Quanfu He ◽  
Nir Bluvshtein ◽  
Lior Segev ◽  
Daphne Meidan ◽  
J. Michel Flores ◽  
...  
Keyword(s):  
Refractive Index ◽  
Secondary Organic Aerosols ◽  
Complex Refractive Index ◽  
Organic Aerosols ◽  
Atmospheric Aging

scholarly journals Modeling of Aerosol Radiation-Relevant Parameters in the Troposphere of Siberia on the Basis of Empirical Data

Atmosphere ◽  
2018 ◽  
Vol 9 (11) ◽  
pp. 414 ◽  
Author(s):  
Mikhail Panchenko ◽  
Svetlana Terpugova ◽  
Victor Pol’kin ◽  
Valerii Kozlov ◽  
Dmitry Chernov
Keyword(s):  
Complex Refractive Index ◽  
West Siberia ◽  
Single Scattering ◽  
Single Scattering Albedo ◽  
Optical Characteristics ◽  
Asymmetry Factor ◽  
Size Spectrum ◽  
Scattering Phase ◽  
Scattering Phase Function ◽  
Modal Radius

The paper presents the generalized empirical model of the aerosol optical characteristics in the lower 5-km layer of the atmosphere of West Siberia. The model is based on the data of long-term airborne sensing of the vertical profiles of the angular scattering coefficient, aerosol disperse composition, as well as the content of absorbing particles. The model provides for retrieval of the aerosol optical characteristics in visible and near IR wavelength ranges (complex refractive index, scattering and absorption coefficients, optical depth, single scattering albedo, and asymmetry factor of the scattering phase function). The main attention in the presented version of the model is given to two aspects: The study of the effect of the size spectrum of the absorbing substance in the composition of aerosol particles on radiative-relevant parameters (the single scattering albedo (SSA) and the asymmetry factor (AF)) and the consideration of different algorithms for taking into account the relative humidity of air. The ranges of uncertainty of SSA and AF at variations in the modal radius of the absorbing fraction at different altitudes in the troposphere are estimated.

Simultaneous Determination of Layer Thickness, Composition, and Mass Absorption by X-Ray Diffraction

1992 ◽  
Vol 7 (4) ◽  
pp. 194-196 ◽  
Author(s):  
Stefano Battaglia ◽  
Marco Franzini ◽  
Leonardo Leoni
Keyword(s):  
Absorption Coefficient ◽  
Simultaneous Determination ◽  
Mass Absorption Coefficient ◽  
Crystalline Substance ◽  
X Ray Diffraction ◽  
Mass Thickness ◽  
Mass Absorption ◽  
Crystalline Substrate ◽  
Quantitative Results

AbstractThis paper describes a new method for the simultaneous determination of mineral composition, mass thickness and mass absorption coefficient of a thin layer of a crystalline substance deposited on a crystalline substrate.The samples were deposited on membrane disc filters, consisting of mixtures of cellulose acetate and cellulose nitrate. Quantitative results are achieved by measuring the diffraction intensity of the analyte and the attenuation of a reflection of the crystalline material supporting the deposited sample. The mean accuracy of the analysis was found to be: ≈ 3% for mass thickness, ≈ 1% for mass absorption coefficient and ≈ 4% for quantitative mineralogical determination.

scholarly journals Atmospheric radiative effects of an in-situ measured Saharan dust plume and the role of large particles

2007 ◽  
Vol 7 (3) ◽  
pp. 7767-7817 ◽  
Author(s):  
S. Otto ◽  
M. de Reus ◽  
T. Trautmann ◽  
A. Thomas ◽  
M. Wendisch ◽  
...  
Keyword(s):  
Complex Refractive Index ◽  
Single Scattering ◽  
Single Scattering Albedo ◽  
Saharan Dust ◽  
Dust Particles ◽  
Modal Parameters ◽  
Size Distributions ◽  
Radiative Effects ◽  
Enhanced Absorption ◽  
Large Particles

Abstract. This work will present aerosol size distributions measured in a Saharan dust plume between 0.9 and 12 km altitude during the ACE-2 campaign 1997. The distributions contain a significant fraction of large particles of diameters from 4 to 30 μm. Radiative transfer calculations have been performed using these data as input. Shortwave, longwave as well as total atmospheric radiative effects (AREs) of the dust plume are investigated over ocean and desert within the scope of sensitivity studies considering varied input parameters like solar zenith angle, scaled total dust optical depth, tropospheric standard aerosol profiles and particle complex refractive index. The results indicate that the large particle fraction has a predominant impact on the optical properties of the dust. A single scattering albedo of ωo=0.75–0.96 at 550 nm was simulated in the entire dust column as well as 0.76 within the Saharan dust layer at ~4 km altitude indicating enhanced absorption. The measured dust leads to cooling over the ocean but warming over the desert due to differences in their spectral surface albedo and surface temperature. The large particles absorb strongly and they contribute at least 20% to the ARE in the dusty atmosphere. From the measured size distributions modal parameters of a bimodal lognormal column volume size distribution were deduced, resulting in a coarse median diameter of ~9 μm and a column single scattering albedo of 0.78 at 550 nm. A sensitivity study demonstrates that variabilities in the modal parameters can cause completely different AREs and emphasises the warming effect of the large mineral dust particles.

Mass Absorption Coefficient Measurements Using Thin Films

1969 ◽  
Vol 13 ◽  
pp. 632-638 ◽  
Author(s):  
P. Lublin ◽  
P. Cukor ◽  
R. J. Jaworowski
Keyword(s):  
Thin Films ◽  
Absorption Coefficient ◽  
Mass Absorption Coefficient ◽  
Absorption Coefficients ◽  
Electron Probe Analysis ◽  
Mass Absorption ◽  
Probe Analysis ◽  
Absorption Correction ◽  
Thin Foils ◽  
Metal Organic

For quantitative electron probe analysis, the raw intensity ratios must be corrected to take into account deviations due to absorption, fluoresecnce and electron beam penetration. The major correction is usually the absorption correction, so that for best results, accurate mass absorption coefficients are required. Many tables of absorption coefficients are calculated by interpolation or extrapolation from available measured values, and therefore new measurements are required for increased reliability. The region which requires the most attention for present-day probe analysis is the 2 to 10 Å range.Thin foils of the lighter metals are available for mass absorption coefficient measurements, but heavy metal foils, which must be extremely thin, are not obtainable, A method has been developed to prepare thin films of heavy metals on a suitable substrate by pyrolytic decomposition of metal organic compounds.

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